• Corrosion Science and Technology
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• 제22권5호
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• pp.330-340
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• 2023

The objective of this study was to analyze effects of aging time on property degradation of super austenitic stainless steel of PRE 52.8 and super duplex stainless steel of PRE 48.7. To analyze corrosion properties based on aging time, a critical pitting temperature test was performed in a solution of 6% FeCl₃ + 1% HCl and an anodic polarization test was performed in deaerated 0.5N HCl + 1N NaCl solution at a temperature of 50 ℃. Surface hardness was measured to analyze mechanical properties. It was found that corrosion properties and mechanical properties deteriorated rapidly as aging time increased. Critical pitting temperature had the most effect on critical aging time at which property changes occurred rapidly, followed by pitting potential and hardness. This trend was found to be closely related to the fraction of sigma phase. Rate of sigma phase formation was found to be significantly faster in duplex stainless steel than in austenitic stainless steel.

• 대한기계학회논문집A
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• 제26권11호
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• pp.2322-2327
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• 2002

The corrosion degradation characteristics of the 12Cr alloy steel, which is widely used in fossil power plants as a turbine blade material, are evaluated nondestructively by use of the backward radiated Rayleigh surface wave. In order to evaluate corrosion degradation characteristics, we constructed automated system for the backward radiation, and the frequency dependency of the Rayleigh surface wave is investigated indirectly by measuring the angular dependency of the backward radiation of the incident ultrasonic wave in the specimens. The velocity of the surface wave decrease as the increase of the aging time in the backward radiation profile, which seems to result from the increase of the effective degrading layer thickness. And, amplitude of the surface wave increase as the aging time, which seems to result from the increase of the intergranular corrosion. The result observed in this study demonstrates high potential of the backward radiated ultrasound as a tool for the nondestructive evaluation of the corrosion degradation characteristics of the aged materials.

• 한국표면공학회지
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• 제23권2호
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• pp.30-38
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• 1990

For the purpose of suggesting the thermal resistant catalyst for automobile emission control, various catalysts, Pd-WO3 and PD-La2O3 systems, were charactrized before and after thermal aging. It was found that La2O3 formed amorphous surface compound on the support by strong metal-support interaction(SMSI). And by Temperature Programmed Desorption (TPD) expeiment, it was found that the distribution of acid site which is strong acid sites by adding the promoters. After thermal aging, it was observed that the acidity of Pd-WO3 system was decreased largely because of losing acid site by metal vaporization. On the other hand, there was pretty small change in the properties of matter of Pd-La2O3 system. Therefore, it could be considered that La2O3 formed heat resisting amorphous surface compound on the support by SMSI.

• 약학회지
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• 제35권4호
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• pp.277-282
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• 1991

Rheological, colloidal and micromeritical properties were followed to investigate aging mechanisms of hydrous aluminum oxide suspension using Zeta-meter systems, BET adsorption apparatus, Master sizer and electronmicroscope. The results indicate that hydrous aluminum oxide suspension revealed plastic flow with thixotropy. The viscosity, thixotropy and yield value were increased with increasing concentration. During aging process, the viscosity and thixotropic index were increased by an addition of glycerin, however, sorbitol stabilized aging process of the suspension being accompanied with growth of particle size and reduction in specific surface area, pore area and pore volume, and consistency. Diminution of adsorptive power of the particles was also protected by addition of sorbitol to hydrous aluminum oxide suspension. From these results, one of aging mechanism of hydrous aluminum oxide suspension assumed growth and/or crystallization of colloidal particles in aqueous suspension.

