• 제목/요약/키워드: sulphide minerals

검색결과 14건 처리시간 0.021초

구리, 니켈, 코발트 혼합용액으로부터 침전법에 의한 구리의 분리 (Precipitation of Cu as the sulphide from Sulphate solution containing Cu, Ni and Co)

  • 박경호;정선희;박진태;남철우;김홍인
    • 자원리싸이클링
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    • 제14권6호
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    • pp.16-20
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    • 2005
  • 구리, 니켈 그리고 코발트를 함유한 용액으로부터 구리를 선택적으로 분리하기 위하여 $Na_{2}S$를 첨가하여 구리를 CuS로 침전시키는 연구를 행하였다. 구리의 침전율은 용액의 pH가 높을수록, 첨가한 $Na_{2}S$의 양이 많을수록,농도가 낮을수록, 반응온도와 반응시간이 증가할수록 증가하였다. pH 1, $20\%\;Na_{2}S$ 첨가량이 구리의 3 당량비, 온도 $25^{\circ}C$ 그리고 반응시간 30분에서 구리의 침전율은 $94.1\%$이었으며 니켈과 코발트도 각각 $4.3\%$$4.5\%$가 침전되었다. 즉 일부 니켈과 코발트 이온이 같이 공침되기 때문에 정량적으로 구리만을 침전, 분리하는 것은 가능하지 않았다.

해저열수광상 개발동향과 우리나라의 대응방안 (Strategies for Development of Seafloor Polymetallic Sulphides in Consideration of International Progress)

  • 박성욱;양희철;정현수
    • 한국해양학회지:바다
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    • 제13권3호
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    • pp.271-279
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    • 2008
  • 해저열수광상은 황화물 미네랄이 해저의 열수작용을 통해 형성된 광상을 의미하며 특히, 구리, 납, 아연, 금, 은 등의 금속이 다량 포함되어 있다. 현재 해저열수광상 개발분야의 선두주자는 노틸러스사이다. 노틸러스사는 파푸아뉴기니, 피지, 통가, 솔로몬제도, 뉴질랜드 등 남서태평양 도서국에 약 37만 $km^2$에 달하는 탐사권을 보유 또는 신청해 놓은 상태이다. 넵튠사 역시 뉴질랜드, 파푸아뉴기니, 마이크로네시아에서 27만 $km^2$가 넘는 면적의 탐사권을 취득하였다. 이들 두 광업회사는 2010년 세계 최초로 해저열수광상의 상업생산을 목표로 적극적인 활동을 전개하고 있다. 주변국가인 중국과 일본은 전략광물의 안정적 공급을 위하여 해저열수광상 탐사활동을 적극적으로 수행하고 있는 실정이다. 중국의 경우 중국대양협회를 통해 전 지구 대양을 대상으로 심해저자원개발을 위한 국가연구개발사업을 수행하고 있다. 일본의 경우 자국의 EEZ를 중심으로 해저열수광상 조사사업을 수행하고 있다. 이러한 국제적인 해저열수광상 개발동향을 고려하여 우리나라의 해저열수광상 개발을 위한 전략방향을 소관부처의 일원화와 법제도 정비, 사업추진주체 결정, 정부의 적극적 예산지원, 해저열수광상 개발을 위한 중장기 계획수립 등의 측면에서 제안하였다.

송광광산(松廣鑛山)의 지질광상(地質鑛床) (Geology and Ore deposits of Songgwang Mine)

  • 홍만섭
    • 자원환경지질
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    • 제2권3호
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    • pp.58-67
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    • 1969
  • Songgwang lead zinc mine is located in about 12km to the north-east of Jeonju City. Geology of the mine and its visinity is consisted of Jeonju series belonged to so-called Okcheon system, Seodaesan tuff formation, Silla series, and the quartz porphyry intruded into these formations. Jeonju series comprising 3 formations; that is, of Sadaeri, Sindong, and Girinbong. Jeonju series is generally distributed in southern part of the area, striking NNW, and diping NE $30^{\circ}$, or NW $30^{\circ}$. It is deformed to form synclinorium and anticlinorium plunging to the north with low angle. In the northern part of the area, Jeonju series was cut by Sinpeongri-fault of NEE direction near Sinpeongri. In the north side of the fault, it is overturned and shows NEE or NWW strikes and NW $60^{\circ}$ dips. At the west of Songgwangri, it is cut by 3 thrusts; the two are almost parallel each other, and the third oneis manifested by the fact that the lower black shale zone thrusted over the upper limestone. Songgwangri thrust, so named, is a post-mineral fault and its plane represents a premineral slip plane. Enrichment of are took place along the bedding plane or fissure parallel to it, as seen in adit No. 1 or No. 2 along the floor of the thrust, and along the sheared zone or the brecciated zone oblique to the plane near the thrust in crystalline limestone of Sindong formation as observed in the underground levels of inclined slope. Ore minerals are chiefly zincblende, galena, pyrrhotite, arsenopyrite, acompanied pyrite and chalcopyrite, and contain Au and Ag. In earlier stage of mineralization, the limestone was recrystalized, and sulphide minerals were enriched in the· permiable zone said above by pyrometasomatism, and in later stage the limestone was affected chloritization and sericitization. However hydrothermal replacement was weak, so that enrichment did not took place. It seems that minerallizing materials came up through the premineral slip plane and injected, and replaced the limestone in permiable zone said above with sulphide are minerals. Then Songgwangri thrust took place and, the lower black shale zone thrusted upon crystalline limestone.

