• Title/Summary/Keyword: surface aging

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The Change of Microstructures by Low Temperature Aging in Y-TZP (저온 열처리에 의한 Y-TZP 미세조직의 변화)

  • Lee, Jong-Kook;Kim, Hwan
    • Journal of the Korean Ceramic Society
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    • v.27 no.6
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    • pp.735-740
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    • 1990
  • The phase transformation of Y-TZP by low temperature aging treatments and its related behaviors of crack formation were investigated. The kinetics of phase transformation was greatly dependent on the amounts of Y2O3, grian size and microstructures of sintered body. The phase transformation happened to start at specimen surface and near the pore in the first place, where the change of strain energy during the phase transformation was small and the water vapor that accelerated phase transformation easily diffused.

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The New Estimation of Surface Discharge Insulation Using Fractal Dimension (프랙탈 차원을 이용한 SD절연의 새로운 평가)

  • Lim, Jang-Seob;Han, Jae-Hong;Kim, Duck-Keun
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.05a
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    • pp.55-58
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    • 2000
  • Fractal mathematics is being highlighted as a research method for classification of image. But the application of Fractal dimension(FD) has been required the complicated calculation method because of its complex repetition progressing. In this paper, it has been developed the new approach method to express the Fractal Dimension(FD) for aging level calculation and estimation system of outside insulator using special image processing algorithm. As a result after FD testing, the recognized aging estimation of FD has a very characteristics compared to the conventional visual inspection.

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Tracking Resistance and Aging Characteristics of Epoxy Insulating Materials by the Rotating Wheel Dip Test (Rotating Wheel Dip Test에 의한 에폭시 절연재료의 내트래킹성과 열화 특성)

  • Cho, Han-Goo
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.21 no.6
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    • pp.530-537
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    • 2008
  • This paper describes the results of a study on the tracking performance of outdoor insulating materials based on the rotating wheel dip test(RWDT). And, the influence of surface degradation was evaluated through such as measurement of the flashover voltage after and before tracking test, also aspects of surface degradation using scanning electron microscopy. The time to tracking breakdown of treated filled specimen is longer than untreated filled specimen. And, after the RWDT, the surface of specimen by adding untreated filler appeared heavy erosion. It was found that the addition to surface treated filler, the better tracking resistance. In the RWDT, the breakdown specimen is not affected by the dry flashover voltage, despite the fact that the surface degradation of tracking test has different state on each specimen. This suggests that wet flashover voltage play an important role in evaluating of tracking and erosion on the surface degradation in tracking test. And, the flashover voltage of specimen under wet conditions are greatly affected by the salt concentration and degree of degradation by the RWDT Because of hydrophobicity and degree of degradation by the RWDT, the flashover voltage of treated filled specimen is higher than that of untreated filled specimen. Different types of specimen may have different hydrophobicity and their surface state under contaminated conditions may not be the same.

Effects of high-pressure processing on taste-related ATP breakdown compounds and aroma volatiles in grass-fed beef during vacuum aging

  • Utama, Dicky Tri;Lee, Seung Gyu;Baek, Ki Ho;Jang, Aera;Pak, Jae In;Lee, Sung Ki
    • Asian-Australasian Journal of Animal Sciences
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    • v.31 no.8
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    • pp.1336-1344
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    • 2018
  • Objective: This study aimed to observe whether high-pressure processing (HPP) affected aroma development and the degradation rate of umami taste-related ATP breakdown products, specifically inosinic acid in grass-fed beef during vacuum aging. Methods: Strip loin (longissimus lumborum) cuts obtained from six grass-fed Friesian Holstein steers (32 months old) on day 4 post slaughter were vacuum-packed and subjected to pressurization at 300 and 500 MPa for 180 s at $15^{\circ}C{\pm}2^{\circ}C$. The samples were then stored for 4 weeks at $5^{\circ}C{\pm}0.5^{\circ}C$ under vacuum and compared with the control (0.1 MPa). Results: HPP increased the shear force value, promoted moisture loss and lipid oxidation, induced surface paleness, stabilized pH during aging, and reduced bacterial load and growth. The shear force value of 500 MPa-treated samples remained higher than the control after aging, while no significant differences were found between the control and 300 MPa-treated samples. Degradation of inosinic acid and inosine occurred during pressurization, resulting in an increase in hypoxanthine content. However, the degradation rate in HPP-treated samples during aging was slower; therefore, inosinic acid and inosine content remained higher than in control samples. No significant differences were found in hypoxanthine content at the end of aging. HPP intensified the levels of hexanal, octanal, 2-methylbutanal, 3-methylbutanal, benzaldehyde, and 2,5-dimethylpyrazine in cooked-aged beef samples. Conclusion: HPP induced aroma development and delayed the degradation of inosinic acid. However, it also reduced the postmortem tenderization rate.