• 대한전기학회:학술대회논문집
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• 대한전기학회 1994년도 하계학술대회 논문집 C
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• pp.1615-1618
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• 1994

This paper studied the streaming electrification of the U.H.V. transformer with the spinning cylinder system, and compared and analyzed it with the conventional forced flowing system which uses a pump or gas for oil flowing. Also, accumulated surface voltage in its electrified material was measured with the electrostatic voltmeter, and the effect of insulation oil aging was measured. As results, in spinning cylinder system, characteristics of the streaming electrification to its rotational speed and oil temperature are same tendency as those of tile forced flowing system and it showed the spinning cylinder system is useful to study the streaming electrification. And, aging of insulation oil increases the electricity of streaming electrification at initial stage of aging.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 1999년도 춘계학술대회 논문집
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• pp.214-217
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• 1999

Polymeric composite insulators have been in use for outdoor insulation. However, our knowledge about their long-term performance in a outdoor environment is still very limited. Especially, these insulator are subjected to the environmental stress such as ultraviolet radiation. Hence, in this paper. the influence of UV radiation on the aging of the shed materials was evaluated. For the aging evaluation, these insulators studied by experiment methods such as contact angle measurement. oxidation induced time. SEM/EDX, FTRI-ATR, tracking test for the different insulator samples. With the increased UV exposure time, samples are shown to exhibit degradation comparable to those of new ones

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2000년도 하계학술대회 논문집
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• pp.144-147
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• 2000

The effect of accelerated aging test on ethylene-propylene-diene monomer(EPDM) rubber used for outdoor insulation was studied by X-ray photoelectron spectroscopy(XPS), scanning electron microscope(SEM), FFT spectrum alalysis, and electrical pulse counts using PC by oscilloscope(300 MHz). In electrical alalysis, FFT spectrum analysis indicated arcing caused a significant increase in the third harmonic content of the leakage current of polluted insulator. Also, pulse counts increased as aging time. The surface oxygen and aluminum content were found to increase and that of carbon and nitrogen were found to decrease with time. The detailed XPS analysis indicated that the concentration of carbon in C-C decreased and concentration of highly oxidized carbons increased with time, which was due to the oxidation of EPDM rubber polymer SEM analysis indicated that crack and erosion of EPDM rubber occurred with time.

• 한국구조물진단유지관리공학회 논문집
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• 제3권3호
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• pp.157-165
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• 1999

The nondestructive testing methods are commonly used to determine the in-situ compressive strength of concrete. The correlation curves to evaluate the effect of aging on the development of concrete strength was proposed. Thirty two ${\Phi}10{\times}20cm$ cylinder specimens were cast from 5 batches having different strength levels. The correlation curves for rebound hammer method, ultrasonic pulse velocity method and combined method were derived from the laboratory tests and multiple regression analysis. To account for the change of condition such as surface hardness, internal moisture contents, the aging coefficients are applied to the correlation curves. From the comparison the nondestructive strength with the core strength taken from the existing reinforced concrete structures, the validity of the proposed correlation curves are verified.

• 폴리머
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• 제29권1호
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• pp.96-101
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• 2005

PTFE 및 PFA 등의 불소수지는 최대 연속 사용 온도가 260$^{\circ}C$에 달하는 고온 내열성 고분자 소재로서, 본 연구에서 수행된 280 $^{\circ}C$, 7주 간의 열노화에 의해서도 충분한 열적 안정성이 유지됨을 관측하였다. 그러나 기계적 강도, 융점 및 열분해 개시 온도 등의 소재적 물성이 유지됨을 의미하는 상기한 열적 안정성은 본 연구에서 수행된 코팅막으로서의 표면접촉각, 미세 모폴로지, 내스크래치성 분석에 의한 방법을 기준하면 충분하지 못하다는 것이 확인 되었다. 공기 치환율이 제어되는 기어식 노화시험기로 진행된 불소수지 코팅막의 280 $^{\circ}C$ 열노화에 대한 분석의 결과는 심각한 표면 모폴로지의 손상과 금속기재에 대한 접착력의 손실을 지적하고 있다.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 1998년도 가을 학술발표회 논문집(I)
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• pp.145-150
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• 1998

This study deals with the effect on performance of epoxy resign mortar mixed special cement for surface control and maintenance of aging concrete construction. The test of main property of epoxy resign in this study are the evaluation on the adhesive strength between substrate and epoxy resign mortar under the environment of wet or concrete substrate surface. We gained the test results of good adhesive strength over 15 kgf/$\textrm{cm}^2$ under the wet and dry condition of concrete surface.