• 접착 및 계면
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• 제20권2호
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• pp.71-75
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• 2019

탄닌산은 식물계에서 가장 많이 발견되는 폴리페놀 중 하나로, 초기 탄닌산 연구는 항산화제 등과 같은 생리학적 기능에 집중되어 있었다. 그러나 최근에는 탄닌산이 단백질, DNA 등 거의 모든 생체고분자와 분자간결합을 하는 것이 밝혀짐에 따라 분자적 접착제로서 많은 관심을 받고 있다. 탄닌산의 다양한 특성들은 표면의 기능, 젖음성을 조절할 뿐 아니라 에너지 저장 및 발생 장치에 기여하고, 의학적 제재로의 다양한 가능성을 보이고 있다. 본 논문에서는 분자적 접착제로서의 탄닌산과 생체고분자와의 결합, 탄닌산을 통한 표면 개질, 의료용 제재로의 활용 등에 대해 다루고자 한다.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2022년도 봄 학술논문 발표대회
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• pp.59-60
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• 2022

When a metal sprayed film of several hundred ㎛ on the concrete surface is possible to 80 dB of shielding effect electromagnetic waves (ElectroMagnetic Pulse, EMP). Therefore, in this study, as a way to secure EMP shielding performance by applying a metal spray coating showing excellent EMP shielding performance to a concrete structure, the metal spray welding efficiency and thin film adhesion performance according to the concrete spray direction and surface treatment method were evaluated. Metal sprayed efficieny according to the metal spraying direction and method was confirmed that the difference was insignificant by applying the roughening agent. However, the method of strengthening the concrete surface and applying the sealing agent show maximum adhesion strength of 3.98 MPa compared to other methods, and it is judged that this method can be utilized for the metal spraying method for concrete EMP shielding.

• Journal of the Korean Wood Science and Technology
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• 제34권3호
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• pp.38-45
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• 2006

본 연구의 목적은 왕겨분말을 NaOH와 acetic acid 처리를 통하여 왕겨분말-폴리프로필렌(PP) 바이오복합재의 계면 결합을 증가시키는 것이다. 처리하지 않은 왕겨분말, NaOH와 acetic acid 처리된 왕겨분말을 충전제로 사용하여 바이오복합재를 제조한 후 왕겨분말의 처리에 대한 효과를 조사하였다. NaOH와 acetic acid 처리된 왕겨분말이 충전된 바이오복합재의 인장강도가 처리하지 않은 왕겨분말이 충전된 바이오복합재보다 증가하였다. NaOH와 acetic acid로 처리 전후의 왕겨분말 표면은 scanning electron microscopy (SEM)의 사진으로 명확하게 관찰할 수 있었다. SEM을 이용하여 측정한 결과 왕겨분말 표면의 이물질이 제거된 것을 발견 할 수 있었다. NaOH와 acetic acid 처리된 왕겨분말의 화학적 구조는 fourier transform infrared (FTIR)을 이용하여 분석하였다. 처리하지 않은 왕겨분말, NaOH와 acetic acid로 처리된 왕겨분말의 결정화구조 및 결정화도는 wide-angle X-ray scattering (WAXS)을 이용하여 분석하였다.

• 한국염색가공학회지
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• 제30권2호
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• pp.77-89
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• 2018

In the case of fiber/rubber composites for tire applications, the interfacial adhesion between fiber and rubber significantly affects the physical properties of the finished products. Generally, organic synthetic fibers used for tire cords are treated with resorcinol formaldehyde latex(RFL) primer on the surface of the fiber to improve the adhesion to rubber. Changes of adhesion between rubber and tire cords might weaken as temperature rises due to overheating of car engine and friction with road. In this study, the effects of temperature on the primer treated polyketone cord/rubber composites and the changes in interfacial adhesion were investigated. Polyketone cord/rubber composites were prepared after RFL solution treatment on the surface of polyketone fibers. After that, composites was thermally aged at different temperature conditions(60, 80, 100, $120^{\circ}C$) and times(1, 5, 10, 15days). The adhesion strength of polyketone cord/rubber composite treated with RFL primer was higher than untreated composite by more than 3 times. After heat aging, the adhesion strength of untreated polyketone cord/rubber composites increased while the RFL treated polyketone cord/rubber composites decreased somewhat.

