• 제목/요약/키워드: supercritical fluid

검색결과 391건 처리시간 0.037초

자유류 난류와 표면 트립 와이어가 구 주위 유동에 미치는 영향 (Effects of the Free-Stream Turbulence and Surface Trip Wire on the Flow past a Sphere)

  • 손광민;최진;전우평;최해천
    • 유체기계공업학회:학술대회논문집
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    • 유체기계공업학회 2006년 제4회 한국유체공학학술대회 논문집
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    • pp.187-190
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    • 2006
  • In the present study, effects of tree-stream turbulence and surface trip wire on the flow past a sphere at $Re\;=\;0.4\;{\times}\;10^5\;{\sim}\;2.8\;{\times}\;10^5$ are investigated through wind tunnel experiments. Various types of grids are installed upstream of the sphere in order to change the tree-stream turbulence intensity. In the case of surface trip wire, 0.5mm and 2mm trip wires are attached from $20^{\circ}\;{\sim}\;90^{\circ}$ at $10^{\circ}$ interval along the streamwise direction. To investigate the flow around a sphere, drag measurement using a load cell, surface-pressure measurement, surface visualization using oil-flow pattern and near-wall velocity measurement using an I-type hot-wire probe are conducted. In the variation of free-stream turbulence, the critical Reynolds number decreases and drag crisis occurs earlier with increasing turbulence intensity. With increasing Reynolds number, the laminar separation point moves downstream, but the reattachment point after laminar separation and the main separation point are fixed, resulting in constant drag coefficient at each free-stream turbulence intensity. At the supercritical regime, as Reynolds number is further increased, the separation bubble is regressed but the reattachment and the main separation points are fixed. In the case of surface trip wire directly disturbing the boundary layer flow, the critical Reynolds number decreases further with trip wire located more downstream. However, the drag coefficient after drag crisis remains constant irrespective of the trip location.

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Stability and antioxidant effect of rapeseed extract in oil-in-water emulsion

  • Zhang, Hua;Shin, Jung-Ah;Hong, Soon Taek;Lee, Ki-Teak
    • 농업과학연구
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    • 제43권2호
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    • pp.249-257
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    • 2016
  • In this study, rapeseed extracts were obtained by supercritical carbon dioxide fluid extraction of defatted rapeseed to evaluate the stability and antioxidant activity of an oil-in-water (O/W) emulsion system. The oil-in-water emulsions were prepared from stripped soybean oil with different concentrations (0.3, 0.4, 0.5, and 0.6%) of rapeseed extract as an emulsifier. Their emulsion stability was compared to that of emulsions prepared with the commercial emulsifier, Tween 20 (Polysorbate 20, 0.2%). After stripping the soybean oil, the total tocopherol content was reduced from 51.4 g/100 g to 1.1 g/100 g. Emulsion stability and oxidative stability of emulsions prepared with Tween 20 and rapeseed extract as emulsifiers were evaluated. For 30 days droplet sizes of emulsions containing rapeseed extract (0.4, 0.5, and 0.6%) were not significantly different (p > 0.05). Similar results were obtained for emulsion stability (ES) and Turbiscan analysis, suggesting that the addition of rapeseed extract increased emulsion stability. The addition of rapeseed extract at more than 0.4% resulted in an emulsion stability comparable to the addition of 0.2% Tween 20. The antioxidative ability of rapeseed extract increased with the amount added in the emulsion. Moreover, the addition of 0.6% rapeseed extract resulted in the lowest emulsion peroxide values (10.3 mEq/L) among all treatments. Therefore, according to the stability of its antioxidative and physical stability properties, rapeseed extract from super critical extraction could be successfully applied to the food and cosmetic industries.

