• Title/Summary/Keyword: sulfur oxides

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질산화가스와 아황산가스의 비를 이용한 대기오염 기여도 분석 (Analysis of Air Pollutant Sources Contribution by using Ratio of Sulfur Dioxide Gas to Nitrogen Oxides Gas)

  • Wan, Cha-Ju;Cheol, Choe-Byeong;Cheon, Choe-Jae
    • 한국대기환경학회:학술대회논문집
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    • 한국대기환경학회 2003년도 춘계학술대회 논문집
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    • pp.261-264
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    • 2003
  • We try to distribute air pollution sources at target area. The complex method is used to distribute air pollution sources. Most of people, However, want to simple indicator as standard for express air pollution source. In many area, air pollution is caused by different types of sources. The general type is point source, such as tall stack of power plants and oil refineries stacks. A second type is areal source, such as local industry and transportation. In this aspect, the ratio of sulfur dioxide to nitrogen oxides (RSN =SO$_2$/NOx)is an indicator of air pollution source. the role of this ratio is to show the characteristics at target area of the relationship the point and the areal source. (omitted)

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철강산업 용융로의 대기오염물질 배출계수 산정 연구 (A Study on the Emission Factors of Air Pollutants for the Melting Furnaces of the Iron and Steel Industry)

  • 석광설;방선애;홍지형;이석조;김대곤;이대균;허정숙;이은정
    • 한국대기환경학회지
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    • 제20권4호
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    • pp.571-578
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    • 2004
  • The purpose of this study is to estimate of emission factors of the air pollutants for the melting furnaces for the iron and steel industry. The result of this study is able to obtaine the emission factor of particulate matters (PM), sulfur dioxide. nitrogen oxides for melting furnace. The emission factors of each pollutants were as follows : - the emission factor varied between 6.13E-03~6.12E-01 kg/ton for PM -1.59E-01~2.45E+00kg/ton for $SO_2$ - 6.82E-02~6.88E-01 kg/ton for NOx, respectively. Analysis of the differences in the emission factors of ours and U.S. EPA's yielded the following results for the Wilcoxon method : p>0.05. The statistical analysis showed no differences in the our emission factors and U.S. EPA's

국내 무연탄 발전소 혼소율 변화에 따른 탈황 특성 연구

  • 김정유;박대영;이재헌;문승재
    • 한국전산유체공학회:학술대회논문집
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    • 한국전산유체공학회 2008년도 춘계학술대회논문집
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    • pp.84-87
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    • 2008
  • The sulfur oxides is one of important materials to come about air pollution at thermal plant consuming fossil fuel. The several flue gas desulfurization equipments are installed and operated to decrease sulfur oxides. The flue gas desulfurization of our thermal plant is designed for optimizing flue gas desulfurization technical development and research by Korea Electric Power Research Institute. We operate this desulfurization equipment. Now, our country imports nearly 97 percentage of the energy source and competes with the world for the energy because of the rise of raw materials cost. The fuel cost decrease of power plants is the most important factor of the operation. The fuel used in the experiment is the domestic anthracite from Kangwon Taeback and the bituminous coal from Russia,Taldinsky Mine. This Study is experimental investigations of desulfurization characteristics for domestic anthracite power plant by increasing bituminous coal. We surveyed possible parameters and conducted the performance about desulfurization equipment in Y.D thermal power plant.

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A Study on the Priority Analysis of Government Support Policies for SOx Emission of Ships

  • Yang, Han-Na;Lee, Gwang-Un;Shin, Chang-Hoon
    • 한국항해항만학회지
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    • 제43권2호
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    • pp.86-92
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    • 2019
  • IMO has enacted a convention that air pollution due to emissions of ships and sulfur oxides emissions should be significantly reduced by 2020. Based on the current support policies, this work intended to draw up the government support plans required by the shipping companies. Analytic Hierarchy Process analysis was done with factors derived from brainstorming and literature studies. The analysis results showed that the cost factor was generally the most important criterion and the Financial Aid was relatively more important within this cost factor. The policy implications for the regulation of sulfur oxides emissions was provided.