• International Journal of Precision Engineering and Manufacturing-Green Technology
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• 제5권5호
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• pp.583-591
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• 2018

Tool-chip adhesion impacts on cutting performance significantly, especially in finish cutting process. To promote cutting tools' anti-adhesion property, the concave micro-grooves texture (MGT) and convex volcano-like texture (VLT) were fabricated separately on lathe tools' rake faces by laser surface texturing (LST). Various orientations of MGT and different area densities (9% and 48%) and regions (partial and full) of VLT were considered in textured patterns designing. The following orthogonal cutting experiments, machining of aluminum alloy 5038, analyzed tools' performances including cutting force, cutting stability, chip shape, rake face adhesion and abrasion. It indicated that under dry finish cutting conditions, MGT contributed to cutting stability and low cutting forces, meanwhile friction and normal force reduced by around 15% and 10%, respectively with a weak correlation to the grooves' orientation. High density VLT tools, on the other hand, presented an obvious anti-adhesion property. A $5{\mu}m$ reduction of crater wear's depth can be observed on textured rake faces after long length cutting and textured rake faces presented half size of BUE regions comparing to the flat tool, however, once the texture morphologies were filled or worn, the anti-adhesion effect could be invalid. The bearing ratio curve was employed to analysis tool-chip contact and durability of textured surfaces contributing to a better understanding of anti-adhesion and enhanced durability of the textured tools.

• Journal of Microbiology and Biotechnology
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• 제25권6호
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• pp.771-781
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• 2015

To examine if the molecular chaperone DnaK operon proteins of Streptococcus suis type 2 (SS2) are involved in adhesion to host cells, the abundance values of these proteins from the surface of two SS2 strains of different adhesion capability were compared. Their roles in growth and adhesion to human laryngeal epithelial cell line HEp-2 cells were investigated on SS2 strain HA9801 and its mutants with DnaK operon genes partially knocked-out (PKO mutant) under heat stress. The major difference was that DnaJ was more abundant in strain HA9801 than in strain JX0811. Pretreatment of the bacteria with hyperimmune sera to DnaJ, but not with those to other proteins, could significantly reduce SS2 adhesion to HEp-2 cells. PKO of dnaJ g ene resulted in decreased SS2 growth at 37℃ and 42℃, and reduced its adhesion to HEp-2 cells. The wild-type strain stressed at 42℃ had increased expression of DnaJ on its surface and elevated adhesion to HEp-2 cells, which was also inhibitable by DnaJ specific antiserum. These results indicate that the DnaJ of S. suis type 2 is important not only for thermotolerance but also for adhesion to host cells. Because DnaJ expression is increased upon temperature upshift with increased exposure on the bacterial surface, the febrile conditions of the cases with systemic infections might help facilitate bacterial adhesion to host cells. DnaJ could be one of the potential candidates as a subunit vaccine because of its good immunogenicity.

• 한국정밀공학회:학술대회논문집
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• 한국정밀공학회 2006년도 춘계학술대회 논문집
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• pp.203-204
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• 2006

Studies on some biodegradable polymers and other materials such as hydrogels have shown the promising potential for a variety of surgical applications. Postoperative adhesion caused by the natural consequence of surgical wound healing results in problems of the repeated surgery. Recently, scientists have developed absorbable anti-adhesion barriers that can protect a tissue from adhesion in case they are in use; however, they are dissolved when no longer needed. Although these approaches have been attempted to fulfill the criteria for adhesion prevention, none can perfectly prevent adhesions in all situations. Overall of this work, a new method to fabricate an anti-adhesion membrane using biodegradable polymer and hydrogel has been developed. The ideal barrier for preventing postoperative adhesion would have the following properties; it should be (i) resorbable (ii) non-reactive (iii) easy to apply (iv) capable of being fixed in position. In order to fulfill these properties, we adopted solid freeform fabrication method combined with surface modification which includes the hydrogel coating, therefore, inner or outer structure can be controlled and the property of anti adhesion can be improved.

