• 한국전산유체공학회지
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• 제19권1호
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• pp.15-20
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• 2014

Accurate simulation of free-surface wave flows around a ship is very important for better hull-form design. In this paper, a computational fluid dynamics (CFD) code, termed SNUFOAM, which is based on the open source libraries, OpenFOAM, was developed to predict the wave patterns around a ship. Additional anti-diffusion source term for minimizing a numerical diffusion, which was caused by convection differencing scheme, was considered in the volume-fraction transport equation. The influence of the anti-diffusion source term was tested by applying it to free-surface wave flow around the Wigley model ship. In results, the band width of the volume fraction contours between 0.1 to 0.9 at the hull surface was narrowed by considering the anti-diffusion term.

• 한국지하수토양환경학회:학술대회논문집
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• 한국지하수토양환경학회 2005년도 총회 및 춘계학술발표회
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• pp.114-116
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• 2005

Natural attenuation has been actively studied and often selected as final clean-up process in remediation of contaminated ground-water and soil for the last decade. Accordingly, understanding of natural processes affecting the fate and transport of contaminants in the subsurface becomes important for a success of implementation of the natural remediation strategy, Contaminant advection and diffusion processes in the unsaturated zone are naturally related to environmental changes in the atmosphere. The atmospheric pressure changes affecting the transport of contaminants in the subsurface are investigated in this study. Moisture content, trichloroethylene (TCE) concentration, temperature, and pressure variations in the subsurface were measured for the July, August, November, and December 2001 at Picatinny Arsenal, New Jersey. These data were used for a one-phase flow and one-component transport model in simulating the soil-gas flow and accordingly the TCE transport in the subsurface in accordance with the atmosphere pressure variations at the surface. The soil-gas velocities during the sampling periods varied with a magnitude of $10^{-6}\;to\;10^{-7}\;m\;s^{-1}$ at land surface. The TCE advection fluxes at land surface were several orders of magnitude smaller than the TCE diffusion fluxes. A sensitivy analysis indicated that advection fluxes were more sensitive to changes in geo-environmental conditions compared to diffusion fluxes. Of all the parameters investigated in this study, moisture content has the most significant effect on TCE advection and diffusion fluxes.

• Journal of Electrochemical Science and Technology
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• 제13권3호
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• pp.347-353
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• 2022

Agarose hydrogel, a solid electrolyte, was investigated voltammetrically in terms of transport properties and natural convection effects using a ferrocenyl compound as a redox probe. To confirm the diffusion properties of solute on the agarose interface, the diffusion coefficients (D) of ferrocenemethanol in agarose hydrogel were determined by cyclic voltammetry (CV) according to the concentration of agarose hydrogel. While the value of D on the agarose interface is smaller than that in the bulk solution, the square root of the scan rate-dependent peak current reveals that the mass transport behavior of the solute on the agarose surface shows negligible convection or migration effects. In order to confirm the reduced natural convection on the gel interface, scan rate-dependent CV was performed in the solution phase and on the agarose surface, respectively. Slow scan voltammetry at the gel interface can determine a conventional and reproducible diffusion-controlled current down to a scan rate of 0.3 mV/s without any complicated equipment.

• 한국전산유체공학회:학술대회논문집
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• 한국전산유체공학회 2011년 춘계학술대회논문집
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• pp.46-53
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• 2011

Water is continuously produced in polymer electrolyte membrane fuel cell (PEMFC), and is transported and exhausted through polymer electrolyte membrane (PEM), catalyst layer (CL), microporous layer (MPL), and gas diffusion layer (GDL). The low operation temperatures of PEMFC lead to the condensation of water, and the condensed water hinders the transport of reactants in porous layers (MPL and GDL). Thus, water flooding is currently one of hot issues that should be solved to achieve higher performance of PEMFC. This research aims to study liquid water transport in porous layers of PEMFC by using pore-network model, while the microscale pore structure and hydrophilic/hydrophobic surface properties of GDL and MPL were fully considered.

• 멤브레인
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• 제7권3호
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• pp.150-156
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• 1997

입자의 정밀여과에 있어 임계플럭스의 이론치를 계산하기 위해 확산(diffusion), 횡방향이동(lateral migration), 전단유도확산(shear induced diffusion), 그리고 입자의 정전기적 반발력에서 기인하는 상호작용에 의한 상승이동(interation enhanced migration) 등의 입자의 역전달 이동을 고려하였다. 보통의 여과조건에서 제타전위의 절대치가 20~40mV이고 직경이 0.1$\mu{m}$~10$\mu{m}$인 입자의 경우 상호작용에 의한 이동이 가장 중요한 역전달 메카니즘이었다. 입자크기에 따라 계산된 임계플럭스값을 실험적으로 확인하기 위해 다양한 크기를 갖는 구형인 적철광(hematite)입자를 합성하여 여과실험을 수행하였다. 이 실험치는 역전달 이론에 의해 예측된 플럭스의 이론치와 비교적 잘 일치하였다.

