• Title/Summary/Keyword: surface aging

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Performance of Polymer Suspension Insulator with Shed Profile (갓 형상에 따른 폴리머 현수애자의 열화특성)

  • Cho, H.G.;Lee, U.Y.;Kang, S.H.;Lim, K.J.;Yeo, H.G.;Ji, W.Y.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.11a
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    • pp.539-542
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    • 2003
  • Recently, the polymer insulators which are being used for high voltage applications have some advantages such as light weight, small size, vandalism resistance, hydrophobicity and easy making process. During outdoor service of polymer insulators, the surface of the insulating material is frequently subjected to moisture and contamination which lead to the well known phenomenon of dry band arcing. Their tracking resistance, erosion resistance, end sealing and shed design are very important because dry band arcing causes degradation of polymer surface. The shape design of porcelain insulator is formalized but design standard for polymer insulator is no standardized up to now, much research is necessary in real condition. In this paper, the aging property of polymer insulator with shed shape(regular, alternative type) is analyzed through numerical analysis, CEA(canadian electricity association) tracking wheel test and IEC 61109 Annex C.

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Effect of Fine Copper Sulfides on the High Cycle Fatigue Properties of Bake Hardening Steels for Automotive (자동차용 소부경화형(BH) 강의 고주기 피로 특성에 미치는 미세 황화물의 영향)

  • Kang, Seonggeu;Kim, Jinyong;Choi, Ildong;Lee, Sungbok;Hong, Moonhi
    • Korean Journal of Metals and Materials
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    • v.49 no.3
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    • pp.203-210
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    • 2011
  • Bake hardening steels have to resist strain aging to prevent the yield strength increment and stretcher strain during press process and to enhance the bake hardenability during baking process after painting. The bake hardening steels need to control the solute carbon and the solute nitrogen to improve the bake hardenability. Ti and/or Nb alloying for nitride and carbide precipitation and low carbon content below 0.003% are used to solve strain aging and formability problem for automotive materials. However, in the present study, the effect of micro-precipitation of copper sulfide on the bake hardenability and fatigue properties of extremely low carbon steel has been investigated. The bake hardenability of Cu-alloyed bake hardening (Cu-BH) steel was slightly higher (5 MPa) than that of Nb-alloyed bake hardening (Nb-BH) steel, but the fatigue limit of Cu-BH steel was far higher (45 MPa) than that of Nb-BH steel. All samples showed the ductile fracture behavior and some samples revealed distinct fatigue stages, such as crack initiation, stable crack growth and unstable crack growth.

Treatment of Whitening of a Car TPE Component (자동차용 TPE 부품의 백화 처리)

  • Choi, Sung-Seen;Chung, Hye-Seung;Joo, Yong-Tae;Min, Byung-Kwon;Lee, Seong-Hoon
    • Elastomers and Composites
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    • v.45 no.2
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    • pp.94-99
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    • 2010
  • 340 nm UV radiation of $2500\;kJ/m^2$ irradiated a thermoplastic elastomer (TPE) specimen used for interior and exterior materials of a car. After the UV irradiation, the black sample surface was changed to gray. Materials on the aged sample were collected and analyzed using GC/MS, but significant materials were not found. Lots of small cracks were found on the aged specimen surface. Whitening phenomenon of the aged sample disappeared by brushing or searing with a fire on the aged surface. After brushing or searing with a fire, small cracks on the surface vanished. Samples before and after the aging, and the treated samples with brush or fire were analyzed using image analyzer, SEM, EDX, and ATR and the results were compared. The vanished whitening phenomenon by brushing or searing was explained with filling the small cracks by polypropylene of TPE.

Effect of Aging Treatment Temperature on Surface Modifications in Ni-Ti alloy (Ni-Ti합금의 표면개질에 미치는 시효처리 온도의 영향)

  • Park, J.M.;Kim, W.C.
    • Journal of the Korean Society for Heat Treatment
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    • v.22 no.6
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    • pp.368-374
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    • 2009
  • Nickel titanium shape memory alloys (NiTi) have been investigated for applications in the biomedical industry. However, little is known about the influences of surface modifications on the propertise of these alloys. The effect of electropolishing and heat treatments was found to exhibit significant surface roughness. Change of phase was B2, r-phase and B19' by heat treatments. In this study, effect of the electropolishing conditions on surface roughness is investigated in Ni-Ti alloys (Nitinol). Variation in phases with heat treatment temperature is investigated for a Ni-Ti alloy by X-ray diffraction and DSC. Characteristic of the microstructure have been observed by SEM. Surface roughness have been measured by AFM. The results clearly show that significant different in surface property to heat treated at $500^{\circ}C$ (R-phase). $TiO_2$ phases preciritated all of the specimens. It is not good effect of surface roughness because made to surface relief. The surface roughness appears to be important in the property of Ni-Ti alloys for biomedical applications.