증기터빈 1단 노즐의 조속현상이 터빈성능에 미치는 영향 (Effects of flow variation in the first stage nozzle on the performance of a partial arc admission in a steam turbine)

  • 윤인수;이태구;문승재;이재헌
    • 플랜트 저널
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    • 제4권3호
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    • pp.60-65
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    • 2008
  • Power plant industry has been developed at high-capacity, high-technology, and innovation. Steam turbine became the most useful equipment that dominate more than 50% of all the world electricity production. And developed new materials of the turbine blade and extended length of the turbine last blade brought reform in steam turbine performance upgrade. In this paper, when do partial load driving in high-capacity steam turbine, optimum driving method found whether there is something. In operating steam turbine, there is a lot of loss from secondary wake and throttle of the 1st stage nozzle by the biggest leading factor that load fluctuation affects in high-pressure steam turbine performance. Effect of internal efficiency by 1 stage nozzle is the biggest here, but here fluid flow and flow analysis were not yet examined closely definitely. So, Analyzed design data and acceptance performance test result to applying subcritical pressure drum type 560 MW, supercritical-pressure once through type 500 MW, and 800 MW steam turbines actually. In conclusion, at partial load driving, partial arc admission(PAA) is more efficient than full arc admission(FAA) efficiency. This is judged by because increase being proportional with gross energy of stream that is pressure - available energy if pressure of stream that is flowed in to the turbine increases, available energy becomes maximum and turbine efficiency improves. Therefore, turbine performance is that preview that first stage performance fell if decline is serious in partial load because first stage performance changes according to load.

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The antihyperlipidemic effect of alginate-free residue from sea tangle in hyperlipidemic rats

  • Yim, Mi-Jin;Lee, Jeong Min;Choi, Grace;Cho, Soon-Yeong;Lee, Dae-Sung
    • Fisheries and Aquatic Sciences
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    • 제22권11호
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    • pp.27.1-27.6
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    • 2019
  • Background: In order to assess the high value-added use of the alginate-free residue of sea tangle, an animal study was performed to evaluate the functional activities and key compounds present. In the animal study, sea tangle and the alginate-free residue demonstrated good anti-hyperlipidemic and anti-arteriosclerotic abilities. Results: The functional compounds in the alginate-free residue of the sea tangle were effectively extracted by supercritical fluid extraction (SFE). The optimum extraction temperature and pressure were 40 ℃ and 6500 psi (M1) in the SFE, a better method in comparison to the conditions of 70 ℃ and 4500 psi (M2), respectively. The anti-atherosclerotic effects of the alginate-free residue of sea tangle (M1, M2) were investigated in Sprague-Dawley rats treated with poloxamer 407, Triton WR 1339, corn oil, and a high-fat diet. The M1 fraction reduced the serum lipid levels with greater efficacy than the M2 fraction. In the hyperlipidemic rats, treatment with M1 decreased the serum triglyceride (TG), total cholesterol (TC), and low-density lipoprotein-cholesterol (LDL-C) levels when compared to the levels in normal rats. Conclusion: Our results demonstrated that the alginate-free residue of sea tangle reduces serum TC, TG, and LDL-C. These results suggest that the alginate-free residue of sea tangle contains physiologically active components, such as fucosterol, that may exert beneficial effects in the prevention of atherosclerosis.

Antiallergic Effect of Two Variants of Artemisia princeps Pampanini

  • Shin, Yong-Wook;Bae, Eun-Ah;Lee, Bo-Mi;Min, Sung-Won;Lee, Jin-Hee;Baek, Nam-In;Ryu, Su-No;Chung, Hae-Gon;Kim, Nam-Jae;Kim, Dong-Hyun
    • Natural Product Sciences
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    • 제12권2호
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    • pp.67-73
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    • 2006
  • Antiallergic activities of two variants of Artemisia princeps Pampanini SJ-1 (named as Sajabalssuk) and SS-1 (named as Sajuarissuk) cultivated in Ganghwado, which contain high content of eupatilin compared to those cultured by other places, were investigated to evaluate the possibility as inhibitors against allergic diseases. Ethanol and supercritical fluid extracts of SJ-1 and SS-1 inhibited the release of ${\beta}-hexosaminidase$ from RBL-2H3 cells, although their water extracts were inactive. These extracts potently inhibited lipopolysaccharide-induced NO production of RAW264.7. However, these extracts almost did not scavenge free radicals. Oral administration of these extracts to mice inhibited passive cutaneous anaphylaxis reaction induced by IgE, and acute dermatitis induced by 12-O-tetradecanoylphorbol-13-acetate. However, these extracts did not inhibit chronic dermatitis. Scratching behaviors, vascular permeability, and writhing syndromes were weakly inhibited by these extract at a dose of 50 mg/kg. Based on these findings, we believe that SJ-1 and SS-1 can improve IgE-induced allergic diseases such as rhinitis and asthma.

