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Effect of Thermal Aging on the Change of Interfacial Adhesion between Polyketone Cord and Rubber by RFL Primer Treatment

RFL 프라이머 처리에 따른 폴리케톤 코드사와 고무 간의 계면접착성 변화에 열노화가 미치는 영향

  • Jo, Hani (Department of Advanced Organic Materials and Textile System Engineering, Chungnam National University) ;
  • Oh, Woo Jin (Department of Advanced Organic Materials and Textile System Engineering, Chungnam National University) ;
  • Kang, Song Hee (Department of Advanced Organic Materials and Textile System Engineering, Chungnam National University) ;
  • Lee, Seung Goo (Department of Advanced Organic Materials and Textile System Engineering, Chungnam National University)
  • 조하니 (충남대학교 유기소재.섬유시스템공학과) ;
  • 오우진 (충남대학교 유기소재.섬유시스템공학과) ;
  • 강송희 (충남대학교 유기소재.섬유시스템공학과) ;
  • 이승구 (충남대학교 유기소재.섬유시스템공학과)
  • Received : 2018.03.29
  • Accepted : 2018.05.15
  • Published : 2018.06.27

Abstract

In the case of fiber/rubber composites for tire applications, the interfacial adhesion between fiber and rubber significantly affects the physical properties of the finished products. Generally, organic synthetic fibers used for tire cords are treated with resorcinol formaldehyde latex(RFL) primer on the surface of the fiber to improve the adhesion to rubber. Changes of adhesion between rubber and tire cords might weaken as temperature rises due to overheating of car engine and friction with road. In this study, the effects of temperature on the primer treated polyketone cord/rubber composites and the changes in interfacial adhesion were investigated. Polyketone cord/rubber composites were prepared after RFL solution treatment on the surface of polyketone fibers. After that, composites was thermally aged at different temperature conditions(60, 80, 100, $120^{\circ}C$) and times(1, 5, 10, 15days). The adhesion strength of polyketone cord/rubber composite treated with RFL primer was higher than untreated composite by more than 3 times. After heat aging, the adhesion strength of untreated polyketone cord/rubber composites increased while the RFL treated polyketone cord/rubber composites decreased somewhat.

Keywords

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