• Journal of Advanced Research in Ocean Engineering
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• 제2권2호
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• pp.48-60
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• 2016

Accurate simulation of free-surface wave flows around a ship is very important for better hull-form design. In this paper, a computational fluid dynamics (CFD) code which is based on the open source libraries, OpenFOAM, was developed to predict the wave patterns around a ship. Additional anti-diffusion source term for minimizing a numerical diffusion, which was caused by convection differencing scheme, was considered in the volume-fraction transport equation. The influence of the anti-diffusion source term was tested by applying it to free-surface wave flow around the Wigley and KCS model ships. In results, the wave patterns and hull wave profiles of the Wigley and KCS model ships for various anti-diffusion coefficients showed quite close patterns. While, the band width of the water volume-fraction values between 0.1 to 0.9 at the Wigley and KCS model hull surfaces was narrowed by considering the anti-diffusion term. From the results, anti-diffusion source term decreased free-surface smearing.

• 멤브레인
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• 제14권1호
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• pp.75-84
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• 2004

폴리아미드계 역삼투 분리막의 투과성능을 비교하기 위하여 NaCl과 NaOCl을 함유하는 혼합용액을 공급수로 사용하여 연속운전과 단속운전 하에서 실험하여 보았다. 이 결과를 가지고 막 이동 모델의 선택적 적용이 가능함을 제시하고자 하였으며 투과 성능 분석 결과, 용액 확산 모델과 선흡착-모세관이동 모델이 운전 모드에 따라 상대적으로 유용함을 볼수 있었다. 연속 운전에서는 선흡착-모세관이동 모델을, 단속 운전에서는 용액 확산 모델을 따름을 알 수 있었다 NaOCl에 의한 표면 변화를 SEM 사진을 통하여 확인 할 수 있었다. 연속운전 후의 막은 염소 투과 결과 표면에서 부분적인 ridge and valley 구조가 나타났으며 단속 운전 후의 막은 표면 전반에서 변성이 일어난 것을 볼 수 있었다.

• Computers and Concrete
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• 제15권3호
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• pp.461-471
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• 2015

The permeability is the most direct indicator to reflect the durability of concrete, and the testing methods based on external electric field can be used to evaluate concrete permeability rapidly. This study aims to use an experiment method to accurately predict the permeability of concrete box beam during service. The ion migration experiments and concrete surface resistivity are measured to evaluate permeability of five concrete box beams, and the relations between these results in service concrete and electric flux after 6 hours by ASTM C1202 in the laboratory are analyzed. The chloride diffusion coefficient of concrete, concrete surface resistivity and concrete 6 hours charge have good correlation relationship, which denote that the chloride diffusion coefficient and the surface resistivity of concrete are effective for evaluating the durability of concrete structures. The chloride diffusion coefficient of concrete is directly evaluated permeability of concrete box beam in service and may be used to predict the service life, which is fit to engineering applications and the concrete box beam is non-destructive. The concrete surface resistivity is easier available than the chloride diffusion coefficient, but it is directly not used to calculate the service life. Therefore the mathematical relation of the concrete surface resistivity and the concrete chloride diffusion coefficient need to be found, which the service life of reinforced concrete is obtained by the concrete surface resistivity.

• 멤브레인
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• 제7권1호
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• pp.1-10
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• 1997

A review is presented for various gas transport mechanisms through microporous membranes of both polymeric and inorganic materials. Different transport modes manifest depending on the pore size and the flow regime, which is a function of pressure, temperature, and the interaction between gas molecules and the pore walls. For microporous membranes whose pores are small and the internal surface area huge, the surface diffusion becomes a significant factor. If the pores become even smaller, then the transport mechanism will be more of an activated diffusion type. When conditions are right capillary condensation will take place to create an enormous capillary pressure gradient, which will greatly enhance the permeation flux. At the same time the capillary condensate of the heavier component may block the membrane pores denying the passage of the lighter gas molecules. All of these phenomena will influence the separation of mixtures.

• 한국막학회:학술대회논문집
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• 한국막학회 2004년도 Proceedings of the second conference of aseanian membrane society
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• pp.128-131
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• 2004

The composite mesoporous ceramic membranes were prepared with ${\gamma}$-alumina and poly (2, 6-dimethyl-l, 4-pyphenylene oxide) (PPO) on the surface of the macroporous $\alpha$-alumina ceramic membranes and the permeation results were compared with those of the $\alpha$-alumina membrane for large-scale applications. In the results of the transport experiments, the ceramic membranes gave high gas permeances mainly due to Knudsen diffusion and surface diffusion as an additional mechanism. And, the polymer modification increased the permeances of the strongly adsorbing gas components. In this study the modifications of alumina ceramic membranes could increase the gas permeation performances especially for the strongly absorbing gas components.