Polycaprolactone, 디클로로메탄, 이산화탄소로 구성된 3성분계 고압 상거동 측정 (High-Pressure Phase Behavior of Polycaprolactone, Carbon Dioxide, and Dichloromethane Ternary Mixture Systems)

  • 권정민;신헌용;김수현;김화용
    • Korean Chemical Engineering Research
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    • 제53권2호
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    • pp.193-198
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    • 2015
  • Polycaprolactone, Dichloromethane, 이산화탄소로 구성된 3성분계 고압 시스템의 상거동 측정 실험은 가변 부피 셀 장치를 이용해서 측정했다. 실험의 온도범위는 313.15 K에서 353.15 K, 압력은 약 300 bar까지 측정했으며 실험결과는 Polycaprolactone의 질량 분율이 1.0%, 2.0%, 3.0%일 때 온도와 이산화탄소/Dichloromethane의 질량 분율로 정리했다. 또한 실험 결과는 hybrid 상태방정식 (Peng-Robinson 상태방정식과 SAFT 상태방정식의 혼합형태) 을 이용하여 열역학적으로 검증하였으며, 혼합규칙은 반데르 발스의 단일 유체 혼합규칙을 사용했다. 이 다성분계 시스템에서 이원 상호 작용 파라미터 등, 각종 파라미터는 심플렉스 알고리즘을 통해 최적화했다.

합성가스로부터 탄화수소제조를 위한 피서트롭스 반응에 관한 촉매 종류 및 반응매체의 영향 (Effect of Catalyst Type and Reaction Medium on Fischer-Tropsch Synthesis for Production of Hydrocarbon from Syngas)

  • 김철웅;정순용;정광은;고재천;채호정;김태완;박현주;이상봉;한정식;정병훈
    • 한국추진공학회:학술대회논문집
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    • 한국추진공학회 2010년도 제35회 추계학술대회논문집
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    • pp.658-663
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    • 2010
  • 석유자원의 고갈에 따라 전 세계적으로 석유대체자원인 석탄, 천연가스 및 바이오매스로부터 합성 연료 및 화학물질을 제조하기 위한 피셔트롭스 반응에 관한 많은 연구가 이루어지고 있다. 일반적으로 이러한 피셔트롭스 반응은 주로 스케일 업이 비교적 용이한 고정층 반응기를 사용한 기상반응이 적용되고 있으나, 촉매 기공에서의 확산제어 및 왁스의 생성에 따른 촉매의 비활성화 등의 문제점에 기인하여 최근 들어 초임계 유체를 이용한 반응이 많이 연구되고 있다. 본 연구에서는 피셔트롭스 반응에 관한 담지 촉매 및 반응매체에 관한 좀 더 심도 있는 영향을 고찰하기 위해 다양한 담지촉매를 제조하여 피셔트롭스 반응에 관한 기상반응과 초임계 반응을 비교, 고찰하였다.

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추출법에 따른 참당귀의 부위별 정유성분 비교 (Comparison of Volatile Compounds in Plant Parts of Angelica gigas Nakai by Extracting Methods)