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금풍광산(鑛山) 광물(鑛物)찌꺼기의 광물(鑛物)학적 특성(特性) 및 중금속(重金屬) 제거(除去) (Mineralogical Characteristics and Removal of Heavy Metals from Gum-poong Mine Tailings)

  • 차종문;박제현;강헌찬
    • 자원리싸이클링
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    • 제21권6호
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    • pp.51-57
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    • 2012
  • 본 연구의 목적은 금풍광산 광물찌꺼기 내 중금속의 광물학적 특성을 조사하고, 중금속 제거를 위한 부유선별 실험을 하였다. 광물학적 분석 결과, 휘동석, 유비철석, 황철석, 섬아연석, 방연석 등 황화광물이 존재하였다. 카드뮴과 다른 중금속(Cu, Pb, Zn)의 상관관계를 살펴보면 Cd는 Zn과 좋은 양의 상관관계를 가졌다. K.A.X.(Potassium Amyl Xanthate)와 Aerofloat 211을 포수제로 사용한 부유선별 실험 결과 광물찌꺼기 내 잔류 중금속(As, Cd, Cu, Pb, Zn)의 농도가 토양오염기준치를 만족하는 결과를 얻었다.

상동광상(上東鑛床)의 동위원소연구(同位元素硏究) (Stable Isotope Study on the Sangdong Deposit)

  • 문건주
    • 자원환경지질
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    • 제17권3호
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    • pp.171-177
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    • 1984
  • Representative sulphide samples from the Sangdong skarn orebody and quartz veins show relatively narrow ranges of sulphur isotope values ranging from $^+5.5$ to $^+6.9$ permil and average $^+5.0$ permil with a standard deviation of 0.77 permil. Much higher temperature isotopic temperatures than homogenization temperatures may indicate even minerals in contact did not form together in isotopic equilibrium. Under conditions of formation of the skarn and quartz veins, ${\delta}^{34}\;H_2S$ ranges from $^+4.5$ to $^+5.3$ permil, suggesting a magmatic origin for the sulphur. Carbon and oxygen isotope values seem to show some of the spread of increasing ${\delta}^{13}C$ values of the interbedded limestone with distance from the central zone of the Sangdong mineralization. Negative values of ${\delta}^{13}C$ fluids appear to be typical of many ore deposits including those of magmatic origin. Calculated ${\delta}^{18}C$ values of the fluids are typical of those derived from magmatic sources.

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Mineralogical studies and extraction of some valuable elements from sulfide deposits of Abu Gurdi area, South Eastern Desert, Egypt

  • Ibrahim A. Salem;Gaafar A. El Bahariya;Bothina T. El Dosuky;Eman F. Refaey;Ahmed H. Ibrahim;Amr B. ElDeeb
    • 분석과학
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    • 제37권1호
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    • pp.47-62
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    • 2024
  • Abu Gurdi area is located in the South-eastern Desert of Egypt which considered as volcanic massive sulfide deposits (VMS). The present work aims at investigating the ore mineralogy of Abu Gurdi region in addition to the effectiveness of the hydrometallurgical route for processing these ores using alkaline leaching for the extraction of Zn, Cu, and Pb in the presence of hydrogen peroxide, has been investigated. The factors affecting the efficiency of the alkaline leaching of the used ore including the reagent composition, reagent concentration, leaching temperature, leaching time, and Solid /Liquid ratio, have been investigated. It was noted that the sulfide mineralization consists mainly of chalcopyrite, sphalerite, pyrite, galena and bornite. Gold is detected as rare, disseminated crystals within the gangue minerals. Under supergene conditions, secondary copper minerals (covellite, malachite, chrysocolla and atacamite) were formed. The maximum dissolution efficiencies of Cu, Zn, and Pb at the optimum leaching conditions i.e., 250 g/L NaCO3 - NaHCO3 alkali concentration, for 3 hr., at 250 ℃, and 1/5 Solid/liquid (S/L) ratio, were 99.48 %, 96.70 % and 99.11 %, respectively. An apparent activation energy for Zn, Cu and Pb dissolution were 21.599, 21.779 and 23.761 kJ.mol-1, respectively, which were between those of a typical diffusion-controlled process and a chemical reaction-controlled process. Hence, the diffusion of the solid product layer contributed more than the chemical reaction to control the rate of the leaching process. High pure Cu(OH)2, Pb(OH)2, and ZnCl2 were obtained from the finally obtained leach liquor at the optimum leaching conditions by precipitation at different pH. Finally, highly pure Au metal was separated from the mineralized massive sulfide via using adsorption method.