Surface Characteristics and Tracking Resistance of Epoxy Insulating Materials against Ultraviolet (자외선 열화에 의한 에폭시 절연재료의 표면특성과 내트래킹성)

  • Cho, Han-Goo;Yoo, Dae-Hoon;Kang, Hyung-Kyung
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.06a
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    • pp.495-496
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    • 2008
  • This paper describes the influence of Ultra-violet irradiation on time to tracking resistance of epoxy insulating materials by use of the inclined plane test. And, the influence of surface degradation was evaluated through several method such as measurement of contact angle, surface roughness, using a scanning electron microscopy. As the 1000 hours of the surface degradation with UV-CON, the flashover time decreases at different rates depending on epoxy resin and silicone rubber specimen. As the duration of the surface degradation with UV-CON is prolonged, the contact angle of epoxy resin decreases at the rate of degradation time, while that of silicone rubber was not exchanged. It is assumed that this phenomenon is related to the decrease in hydrophobicity of the surface of the materials. Also, as to epoxy resin, the decrease of hydrophobicity due to surface degradation with UV-CON is greater than that resulting from surface degradation with WOM. The UV radiation produced chalking and crazing on the surface of the insulating materials specimen.

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Change of fluorescence in ambers according to artificial aging (인공열화에 따른 호박(amber)의 형광특성 변화)

  • Park, Jong-Seo;Lim, Yu-Jin
    • Analytical Science and Technology
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    • v.25 no.3
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    • pp.197-206
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    • 2012
  • Ambers are composed of polymer molecules which contain aromatic moieties such as benzene, naphthalene, phenanthrene and anthracene. They emit fluorescence when irradiated with ultraviolet light, which was used for confirming an amber. The fluorescence of amber, however, tends to decrease as the surface of amber is weathered with light, heat, oxygen for a long time. In this study, the reliability of confirming amber with its fluorescence by measuring the changes of fluorescence after artificial aging. Aging factors were UV light (${\lambda}$=340 nm), oxygen with heat (100%, $90^{\circ}C$) and heat ($90^{\circ}C$) and aging time was for 5, 15, 30 and 60 days, respectively. In the excitation and emission spectra of amber, the intensity decreased and the maximal wavelength was shifted to longer wavelength with artificial aging time. Especially, there was a drastic decrease in the intensity of spectra to 1.7% of initial value after 60 days aging under oxygen with heat. Only in Colombian amber there showed an increase of fluorescence intensity for a certain aging time, which could be explained by the production of aromatic ring in the presence of light and heat. Conclusively, the fluorescence can be lessened by the natural weathering with light, heat and oxygen and it is not accurate to recognize amber just with UV irradiation method.

Depigmenting Effects of Mistletoe (Viscum album var. coloratum) Extracts (겨우살이 추출물의 미백 효과)

  • Hah, Young-Sool;Kim, Eun-Ji;Goo, Young Min;Kil, Young Sook;Sin, Seung Mi;Kim, Sang Gon;Kang, Ha Eun;Yoon, Tae-Jin
    • Journal of Life Science
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    • v.32 no.5
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    • pp.355-361
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    • 2022
  • Melanin pigments are the main cause of skin color. They are produced in melanocytes and then transferred to keratinocytes, which eventually gives the skin surface a variety of colors. Although many skin-lightening or depigmenting agents have been developed, the demand for materials to reduce pig- mentation is still increasing. Here, we tried to find materials for skin-lightening or depigmentation using natural compounds and found that mistletoe (Viscum album var. coloratum) extracts (ME) had an inhibitory effect on tyrosinase activity. As a result, ME significantly reduced pigmentation in human primary melanocytes. In addition, a promoter reporter assay revealed that ME inhibited the transcription of microphthalmia-associated transcription factor (MITF), melanophilin (MLPH), tyrosinase-related protein-2 (TRP-2), and tyrosinase (TYR) genes in HM3KO melanoma cells. In addition, ME decreased the protein level for pigmentation-related molecules, such as TYR and TRP-1. Furthermore, it markedly inhibited the melanogenesis of zebrafish embryos, an in vivo evaluation model for pigmentation. To elucidate the action mechanism of ME, we investigated its effects on intracellular signaling. Eventually, the ME dramatically decreased the phosphorylation of the cAMP responsive element binding protein (CREB), AKT, and ERK. The data suggest that ME may inhibit the melanogenesis pathway by regulating the signaling pathway related to pigmentation. Taken together, these data propose that ME can be developed as a depigmenting or skin-lightening agent.