Influence of Electrolyte Aging on Electrotinning in Phenolsulfonic Acid Bath (전기주석도금 반응에 미치는 PSA계 도금용액 노화의 영향)

  • Bae Dae Chul;Kim Tae Yeob;Cho Joon Hyung;Lee Jae Ryung;Chang Sam Kyu;Cho Kyung-mox
    • Journal of the Korean Electrochemical Society
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    • v.3 no.3
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    • pp.162-168
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    • 2000
  • The influence of phenolsulfunate concentrations on electroplating characteristics and electrochemical behaviors was investigated with a viewpoint of electrolyte aging using the circulation cell and potentiostate And comparison of tinplate coating appearance such as glossiness and Image clarify has been also studied with varying of phenolsulfonic acid (PSA) solutions. As the aging of electrolyte proceeded, the limiting current density was moved to a lower current density region by the limitation of mass transfer, and higher phenolsulfunate concentrations resulted in the narrower optimum current density range and deterioration of coating surface of tinplates. The difference of the limiting current density was not remarkable with increasing electrolyte temperature. Thus the electrolyte aging was attributed to the limitation of thermally-activated process such as mass transfer of reducible ions. It has also been considered that the accumulation of phenolsulfonate suppressed normal electrotinning reaction by reducing the mobility of stannous ions, taking into account of the smaller effect of electrolyte aging. Experiments showed similar polarization behavior between the electrolyte of high phenolsufonate solution and the aged one, which comes to conclude that the accumulation of phenolsulfonate is one of the major causes of electrolyte aging.

Quality Properties Depending on Aging of Deabong Persimmon-fermented Liquor (매실 첨가 대봉감 발효 숙성주의 이화학적 특성)

  • Kwang Keun, Cho;Sang Won, Gal;Sang-Won, Lee
    • Journal of Life Science
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    • v.32 no.11
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    • pp.847-854
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    • 2022
  • The purpose of this study was to prepare Daebong persimmon-fermented liquor supplemented with Prunus mume fruit to promote the consumption of Daebong persimmon and to develop local specialties. As fermentation progressed, the alcohol content rapidly increased, whereas the sugar content decreased. With the production of CO2 from the second day of fermentation, the epidermis and flesh solids of the Daebong persimmons began mixing together and rose to the surface of the fermentation container. This phenomenon continued until the fourth and fifth days of fermentation; on the fifth day, the ethanol and sugar contents were 11.4% and 9.8°Brix, respectively. A concentration of 6 to 9% (w/w) P. mume fruit was found to be the optimal amount during Daebong persimmon fermentation. When the fermented liquor was stored for 60 days at 5℃, the pH and ethanol content showed no significant change during the aging period. As aging progressed, the content of sugar slowly decreased in both the control sample and in the one to which P. mume was added, showing 9.8 and 10.4 mg/ml at the eighth week post-aging, respectively. The total acid content was 0.79~0.81% at the beginning of aging but slightly increased to 0.84~0.86% in the second week of aging. As a result of the sensory test, the sour taste, sweetness, and flavor were slightly stronger in the P. mume fruit group than in the control group.

Nondestructive Characterization of Degradation of EPDM Rubber for Automotive Radiator Hoses (자동차 냉각기 호스용 EPDM고무의 노화에 대한 비파괴 특성평가)

  • Kwak, Seung-Bum;Choi, Nak-Sam;Choi, Youn-Joung;Shin, Sei-Moon
    • Journal of the Korean Society for Nondestructive Testing
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    • v.25 no.5
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    • pp.368-376
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    • 2005
  • Coolant rubber hoses for automobile radiators can be degraded and thus failed due to the influence of contacting stresses of air and coolant liquid under thermal and mechanical loadings. In this study, for EPDM(ethylene-propylene diene monomer) rubber conventionally used as a radiator hose material the aging behaviors of the skin part due to thermo-oxidative and electro-chemical stresses were nondestructively evaluated. Through the thermo-oxidative aging test, it was shown that the surface hardness IRHD(International Rubber Hardness Degrees) of the rubber increased with a considerable reduction of failure strain. On account of the penetration of coolant liquid into the skin part the weight of rubber specimens degraded by electro-chemical degradation(ECD) test increased, whereas their. failure strain and IRHD hardness decreased largely. The penetration of coolant liquid seemed to induce some changes in inner structure and micro hardness distribution of the rubbers. Consequently, EPDM rubbers degraded by thermo-oxidative aging and ECD could be characterized nondestructively by micro-hardness and chemical structure analysis methods.