삼광(三光) 금(金) 광상(鑛床)의 광화(鑛化) 온도(溫度) 및 근원(根源)에 관關(한) 연구(硏究) (Study on the Temperature and the Origin of Mineralization at the Samkwang Au Deposits)

  • 문건주
    • 자원환경지질
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    • 제19권1호
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    • pp.19-24
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    • 1986
  • The Samkwang mine is one of gold deposits distributed mainly in the southwestern province (Chungnam) of the Korean peninsula. Golds occur in quartz veins aged of $223{\pm}4MA$ according to K-Ar age dating from muscovite in a pegmatitic quartz vein. Quantz veins intrude Precambrian biotite-granite gneiss and mica schist of unknown age. Fluid inclusions in the quartz show a range of homogenization temperatures from 159 to $274^{\circ}C$. A calculated temperature from the isotopes of the galena-sphalerite pair is $375^{\circ}C$. Two phases-fluid inclusions homogenized either by liquid or vapor phase are frequently observed in specimens over $260^{\circ}C$, which may indicate the boiling of the fluids. Pressure of formation of the quartz veins inferred by the homogenization temperatures of liquid-$CO_2$ bearing fluid is 1kb. Based on these data, it is assumed that the temperature of the formation of the Samkwang mine may lie in between $350^{\circ}-230^{\circ}C$. ${\delta}^{34}S_{{\Sigma}s}$ values of sulphide minerals show narrow range of +2.1 to +4.6, and show a trend of enrichments of $^{34}S$ in the fluid from deep to the surface. ${\delta}^{34}S_{{\Sigma}s}$ in the fluid estimated is less than 3 permil, suggesting sulphur fluid originated from the magma.

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함안군북지구(咸安郡北地區)의 지질(地質)과 동광상(銅鑛床) (Geology and Ore Deposits in the Haman-Kunbuk Copper District)

  • 문정욱;김명환;이지헌;최충정
    • 자원환경지질
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    • 제3권2호
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    • pp.55-73
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    • 1970
  • The district investigated covers the central and southern portions of the Uiryong Quadrangle amounting to $40km^2$ in area and is bounded approximately by geographical coordinates of $128^{\circ}$ 28' $40^{{\prime}{\prime}}{\sim}128^{\circ}$ 24' 25"E in longitude and $35^{\circ}10{\prime}{\sim}35^{\circ}14^{\prime}06^{{\prime}{\prime}}N$ in latitude. The purpose of this investigation was to provide basic information in drawing up a comprehensive development plan of the copper ore deposits known to exist in the HamanKumbuk district with special emphasis given to the ascertainment of geological and paragenetic characteristics. The area consists chiefly of shale, sandy shale and chert, all belong to Kyongsang System of Cretaceous age. Intruded into these rocks are andesite, granodiorite, basic dikes, and acidic dikes. The mineralization which took place in the area, consists of mostly fissure-filling vein deposits, numbering several tens, with varying magnitudes. The fissures and shear zones created in rocks, such as chert and granodiorite, hosted the deposition of mineralizing vapors and/or hydrothermal solutions along their openings. The strike lengths of these veins vary from 50 to 600 meters in extension and 0.1 to 3 meters in width. Although the degree of fluctuation in width is great, it averages 0.3m. The stuctural patterns, which apparently affected the deposition of veins, are fissure patterns, trend NS to $N30^{\circ}W$, and steep-pitching tension fractures as well as normal fault pattern. Ore minerals associated with vein matters are primarily chalcopyrite and small amounts of scheelite, cobaltiferous arsenopyrite, and gold and silver intimately associated with sulphide minerals. Associated with these ore mineral are pyrite, pyrrhotite, magnetite, specularite and arsenopyrite. Gangue minerals noted are quartz, calcite, chlorite, tourmaline and hornblende. In terms of the compositions of associated minerals, the vein deposits in the district could be grouped under the following four categories: 1. Pyrrhoitite, Arsenopyrite, Gold and Silver Bearing Copper Vein (Type I) 2. Calcite-Scheelite-Copper Vein (Type II) 3. Magnetite-Pyrite-Copper Vein (Type III) 4. Tourmaline Copper Vein (Type IV) Of the four types, the first and the fourth are presently yielding relatively higher grades: of copper ores and concentrates. The estimated ore reserves total some 222,000 metric tons with the following breakdown in terms of metal contents: Name of Mines Au(g/t) Ag(g/t) Cu(%) Reserves(M/T) Kunbuk 15.92 78.69 6,074 60.498 Cheil Kunbuk - - 1.040 60,847 Haman - - 2.688 101,204 222,549 As rehabilitation of old workings and/or exploration of veins at depth proceed, additional estimation of ore reserves may become apparent and necessary. With regard to the problem of beneficiation and upgrading of low-grade ores in the district, it would be advisable to make decisions on location, treating capacity and mill flowsheet after sufficient amount of exploration is completed as suggested in the report.