Sn계 무연 솔더에 관한 연구

  • 이창배;정승부;서창제
    • Proceedings of the International Microelectronics And Packaging Society Conference
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    • 2001.11a
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    • pp.75-87
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    • 2001
  • Three different kinds of substrate used in this study : bare Cu substrate, Ni-P/Cu substrate with a Ni-P layer thickness of $5\mu\textrm{m},$ and Au/Ni-P/Cu substrate with the Ni-P and Au layers of $0.15\mu\textrm{m}$ and $5\mu\textrm{m}$ thickness respectively. The wettability of various Sn-base solders was affected by the substrate metal finish used, i.e., nickel, gold and copper. On the Au/Ni-F/Cu substrate, Sn-base solders wet better than any of the other substrate metal finishes tested. The interfacial reaction between various substrate and Sn-base solder was investigated at $70^{\circ}C,$ $100^{\circ}C,$ $120^{\circ}C,$ $150^{\circ}C,$ $170^{\circ}C$ and $200^{\circ}C$ for reaction times ranging from 0 day to 60 day. Intermetallic phases was formed along a Sn-base solder/ various substrate interface during solid-state aging. The apparent activation energy for growth of Sn-Ag/Cu, Sn-Ag-Bi/Cu, and Sn-Bi/Cu couples were 65.4, 88.6, and 127.9 Kj/mol, respectively. After isothermal aging, the fracture surface shoved various characteristics depending on aging temperature and time, and the types of BGA pad.

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The Dry-aging and Heating Effects on Protein Characteristics of Beef Longissiumus Dorsi

  • Kim, Ji-Han;Lee, Ha-Jung;Shin, Dong-Min;Kim, Tae-Kyung;Kim, Young-Boong;Choi, Yun-Sang
    • Food Science of Animal Resources
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    • v.38 no.5
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    • pp.1101-1108
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    • 2018
  • The aim of this study was to investigate the effects of dry-aging (DA) and the cooking process on the myofibril protein functionalities and in vitro digestibility of proteins in beef loin. Six sirloins from beef were dry-aged for 28 d, and the control group (n=6) was analyzed 2 d postmortem for this study. Dimensional changes (reduction of thickness and surface shrinkage) after cooking were significantly greater in the control group than the DA group, whereas the shear force of the DA group was significantly lower than that of the control. Effect of cooking on aggregation, hydrophobicity, and in vitro digestibility were significantly higher in the DA group than in the control. After cooking, the protein in DA sirloins was more oxidized than in the control samples. According to the sodium dodecyl sulfate-polyacrylamide gel electrophoresis result, the low molecular weight bands (below 17 kDa) increased in the DA group, finding that the protein characteristics of dry-aged beef was affected by cooking.

Electrical and Chemical Properties of Mica/Epoxy Composite Materials as Affected by Short-Time Aging

  • Kim, Hee-Dong
    • KIEE International Transactions on Electrophysics and Applications
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    • v.3C no.2
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    • pp.59-65
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    • 2003
  • Electrical properties such as permittivity and tan$\delta$ of unaged (control) and aged (72 h at 18$0^{\circ}C$) mica/epoxy composites of 130 ${\mu}{\textrm}{m}$ thickness were measured and their surface conditions were characterized using scanning electron microscopy (SEM), Fourier transform infrared (FTIR), electron spectroscopy for chemical analysis (ESCA), differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA). Both permittivity and tan6 of control specimens were higher than those of short-time aged specimens. FTIR results show a new peak at 1710 $cm^{-1}$ / for short-time aged specimens, originating from carbonyl group formed by the oxidation reaction during the aging process. ESCA results show that the binding energy at 532.9 eV representing the singlet state of oxygen ( $O_{1s}$) decreases by 13.7%, whereas that at 534.6 eV increases by 13.7%. Glass transition temperatures of control and short-time aged specimens are observed to be 95.4$^{\circ}C$ and 113.4$^{\circ}C$, which increase with the increase of aging time. TGA results indicate that the control specimens contain a smaller amount of volatile components than the short-time aged specimens.s.