The Soluble Form of the Cellular Prion Protein Enhances Phagocytic Activity and Cytokine Production by Human Monocytes Via Activation of ERK and $NF-{\kappa}B$

  • Jeon, Jae-Won;Park, Bum-Chan;Jung, Joon-Goo;Jang, Young-Soon;Shin, Eui-Cheol;Park, Young Woo
    • IMMUNE NETWORK
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    • v.13 no.4
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    • pp.148-156
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    • 2013
  • The $PrP^C$ is expressed in many types of immune cells including monocytes and macrophages, however, its function in immune regulation remains to be elucidated. In the present study, we examined a role for $PrP^C$ in regulation of monocyte function. Specifically, the effect of a soluble form of $PrP^C$ was studied in human monocytes. A recombinant fusion protein of soluble human $PrP^C$ fused with the Fc portion of human IgG1 (designated as soluble $PrP^C$-Fc) bound to the cell surface of monocytes, induced differentiation to macrophage-like cells, and enhanced adherence and phagocytic activity. In addition, soluble $PrP^C$-Fc stimulated monocytes to produce pro-inflammatory cytokines such as $TNF-{\alpha}$, $IL-1{\beta}$, and IL-6. Both ERK and $NF-{\kappa}B$ signaling pathways were activated in soluble $PrP^C$-treated monocytes, and inhibitors of either pathway abrogated monocyte adherence and cytokine production. Taken together, we conclude that soluble $PrP^C$-Fc enhanced adherence, phagocytosis, and cytokine production of monocytes via activation of the ERK and $NF-{\kappa}B$ signaling pathways.

The Effect of Corrosion of Rolling Bearing Ceramics in Alkalic Solution on the Rolling Wear and Hardness (알카리용액에서 구름베어링용 세라믹스의 부식이 구름마모 및 경도에 미치는 영향)

  • 최인혁;김상근;박창남;윤대현;신동우
    • Tribology and Lubricants
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    • v.16 no.2
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    • pp.121-125
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    • 2000
  • Silicon nitride ceramic has been verified as an excellent rolling bearing material because of its high strength and outstanding rolling fatigue life properties. However under some corrosive circumstances it showed drawbacks such as hardness reduction and severe wear caused by corrosion. In this work, the variations of the rolling wear and hardness of three kinds of ceramics were studied for the specimen aged 15 days in alkali water (90 $\pm$ 2$\^{C}$,25 wt% NaOH ). All of the specimens, ① Si$_3$N$_4$, ② 3Y-TZP and ③ 3Y-TZP alloyed with 5 wt% CeO$_2$, were sintered and post-HIPed, and then polished up to 0.02 $\mu$mRa of surface roughness. Rolling wear tests were conducted by MJ type rolling fatigue life tester under the initial theoretical maximum contact stress of 3.16 GPa and the spindle speed of 1,000 rpm. Spindle oil was used as a lubricant. The specimens were not worn before aging. For the specimen aged in alkali water, Si$_3$N$_4$ and 3Y-TZP were worn by rolling wear tests, and hardness was decreased. While aging the specimens, the phase was transformed from tetragonal to monoclinic in 3Y-TZP and the microstructure change occurred in Si$_2$N$_4$. 3Y-TZP specimens alloyed with 5 wt% CeO$_2$ were not worn after aging and no phase transformation occurred while aging.

Effect of Fe Addition on Hydrogen Rich NSR Kinetics over Pt/Co/Ba/Al2O3 Catalyst (Pt/Co/Ba/Al2O3에 Fe 첨가가 수소 풍부 NSR 반응성에 미치는 영향)

  • Kim, Jingul;Jeon, Jiyong;Kim, Seongsoo
    • Transactions of the Korean hydrogen and new energy society
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    • v.23 no.6
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    • pp.581-587
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    • 2012
  • Thermal aging effect on NSR kinetics was studied over Pt/Co/Fe/Ba/$Al_2O_3$ catalyst. The amount of $NO_x$ uptake over Pt/Co/Fe/Ba/$Al_2O_3$ calcined at $400^{\circ}C$ increased with increasing NSR temperature from $200^{\circ}C$ to $400^{\circ}C$, where amount of $NO_x$ uptake is the highest at $400^{\circ}C$ with mol ratio of $NO_x$/Ba = 0.5. Thereafter, the amount of $NO_x$ uptake at $400^{\circ}C$ decreased with the higher calcination temperature, where Pt/Co/Fe/Ba/$Al_2O_3$ catalyst calcined at $700^{\circ}C$ showed an amount of $NO_x$ uptake with the mol ratio of $NO_x$/Ba=0.062. Result of XRD and NSR showed that Fe addition into Pt/Co/Fe/Ba/$Al_2O_3$ suppressed sintering of Pt crystallites and make $NO_x$ uptake larger, compared to no addition of Fe into Pt/Co/Fe/Ba/$Al_2O_3$ catalyst. From BET result, it was found that the change of specific surface area was relatively small by the thermal aging process. Therefore, it was found that the sintering of Pt crystallites caused the decrease of $NO_x$ uptake during NSR reaction and Fe played a role to suppress the sintering process of Pt crystallites caused by thermal aging.