EMISSION CHARACTERISTICS IN ULTRA LOW SULFUR DIESEL

  • Oh, S.-K.;Baik, D.-S.;Han, Y.C.
    • International Journal of Automotive Technology
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    • 제4권2호
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    • pp.95-100
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    • 2003
  • Automobile industry has been developed rapidly as a key manufacturing industry in Korea. Meanwhile, air pollution is getting worse noticeably than ever. In the diesel emission, PM (Particulate Matter) and NOx (Nitrogen Oxides) have been exhausted with a great amount and the corresponding emission regulations are getting stringent. In order to develop low emission engines, it is necessary to research on better qualified fuels. Sulfur contained in fuel is transformed to sulfur compound by DOC (Diesel Oxidation Catalyst) and then it causes to the increase of sulfate-laden PM on the surface of catalyst. In this research, ULSD (Ultra Low Sulfur Diesel) is used as a fuel and some experimental results are investigated. ULSD can reduce not only PM but also gas materials because cetane value, flash point, distillation 90%, pour point and viscosity are improved in the process of desulfurization. However, excessively reduced sulfur may cause to decease lubricity of fuel and engine performance in fuel injection system. Therefore, it requires only modest adjusted amount of sulfur can improve engine performance and DOC, as well as decrease of emission.

우리나라 산림지역에서의 이산화황 농도의 시.공간적 분포 (Temporal and Spatial Distribution of Ambient Sulfur Dioxide Concentration in Forest Areas, Korea)

  • 이승우;이충화;지동훈;윤희정
    • 한국토양비료학회지
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    • 제43권6호
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    • pp.1035-1039
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    • 2010
  • 전국 65개 산림지역 조사지를 대상으로 장기확산형 패시브샘플러를 이용하여 1993년에서 2008년까지 월별 이산화황 ($SO_2$) 농도를 측정하고 도시지역과 비교하여 산림지역에서의 이산화황 농도의 시간적 및 공간적 분포 특성을 구명하였다. 산림 내 이산화황 ($SO_2$)의 연평균 농도는 관측 시작년도부터 점차 낮아지다가 1997년 이후에는 뚜렷한 변화가 없었으며, 이는 환경부의 도시지역의 연도별 농도 변화와도 같은 경향이었다. 조사기간 동안 전체 산림지역 조사지의 연평균 이산화황 농도는 5.6 ppb로 환경부의 도시지역 평균치 (10.1 ppb)와 EC (1999)의 생태적 위해 기준치 (7.6 ppb)에 비해 낮은 수준이었다. 계절별로는 산림지역과 도시지역 모두에서 난방 연료 사용량이 많은 겨울과 봄에 농도가 높았으며 강우와 고온의 영향이 큰 여름에 낮게 나타났다. 지역별로는 다른 지역에 비해 경북과 경기지역에서 이산화황 연평균 농도가 높게 나타났다. 황산화물 배출량과 이산화황 농도 간에 유의적인 정의 상관성이 나타남에 따라 황산화물 배출원의 규모와 근접성이 대기 중 이산화황의 농도를 결정짓는 중요한 인자임을 반영하였다.

Acidity in Precipitation and Solar North-South Asymmetry

  • Moon, Ga-Hee;Ha, Kyoung-Yoon;Kang, Seong-Hoon;Lee, Byoung-Ho;Kim, Ki-Beom;Kim, Jung-Hee;Chang, Heon-Young
    • Journal of Astronomy and Space Sciences
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    • 제31권4호
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    • pp.325-333
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    • 2014
  • We are motivated by both the accumulating evidence for the connection of solar variability to the chemistry of nitrogen oxide in the atmosphere and recent finding that the Galactic cosmic-ray (GCR) influx is associated with the solar north-south asymmetry. We have analyzed the measured pH in precipitation over the 109 stations distributed in the United States. We have found that data of pH in precipitation as a whole appear to be marginally anti-correlated with the solar asymmetry. That is, rain seems to become less acidic when the southern hemisphere of the Sun is more active. The acidity of rain is also found to be correlated with the atmospheric temperature, while not to be correlated with solar activity itself. We have carried on the analysis with two subsamples in which stations located in the east and in the west. We find that the pH data derived from the eastern stations which are possibly polluted by sulfur oxides and nitrogen oxides are not correlated with the solar asymmetry, but with the temperature. On the contrary, the pH data obtained from the western stations are found to be marginally anti-correlated with the solar asymmetry. In addition, the pH data obtained from the western stations are found to be correlated with the solar UV radiation. We conclude by briefly pointing out that a role of the solar asymmetry in the process of acidification of rain is to be further examined particularly when the level of pollution by sulfur oxides and nitrogen oxides is low.