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남한(南韓)의 형석광상(螢石鑛床)의 성인(成因)에 관(關)한 연구(硏究) (A Study on the Genesis of Fluorite Deposits of South Korea)

  • 지정만
    • 자원환경지질
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    • 제8권1호
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    • pp.25-56
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    • 1975
  • Most fluorite deposits of South Korea are distributed in three metallogenic zones namly as: Hwacheon, Hwangangni and Geumsan metallogenic zones. Fluorite deposits of each zone show The characteristic features owing to the geological setting, the structural patterns and their forming processes. deposits of the Hwacheon metallogenic zone are wholly fissure filling hydrothermal veins emThe bedded in shear fractures of the granite gneiss or schists of Precambrian age or in the cooling fractures of the granite and acidic hypabyssal rocks which are assumed to be a differentiated sister rock of the granite. Localization of most fluorite veins of the region is structurally controlled by NW and EW fracture systems and genetically related to the granite intrusion which ascertained as motivating rock of the fluorite mineralization. Fluorites are in most cases accompanied by quartz, chalcedony mainly and rarely agate, calcite, barite and sulphide base metals in some localities. The deposits of the Hwangangni metallogenic zone were formed at the last stage of hydrothermal polymineralization of W, Mo, Cu, Pb, Zn. The majority of the fluorite ore bodies were originated from replacement in limestone beds of Great Limestone Series or in calcareous interbeds of metasediments, whereas some cavity-filling ore bodies were embedded in phyllites and schists of the Ockcheon system and along the fissures in the replaced beds which were originated by volume decrease. The localization of fluorite deposits in this region is genetically related to the Moongyong granite which has been dated as middle Cretaceous, and controlled structurally by the $N20^{\circ}{\sim}50^{\circ}W$ extension fracture system or axial planes of folds, and by faults of NE direction that acted as paths of ore solution. The deposits of the Geumsan metallogenic zone are seemed to be formed through the similar process as that of Hwangangni metallogenic zone, but characteristic distinctions are in that they are more prevailing fracture filling veins and large number of the deposits are localized in roof-pendants or xenolithes of limestone in granites and porphyries. Igneous rocks that presumably motivated the mineraltzation are middle Cretaceous Geumsan granite and porphyries. Metallogenic epoch of the fluorite mineralization of South Korea are puesumably limited in early-middle Cretaceous. Studies of the fluid inclusions in fluorites of the region reveal that the homogenization temperature of the fluorite deposits are as follows: Hwacheon metallogenic zone : $95^{\circ}C{\sim}165^{\circ}C$; Hwangangni metallogenic zone : $97^{\circ}C{\sim}235^{\circ}C$; Geumsan metallogenic zone : $93^{\circ}C{\sim}236^{\circ}C$. Judging from the above results, the deposits of the Hwancheon region were formed at the epithermal stage, and those in the Hwangangni and Geumsan regions, were deposited at epithermal stage preceded by mesothermal mineralization of small scale in which some sulphide minerals were deposited. The analytical data of minor elements in the fluorites reveal that ore solutions of Hwangangni metallogenic zone seemed to be emanated in more acidic stage of magma differentiation than Hwacheon metallogenic zone did.

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