• Title/Summary/Keyword: surface phase transition

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Electrical and thermal characteristics of PRAM with thickness of phase change thin film (상변화 박막의 두께에 따른 상변화 메모리의 전류 및 열 특성)

  • Choi, Hong-Kyw;Kim, Hong-Seung;Lee, Seong-Hwan;Jang, Nak-Won
    • Journal of Advanced Marine Engineering and Technology
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    • v.32 no.1
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    • pp.162-168
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    • 2008
  • In this paper, we analyzed the heat transfer phenomenon and the reset current variation of PRAM device with thickness of phase change material using the 3-D finite element analysis tool. From the simulation, Joule's heat was generated at the contact surface of phase change material and bottom electrode of PRAM. As the thickness of phase change material was decreased, the reset current was highly increased. In case thickness of phase change material thin film was $200\;{\AA}$, heat increased through top electrode and reset current caused by phase transition highly increased. And as thermal conductivity of top electrode decreased, temperature of unit memory cell was increased.

An Investigation of Lattice Boltzmann Multi-phase Model and it Application (래티스볼츠만 다상류 모델의 검토 및 응용)

  • Kang, Ho-Keun;Ahn, Soo-Whan
    • Proceedings of the Korean Society of Marine Engineers Conference
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    • 2006.06a
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    • pp.269-270
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    • 2006
  • A finite difference lattice Boltzmann model which allows us to simulate gas-liquid two-phase flows with large density difference, for instance, 800 times for air and water is considered. Two-particle model is used and the density difference is introduced by changing the acceleration according to the fluid density. Numerical measurement of surface tension agrees well with theoretical predictions. Simulations of two-phase phenomenon for phase-transition is carried out, showing applicability of the model for two-phase flows. The two-dimensional cavitating flow around a board set up in the fluid way is also simulated. As a result, it was confirmed that the FDLB method with two-particle model was effective in numerical simulation of cavitating flow and the bubble periodically grew up at the low pressure area behind the board, in which the fluid condition was influenced by the cavitation number.

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A Study on Stimulus reaction and Physical Properties of PBDG (PBDG의 자격반응과 물성에 관한 연구)

  • Chang, Hun;Lee, Kyung-Sup
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.07a
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    • pp.1047-1049
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    • 2001
  • The displacemant current measuring system used for detecting the dynamic behavior of monolayers at the air-water interface is described. It basically consists of a film balance, a pair of electrodes connected to each other through a sensitive ammeter. Here, one electrode is suspended in air and the other electrode is placed in the water. With Maxwell-displacement-current-measuring method, the phase transitions of Poly-${\gamma}$ -benzyl D-glutamate(PBDG) on a water surface were detected. Measured surface pressure, displacement current and dipole moment of monolayers of PBDG on the water surface. We measured analyzed displacement current that occur when differed temperature. Could know that displacement current is proportional in increase of temperature and great as experiment result.

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Synthesis and characterization of visible light active photocatalytic $TiO_2$

  • Kim, Duk-Su;Park, Kyu-Sung;Kim, Il-Doo;Kim, Ho-Gi
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.07b
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    • pp.1116-1120
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    • 2002
  • Using thermal hydrolysis and hydrothermal treatment, photocatalytic $TiO_2$ powders were synthesized. During the synthesis, the addition of other transition metals such as iron, copper, etc., affected the photocatalytic capability of synthesized powders, and enabled the activation by visible light. To enhance photocatalytic capacity of gas phase decomposition, the rate-determining adsorption rate of pollutant gases were improved via surface modification of $TiO_2$ powders. The surface modifiers were implanted using mechanochemical synthesis of dopants and photocatalytic powders.

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Ferroelectric Domans in $BaTiO_3$ ($BaTiO_3$의 강유전성 분역)

  • 박봉모;정수진
    • Journal of the Korean Ceramic Society
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    • v.33 no.1
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    • pp.56-64
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    • 1996
  • A large amount of papers about the cubic-to-tetragonal phase transition the ferroelectric domain structures of the BaTiO3 were already reported but there exist still some needs to observe the domain behaviors directly. In this study the domain structures of the tinned plates prepared from ta single crystal grown by the TSSG technique were observed using a polarizing microscope TE and X-ray topography. The spatial relation be-tween the orientation states of domains was investigated and the effects of external stresses and electric fields on the behaviors of ferroelectric and ferroelastic domains were studied. All the 90$^{\circ}$walls cut off in the crystal are the wedge shaped lamellar domains and all the straight boundaries in the observed domain patte군 can be interpreted as the head-to-tail 90$^{\circ}$walls. The irregular overlapped boundaries commonly observed by using a polarizing microscope and X-ray topography are complex combinations of well-known 90$^{\circ}$walls and are domain walls were predominant and were stabilized after surface polishing. In the paraelectric phase region the domain walls vanished but the residual surface strain patterns could be seen at the same positions of the stabilized 90$^{\circ}$a-a walls in the tetragonal phase region, These stabilized walls resulted from the surface strain had a memory effect in domain formation during the repeated phase transitions and could notr be affected by an external electtric field.