Adsorptive Desulfurization of Diesel for Fuel Cell Applications: A Screening Test

  • Ho, Hoang Phuoc;Kim, Woo Hyeong;Lee, So-Yun;Son, Hong-Rok;Kim, Nak Hyeon;Kim, Jae-Kon;Park, Jo-Yong;Woo, Hee Chul
    • 청정기술
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    • 제20권1호
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    • pp.88-94
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    • 2014
  • 경유는 연료전지 시스템의 연료원으로써 주목받고 있는 탄화수소 액체연료 중 하나로, 연료개질 촉매와 연료전지의 전극재료를 피독시키는 황화합물을 포함하고 있어 탈황공정이 필요한 것으로 여겨지고 있다. 다양하고도 대안적인 탈황기술이 연구되고 있으나, 초저유황 경유의 탈황 연구는 여전히 부진한 실정이다. 본 연구는 용융탄산염 연료전지 시스템에 응용될 수 있는 원료인 상용초저유황 경유의 탈황에 관한 것이다. 여기서 초저유황의 흡착탈황을 위한 흡착제로 활성탄, 제올라이트, 금속산화물 계 상용흡착제 후보군이 선정되었고 유망한 탈황제를 찾기 위한 스크리닝 평가를 실시하였다. 그 결과 초저유황 경유의 황농도를 0.1 ppmw 수준까지 떨어뜨리기 위한 흡착제 종류로 금속산화물계가 매우 유용하며, 활성탄과 제올라이트 흡착제는 같은 실험조건에서 해당 수준의 황 농도에 이르지 못하는 것으로 나타났다.

Ca(OH)2촉매를 이용한 플라즈마 반응에 의한 황산화물(유해가스)의 제거에 관한 연구 (A study of decomposition of sulfur oxides(harmful gas) using calcium dihydroxide catalyst by plasma reactions)

  • 김다영;황명환;우인성
    • 대한안전경영과학회지
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    • 제16권2호
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    • pp.237-246
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    • 2014
  • Researches on the elimination of sulfur and nitrogen oxides with catalysts and absorbents reported many problems related with elimination efficiency and complex devices. In this study, decomposition efficiency of harmful gases was investigated. It was found that the efficiency rate can be increased by moving the harmful gases together with SPCP reactor and the catalysis reactor. Calcium hydroxide($Ca(OH)_2$), CaO, and $TiO_2$ were used as catalysts. Harmful air polluting gases such as $SO_2$ were measured for the analysis of decomposition efficiency, power consumption, and voltage according to changes to the process variables including frequency, concentration, electrode material, thickness of electrode, number of electrode winding, and additives to obtain optimal process conditions and the highest decomposition efficiency. The standard sample was sulfur oxide($SO_2$). Harmful gases were eliminated by moving them through the plasma generated in the SPCP reactor and the $Ca(OH)_2$ catalysis reactor. The elimination rate and products were analyzed with the gas analyzer (Ecom-AC,Germany), FT-IR(Nicolet, Magna-IR560), and GC-(Shimazu). The results of the experiment conducted to decompose and eliminate the harmful gas $SO_2$ with the $Ca(OH)_2$ catalysis reactor and SPCP reactor show 96% decomposition efficiency at the frequency of 10 kHz. The conductivity of the standard gas increased at the frequencies higher than 20 kHz. There was a partial flow of current along the surface. As a result, the decomposition efficiency decreased. The decomposition efficiency of harmful gas $SO_2$ by the $Ca(OH)_2$ catalysis reactor and SPCP reactor was 96.0% under 300 ppm concentration, 10 kHz frequency, and decomposition power of 20 W. It was 4% higher than the application of the SPCP reactor alone. The highest decomposition efficiency, 98.0% was achieved at the concentration of 100 ppm.