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http://dx.doi.org/10.7316/KHNES.2012.23.6.581

Effect of Fe Addition on Hydrogen Rich NSR Kinetics over Pt/Co/Ba/Al2O3 Catalyst  

Kim, Jingul (Dept. of Chemical Eng., Soonchunhyang University)
Jeon, Jiyong (E&D Corporation Ltd.)
Kim, Seongsoo (Waste Energy Research Center, Korea Institute of Energy Research)
Publication Information
Journal of Hydrogen and New Energy / v.23, no.6, 2012 , pp. 581-587 More about this Journal
Abstract
Thermal aging effect on NSR kinetics was studied over Pt/Co/Fe/Ba/$Al_2O_3$ catalyst. The amount of $NO_x$ uptake over Pt/Co/Fe/Ba/$Al_2O_3$ calcined at $400^{\circ}C$ increased with increasing NSR temperature from $200^{\circ}C$ to $400^{\circ}C$, where amount of $NO_x$ uptake is the highest at $400^{\circ}C$ with mol ratio of $NO_x$/Ba = 0.5. Thereafter, the amount of $NO_x$ uptake at $400^{\circ}C$ decreased with the higher calcination temperature, where Pt/Co/Fe/Ba/$Al_2O_3$ catalyst calcined at $700^{\circ}C$ showed an amount of $NO_x$ uptake with the mol ratio of $NO_x$/Ba=0.062. Result of XRD and NSR showed that Fe addition into Pt/Co/Fe/Ba/$Al_2O_3$ suppressed sintering of Pt crystallites and make $NO_x$ uptake larger, compared to no addition of Fe into Pt/Co/Fe/Ba/$Al_2O_3$ catalyst. From BET result, it was found that the change of specific surface area was relatively small by the thermal aging process. Therefore, it was found that the sintering of Pt crystallites caused the decrease of $NO_x$ uptake during NSR reaction and Fe played a role to suppress the sintering process of Pt crystallites caused by thermal aging.
Keywords
Fe; $NO_x$; Sintering; Thermal aging; NSR;
Citations & Related Records
Times Cited By KSCI : 3  (Citation Analysis)
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