  • 임상현;박유화;함헌주;김희연;정햇님;김경희;안영섭
    • 한국약용작물학회지
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    • 제17권6호
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    • pp.427-433
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    • 2009
  • Volatile flavor compounds from the shoot and root of Angelica gigas Nakai were extracted by HE (Hydrodistillation extraction), SDE (Simultaneous steam distillation & extraction), and SFE (Supercritical fluid extraction system), and analyzed by GC-MS. The amount and the number of chemical components in essential oils from shoot and root by SFE was the higher than those by other extraction methods. Respectively, thirty one constituents were identified from the essential oil of the shoot and root by HE, twenty seven and twenty three constituents were identified from the essential oil of shoot and root by SDE, thirty one and forty five constituents were identified from the essential oil of shoot and root by SFE. The result showed large differences in extraction methods and in plant parts of Angelica gigas Nakai. Also, the bioactive compounds in root part was identified as nodakenin and decursinol (11.95% and 8.42%, respectively) by SFE. These results suggested that SFE was the best extraction method for the increasing of extraction yield, the determination of volatile components and the increasing of bioactive compounds in the shoot and root of Angelica gigas Nakai.

열화 밀랍지의 탈랍 및 강도보강 처리 안정성 평가 (Evaluation of Dewaxing and Strengthening Treatments for Stabilization of Aged Beeswax-treated Hanji)

  • 정혜영;고인희;남현주;최경화
    • 펄프종이기술
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    • 제45권6호
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    • pp.10-16
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    • 2013
  • This study aims to carry out the final evaluation on the deterioration stability of dewaxing and strengthening treatments devised to conserve and restore the beeswax-treated volumes of the Annals of the Joseon Dynasty. Thus, this study artificially deteriorated dewaxed Hanji, strengthened Hanji and beeswax-treated Hanji with optimized processing conditions applied, and comparatively analyzed the deterioration characteristics of each kind of Hanji. As a result of this study, it turned out that there was the loss of physical strength and the value of $L^*$ was increased and the values of $a^*$ and $b^*$ were decreased from removing beeswax after dewaxing by supercritical fluid extraction (SFE). Also deteriorated strength during dewaxing was reinforced by strengthening treatment with methylcellulose and it showed higher strength than beeswax-treated Hanji. From the evaluation on deterioration stability after dewaxing and strengthening, it turned out that deterioration stability of strengthened Hanji is the superior. Therefore, it is presumed that conservation of aged beeswax-treated Hanji can be improved and extended when dewaxing and strengthening are applied under optimum conditions.

Analytical Method for Dioxin and Organo-Chlorinated Compounds: (Ⅱ) Comparison and Extraction Methods of Dioxins from XAD-2 Adsorbent

  • 양정수;이성광;박영훈;이대운
    • Bulletin of the Korean Chemical Society
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    • 제20권6호
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    • pp.689-695
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    • 1999
  • Supercritical fluid extraction (SFE), ultrasonic extraction (USE), and accelerated solvent extraction (ASE) were compared with the well known Soxhlet extraction for the extraction of polychlorinated biphenyls (PCBs) and polychlorinated dibenzo-p-dioxins(PCDDs) from the XAD-2 resin which was used to adsorb PCDDs in the atmosphere. XAD-2 resin spiked with five PCDDs was chosen as a sample. The optimum conditions for the extraction of PCDDs by SFE were turned out to be the use of CO2 modified with 10% toluene at 100 ℃ and 350 atm, with 5 min static extraction followed by 20 min dynamic extraction. SFE gave a good extraction rate with good reproducibility for PCDDs ranging from 68 to 98%. The ultrasonic extraction of PCDDs from XAD-2 was investigated and compared with other extractions. A probe type method was compared with a bath type. Two extraction solvents, toluene and acetone were compared with their mixture. The use of their mixture in probe type, with 9 minutes of extraction time, was found to be the optimum condition. The average recovery of the five PCDDs for USE was 82-93%. Accelerated solvent extraction (ASE) with a liquid solvent, a new technique for sample preparation, was performed under elevated temperatures and pressures. The effect of tem-perature on the efficiency of ASE was investigated. The extraction time for a 10 g sample was less than 15 min, when the organic solvent was n-hexaneacetone mixture (1 : 1, v/v). Using ASE, the average recoveries of five PCDDs ranged from 90 to 103%. SFE, USE, and ASE were faster and less laborious than Soxhlet extraction. The former three methods required less solvent than Soxhlet extraction. SFE required no concentration of the solvent extracts. SFE and ASE failed to perform simultaneous parallel extractions because of instrumental limitations.