• Journal of Sensor Science and Technology
• /
• v.15 no.3
• /
• pp.173-178
• /
• 2006

Silica aerogel with ultra low density and high porosity has been focused on versatile application due to its fascinating properties. Ambient drying process of waterglass, in this study was researched to fabricate a crack-free monolith body in the point view of cost effective way. Wet gel was obtained by removing of $Na^{+}$ ions in waterglass, which contains 8 wt% of $SiO_{2}$. Xylene, which has a low vapor pressure, was used as a solution substitutor to prevent the formation a cracks during drying. Various surface modifiers like as hexamethyldisilazane (HMDSZ), trimethylchlorosilane (TMCS), methyltriethoxylsilane (MTES), methyltrimethoxysilane (MTMS) and phenyltriethoxysilane (PTES) were used in order to improve hydrophobicity of the waterglass Silica aerogel. Some physical properties of the surface modified aerogels were investigated by FT-IR, TGA, BET and SEM. Hydrophobicity and hydrophilicity of Silica aerogel is attributed to the Si-OH bond and the non-polar C-H bond groups on the surface of aerogel. Crack-free waterglass aerogel with >90 % of porosity, 17 nm of pore size and <0.15 $g/cm^{3}$ of density was prepared. HMDSZ and TMCS are effective as a surface modifier

• Journal of the Korean Society of Clothing and Textiles
• /
• v.37 no.7
• /
• pp.962-971
• /
• 2013

We compared the effectiveness of amidase (amano acylase, AA) and an endopeptidase, (trypsin, TR) in modifying the hydrophobicity of polyamide fabric. We evaluated the number of amino groups released into the reaction mixture in order to optimize the treatment conditions. We found that a large number of amino groups were released into the reaction mixture due to the cleavage of amide bonds by AA hydrolysis; however, the TR hydrolysis exhibited a relatively lower activity compared to AA hydrolysis. In AA and TR hydrolysis, significant differences were observed in the K/S values and moisture regain. Amide bonds in polyamide fabric were hydrolyzed by AA hydrolysis effectively. Compared to TR, AA formed more hydrolysis product (amino groups) on the fabric surface. Thus, the hydrophobicity of polyamide fabric was modified using AA hydrolysis (as verified by the wettability test) without any deterioration of fiber strength.

• Journal of Microbiology
• /
• v.37 no.3
• /
• pp.128-135
• /
• 1999

Among oil-degrading microorganisms isolated from oil-polluted industrial areas, one yeast strain showed high degradation activity of aliphatic hydrocarbons. From the analyses of 18S rRNA sequences, fatty acid, coenzyme Q system, G+C content of DNA, and biochemical characteristics, the strain was identified as Yarrowia lipolytica 180. Y. lipolytica 180 degraded 94% of aliphatic hydrocarbons in minimal salts medium containing 0.2% (v/v) of Arabian light crude oil within 3 days at 25$^{\circ}C$. Optimal growth conditions for temperature, pH, NaCl concentration, and crude oil concentration were 30$^{\circ}C$, pH 5-7, 1%, and 2% (v/v), respectively. Y. lipolytica 180 reduced surface tension when cultured on hydrocarbon substrates (1%, v/v), and the measured values of the surface tension were in the range of 51 to 57 dynes/cm. Both the cell free culture broth and cell debris of Y. lipolytica 180 were capable of emulsifying 2% (v/v) crude oil by itself. They were also capable of degrading crude oil (2%). The strain showed a cell surface hydrophobicity higher than 90%, which did not require hydrocarbon substrates for its induction. These results suggest that Y. lipolytica has high oil-degrading activity through its high emulsifying activity and cell hydrophobicity, and further indicate that the cell surface is responsible for the metabolism of aliphatic hydrocarbons.

• Journal of Sensor Science and Technology
• /
• v.15 no.5
• /
• pp.371-377
• /
• 2006

Nano porous, transparent silica aerogels monoliths were prepared under ambient drying (1 atm, $270^{\circ}C$) condition by the combination of sol-gel process and surface modification with subsequent heat treatment. Three kinds of solvent, n-hexane, n-heptane and xylene, were selected in the point view of low surface tension and vapor pressure in order to restrain a formation of cracks during drying. Crack-free silica aerogels with over 93 % of porosity and below $0.14g/cm^3$ of density were obtained by solvent exchange and surface modification under atmosphere condition. Optimum solvent was confirmed n-heptane among these solvents through estimation of FT-IR, TGA, BET and SEM. Modified silica aerogel exhibited a higher porosity and pore size compare to unmodified aerogels. Hydrophobicity was also controled by C-H and H-OH bonding state in the gel structure and heat treatment over $400^{\circ}C$ effects to the hydrophobicity due to oxidation of C-H radicals.