• 약학회지
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• 제53권3호
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• pp.119-124
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• 2009

Cell-cell adhesion managed by various adhesion molecules plays an important role in regulating functional activation of cells. This event mediates attachment of inflammatory cells to endothelial cells, interaction of antigen-presenting cells with T cells and metastatic adherence of cancer cells to epithelial tissue cells. Therefore, this cellular response is considered as one of therapeutic target to treat various cancers and inflammatory diseases. To develop proper model for evaluation of functional activation of adhesion molecules, the ability of U937 and Jurkat T cells responsive to various adhesion inducers such as phorbal-12-myristate-13-acetate (PMA), staurosporin and monoclonal antibodies to CD29, CD43 and CD98 was investigated using quantitative cell-cell adhesion assay. U937 cells made more cell-cell clusters by the treatment of antibodies to CD29 and CD43 than Jurkat T cells, while Jurkat T cells exhibited increased cell-cell adhesion ability in CD98 antibody treatment. In agreement, the surface levels of CD29 and CD98 were highly observed in U937 and Jurkat T cells, respectively. Therefore, our data suggest that Jurkat T and U937 cells can be used for model system to evaluate functional activation of adhesion molecules such as CD29 and CD98.

• Elastomers and Composites
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• 제54권4호
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• pp.299-307
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• 2019

Rubber friction properties include adhesion friction characteristics of the interface, hysteresis friction characteristics originating from repeated rubber deformations, and cohesion friction characteristics due to wear and tear. Cohesion friction is generally sufficiently small (< 3%) that it can be ignored, whereas adhesion friction has a relatively large contribution of 15%, but has not been investigated thoroughly. Therefore, through an adhesion friction study, the adhesion mechanism was examined and the relationship between friction characteristics and adhesion friction on dry surfaces was derived. The wet grip characteristics of tread rubber are fully described by the hysteresis characteristics of tires, but friction characteristics on dry roads are difficult to determine without adhesion factors. The results presented herein demonstrate that the combination of hysteresis and adhesion properties in the tread rubber sufficiently explained the characteristics of the dry grip. Based on the results of this study, technologies will be developed to determine the key factors governing adhesion friction characteristics and improve dry tire braking performance.

• 한국재료학회:학술대회논문집
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• 한국재료학회 2009년도 추계학술발표대회
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• pp.39.1-39.1
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• 2009

NiTi alloy is widely used innumerous biomedical applications (orthodontics, cardiovascular, orthopaedics, etc.) for its distinctive thermomechanical and mechanical properties such as shape memory effect, super elasticity, low elastic modulus and high damping capacity. However, NiTi alloy is still a controversial biomaterial because of its high Ni content which can trigger the risk of allergy and adverse reactions when Ni ion releases into the human body. In order to improve the corrosion resistance of the TiNi alloy and suppress the release of Ni ions, many surface modification techniques have been employed in previous literature such as thermal oxidation, laser surface treatment, sol-gel method, anodic oxidation and electrochemical methods. In this paper, the NiTi was electrochemically etched in various electrolytes to modify surface. The microstructure, element distribution, phase composition and roughness of the surface were investigatedby scanning electron microscopy (SEM), energy-dispersive X-ray spectrometry(EDS), X-ray diffractometry (XRD) and atomic force microscopy (AFM). Systematic controlling of nano and submicron surface features was achieved by altered density of hydro fluidic acid in etchant solution. Nanoscale surface topography, such as, pore density, pore width, pore height, surface roughness and surface tension were extensively analyzed as systematical variables.Importantly, bone forming cell, osteoblast adhesion was increased in high density of hydro fluidic treated surface structures, i.e., in greater nanoscale surface roughness and in high surface areas through increasing pore densities.All results delineate the importance of surface topography parameter (pores) inNiTi to increase the biocompatibility of NiTi in identical chemistry which is crucial factor for determining biomaterials.