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Crystallization and Phase Transition of TiO2Nanotubes by Heat Treatment. (열처리 조건에 따른 TiO2 나노튜브의 결정구조 및 형상 변화)

  • Lee, Ju-Yeong;Mun, Seong-Mo;Jeong, Yong-Su
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2012.05a
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    • pp.319-319
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    • 2012
  • 수용액에서 양극산화법을 이용하여 티타늄 표면에 $TiO_2$ 나노튜브를 형성시켰고, XRD 및 전자현미경을 통해 열처리를 한 $TiO_2$ 나노튜브 소재표면, 계면구조를 관찰하였으며, 이는 향후 나노튜브의 결정구조를 제어할 수 있는 자료로 활용 될 것으로 기대된다.

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Electro-rheological Measurements of Phase Inversion of Emulsions under Shear Flow (전단응력 하에서 에멀젼 상 변이의 측정을 위한 전기 유변학적 연구)

  • Seung Jae, Baik;Young-Jin, Lee;Yoon Sung, Nam;Chin Han, Kim;Han Kon, Kim;Hak Hee, Kang
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.30 no.2
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    • pp.147-151
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    • 2004
  • This study aims at measuring electrical and rheological properties of cosmetic emulsions on the skin under shear flow. The effects of volume ratio and surfactants on structural changes of emulsions were examined by determining the changes of electrical resistance, viscosity, and morphology. As the ratio of the internal phase increased, the phase inversion occurred more quickly. The viscosity change was found to increase with increasing of the variation of electrical resistance of the emulsions. This phenomenon may be caused by decreased resistant force against the shear flow because of the breakdown of the internal phase. Surfactants a]so played a key ro]e on phase transition of emulsions. It is likely that polymeric surfactants anchoring on the emulsion surface reinforced the interfacial mechanical strength. As the concentration of surfactants increased, the phase transition occurred more slowly. It has been demonstrated that the phase changes of emulsions under shear flow can be monitored on the real-time basis by using a JELLI$\^$TM/ chip system, a combination of conductiometry and rheometry. Our approach is expected to a useful experimental tool for predicting the phase transition of the cosmetic products during skin application.

Structural Analysis of Simulated Fission-Produced Noble Metal Alloys and Their Superconductivities

  • Park, Yong Jun;Lee, Gwang Yong;Lee, Jong Gyu;Heo, Yong Deuk;Kim, Won Ho
    • Bulletin of the Korean Chemical Society
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    • v.21 no.12
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    • pp.1187-1192
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    • 2000
  • Ternary (Mo-Ru-Pd) and binary (Mo-Ru, Mo-Pd) alloys have been prepared using an Ar arc melting furnace. Mo and the noble metals, Ru and Pd, are the constituents of metallic insoluble residues, which were found in the early days of post-irradiation studies on uranium oxide fuels. In the present study, the structure of the alloys was evaluated using a powder X-ray diffractometer. Unit cell parameters were determined by least squares refinements of powder X-ray diffraction data. Scanning electron microscopic analyses of the surface of the alloys indicated that surface morphology was dependent on the crystallographic structure as well as its composition. Measurements of the magnetic susceptibility of the alloys showed evidence of superconducting transition from 3 to 9.2 K. Among the ternary and binary alloys, the ${\sigma}-phase$ showed the highest superconducting transition temperature,~9.2 K.

Dielectric relaxation properties in the lead scandium niobate

  • Yeon Jung Kim
    • Journal of the Korean institute of surface engineering
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    • v.56 no.4
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    • pp.227-232
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    • 2023
  • In this study, complex admittance as a function of temperature and frequency was measured to analyze the important relaxation properties of lead scandium niobate, which is physically important, although it is not an environmentally friendly electrical and electronic material, including lead. Lead scandium niobate was synthesized by heat treating the solid oxide, and the conductance, susceptance and capacitance were measured as a function of temperature and frequency from the temperature dependence of the RLC circuit. The relaxation characteristics of lead scandium niobate were found to be affected by contributions such as grain size, grain boundary characteristics, space charge, and dipole arrangement. As the temperature rises, the maximum admittance and susceptance increase in one direction, but the resonance frequency decreases below the transition temperature but increases after the phase transition.

Phase Transition and Surface Morphological Characteristics of Intermediate Product Feitknechtite According to Aging Time during the Synthesis of Birnessite (버네사이트 합성 시 에이징 시간에 따른 중간생성물 페이크네타이트 상전이 및 표면 형태학적 특성)

  • Min, Soyoung;Kim, Yeongkyoo
    • Journal of the Mineralogical Society of Korea
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    • v.32 no.3
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    • pp.213-222
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    • 2019
  • Birnessite (birnessite, $7{\AA}$ manganate, ${\delta}-MnO_2$) is a major mineral comprising manganese nodule. Various synthetic methods have been studied and evaluated because it can be used as an ion exchange agent and a battery recharging material. However, it is difficult to obtain a single birnessite phase because it does not have a stoichiometric chemical composition. Feitknechtite (${\beta}-MnOOH$) is formed as an intermediate product during birnessite synthesis and in this study, the transition of this phase to birnessite was compared by using XRD and SEM. Two different methods, Feng et al. (2004) and Luo et al. (1998), based on redox reaction were used. It was possible to obtain the impurity-free birnessite for the sample aged 60 days at $27^{\circ}C$ by Feng et al. (2004) method and 3 days at $60^{\circ}C$ by Luo et al. (1998) method. The phase transition rate of the feitknechtite phase was slower in the case of $Mg^{2+}$ doped birnessite which was synthesized by Luo et al. (1998) method, and almost single phase almost single phase birnessite was identified at high temperature. Crystal surface and morphology also confirmed the difference between the samples synthesized by two methods.