• The Korean Journal of Mycology
• /
• v.38 no.1
• /
• pp.69-74
• /
• 2010

The 2 strains of Pleurotus ostreatus showing very severe and mild symptom of brown blotch were selected, and their F1 hybrid strains were made by mating of their single spore isolates. Hydrophobicity of fruiting body surface and brown blotch severity of the parental and their 11 F1 hybrid strains showing different level of severity of brown blotch were determined. Correlation coefficient (R) between disease severity and hydrophobicity were 0.68 and 0.70 on two independent experiments. Correlation coefficient between disease severity and disease incidence that was determined in the oyster mushroom farm were 0.46 and 0.52 on two independent experiments. When GFP-tagged Pseudomonas tolaasii was monitored with confocal microscope on cap surface of fruiting body, more cells of the pathogen were clustered on the severe strain than the mild strain, which indicates that the bacterial pathogen proliferates more on the severe strain. These results suggest that hydrophobicity of oyster mushroom fruiting body affects disease severity of the brown blotch disease; the longer the bacterial suspension stays on fruiting body surface more severe symptom of the blotch develops.

• Food Science and Biotechnology
• /
• v.14 no.4
• /
• pp.493-497
• /
• 2005

Probiotics are generally excreted within a few days if their ingestion in feces at the same rate as or even more quickly than a transit marker (meaning not clear). Ability of probiotics to adhere to intestine prolongs their persistence in gastrointestinal tract, allowing them to exert healthful effects longer. Hydrophobicities, zeta potentials, Alcian blue-binding capacities, and sedimentation profiles of Pichia farinosa SKM-1, P. anomala SKM-T, and Galactomyces geotrichum SJM-59 were determined to evaluate characteristic properties of cell surfaces responsible for adhesion. Results of intestinal Caco-2 cell line in vitro and murine intestine in vivo studies revealed these strains exhibit adhesive properties regardless of their cell surface hydrophobicity.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
• /
• 2003.09a
• /
• pp.132-135
• /
• 2003

Solution chemistry, sorbate chemistry, and sorbent chemistry were widely investigated to find important factors that affect PAH sorption on mineral surfaces and to elucidate its microscopic mechanism. The solution chemistry, pH and ionic strength caused measurable change of HOC sorption reaction to minerals. The detectable change of Ka occurred at a pH region crossing the PZC (Point of Zero Charge) of each mineral. The PAH hydrophobicity, one of sorbate chemistry, was observed to have a strong correlation with PAM sorption to mineral. Mineral surface area was not found to be a predominant factor controlling PAH sorption. The mineral type might be more likely to play a crucial role in controlling the PAH sorption behavior. The CEC (Cation Exchange Capacity) of mineral, representing surface charge density, has meaningful correlation with regression slope of sorption coefficients (log $K_{d}$) versus aqueous activity coefficients (log Υ$_{w}$).).).

• Proceedings of the KIEE Conference
• /
• 2000.07c
• /
• pp.1569-1571
• /
• 2000

The ageing process was checked by leakage current monitoring in Salt Fog Method. In order to monitor leakage current, DAS with 12-bit, 8-channel A/D converter was prepared. The monitored components of leakage current were averages of the rms and peak, max peak, cumulative charge, and the cumulative number of peak pulses. The acquired data were stored to the disc periodically. And, surface conductivity was measured to investigate loss of hydrophobicity. The results suggest that surface conductivity and leakage current are well corresponding to initial loss of hydrophobicity.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
• /
• v.12 no.1
• /
• pp.1-10
• /
• 1999

In this paper, we have investigated the effects of the environmental factors on Low Molecular Weight (LMW) silicone fluid contents existing in high temperature vulcanized (HTV) silicone rubber sample, using dipping method and contact angle, current measurement. Artificial treatments such as immersion in water, elevated temperature, UV irradiation and dry band arcing under salt-fog condition are selected as the environmental factors. This results will be helpful to investigate the degradation with time and to expect a life time, because the LMW silicone content, which is important to recovery the hydrophobicity of silicone rubber surface, show different results by each environmental factors.

• Textile Coloration and Finishing
• /
• v.33 no.4
• /
• pp.258-268
• /
• 2021

This study conducted on the introduction of recycled cellulose fibers, which are widely used in the textile industry as eco-friendly biomass materials, into polypropylene resins, which are mainly used for interior and exterior materials such as door trims and console parts of automobiles. In general, cellulose fibers can affect mechanical properties and have a lightening effect when used as a reinforcing agent. However, since cellulose fibers have hydrophilic properties and have relatively low compatibility with industrial polymer resins, they are used in combination through fiber hydrophobic surface treatment. Therefore, through this study, the reforming reaction conditions optimized in terms of hydrophobicity and workability for cellulose fibers are studied. Furthermore, polypropylene containing surface-modified cellulose fibers was prepared to compare physical properties by fiber content and study optimized content.