• Title/Summary/Keyword: sulfate resistance

Search Result 239, Processing Time 0.03 seconds

Application of Alkali-Activated Ternary Blended Cement in Manufacture of Ready-Mixed Concrete (알칼리 활성화 3성분계 혼합시멘트의 레미콘 적용 시험)

  • Yang, Wan-Hee;Hwang, Ji-Soon;Lee, Sea-Hyun
    • Journal of the Korea Institute of Building Construction
    • /
    • v.17 no.1
    • /
    • pp.47-54
    • /
    • 2017
  • Cement industry is typical carbon-emission industry. If the industrial by-products(granulated blast-furnace slag (GGBFS), fly ash, etc.) are used a large amount, it might be able to reduce cement consumption and mitigate carbon emissions. In this case, however, decrease of early strength is relatively large. Therefore, there is a limitation in increase of the amount of substitute. Considering these circumstances, it would be a good solution to reduce carbon emissions in cement industry to improve the performances of mixed cement through proper alkali-activation in Portland blended cement using GGBFS or fly ash. Therefore, this study prepared concrete in ready-mixed concrete manufacturing facilities with an addition of a binder which used 2.0% modified alkali sulfate activator after mixing Portland cement, GGBFS and fly ash in the ratio of 4:4:2 and assessed its basic properties. The results found the followings: The use of modified alkali-sulfate activator slightly reduced slump and shortened setting time. As a result, bleeding capacity decreased while early strength improved. In addition, there is no big difference in carbonation resistance. It appears that there should be continued experiments and analyses on the related long-term aged specimens.

Diversity of Bradyrhizobium japonicum with Different Colony Morphology in Intrinsic Antibiotic Resistance, Serological Property, and Protein Profile (콩 근류균(根瘤菌) Bradyrhizobium japonicum의 취락형태별(聚落形態別) 항생제(抗生劑) 반응(反應)과 혈청형(血淸型) 및 단백질전기영동(蛋白質電氣泳動) 유형(類型)의 다양성(多樣性))

  • Kang, Ui-Gum;Ha, Ho-Sung;Jung, Yeun-Tae;Kang, Hang-Won;Yun, Han-Dae;Ha, Yeong-Lae
    • Korean Journal of Soil Science and Fertilizer
    • /
    • v.29 no.1
    • /
    • pp.60-66
    • /
    • 1996
  • Bradyrhizobium japonicum with different colony morphology populated in five Yeongnam soils of Korea was examined for intrinsic antibiotic resistance to eight antibiotics, serological property by immunoblot and immunodiffusion, and protein profile differentiation by sodium dodecyl sulfate-polyacrylamide gel electrophoresis. Colony morphological distribution of one hundred and twenty B. japonicum isolates was 47% for "dry". 41% for "wet", and 12% for "dry/wet" type. The total isolates showed such a strong correlation between the morphology and antibiotic resistance. Colony morphology, which though was dominantly consisted of the same type within a serogroup, wasn't absolutely linked to serological property of B. japonicum. Based on these data, colony morphology was too simple to identify variations with B. japonicum isolates : antibiotic resistance such complicated compared with serological analyses.

  • PDF

Experimental Study to Evaluate the Durability of 100 MPa Class Ultra-high Strength Centrifugal Molding Concrete (100MPa급 초고강도 원심성형 콘크리트의 내구성 평가를 위한 실험연구)

  • Jeong-Hoi Kim;Sung-Jin Kim;Doo-Sung Lee
    • Journal of the Korea institute for structural maintenance and inspection
    • /
    • v.28 no.1
    • /
    • pp.12-23
    • /
    • 2024
  • In this study, a structural concrete square beam was developed using the centrifugal molding technique. In order to secure the bending stiffness of the cross section, the hollow rate of the cross section was set to 10% or less. Instead of using the current poor mixture of concrete and a concrete mixing ratio with a high slump (150-200) and a design strength of 100 MPa or more was developed and applied. In order to investigate the durability of centrifugally formed PSC square beams to be used as the superstructure of the avalanch tunnel or ramen bridge, the durability performance of ultra-high-strength centrifugally formed concrete with a compressive strength of 100 MPa was evaluated in terms of deterioration and chemical resistance properties.Concrete durability tests, including chloride penetration resistance, accelerated carbonation, sulfate erosion resistance, freeze-thaw resistance, and scaling resistance, were performed on centrifugally formed square beam test specimens produced in 2022 and 2023. Considering the information verified in this study, the durability of centrifugally molded concrete, which has increased watertightness in the later manufacturing stage, was found to be superior to that of general concrete.

EFFECT OF MAGNESIUM OXIDE CONTENTS ON THE PROPERTIES OF EXPERIMENTAL ALGINATES (산화마그네슘 함량이 실험적 알지네이트 인상재의 특성에 미치는 영향)

  • Bae Ill-Hwan;Woo Yi-Hyung;Choi Dae-Gyun
    • The Journal of Korean Academy of Prosthodontics
    • /
    • v.41 no.5
    • /
    • pp.551-564
    • /
    • 2003
  • Statement of problem : Magnesium oxide may increase pH of alginate, and supply magnesium ions to the polymerization reaction of alginate. Purpose : This study was designed to evaluate the influence of incorporation of magnesium oxide to alginate composition. Material and Method : Seven kinds of experimental alginates were prepared and used for the experiments. Components with unchanging concentrations were sodium alginate 15%, calcium sulfate 14%, sodium phosphate 2%, and zinc fluoride 3%. Contents of magnesium oxide were varied as 0%, 1%, 2%, 3%, 4%, 5%, 6%. Diatomaceous earth were added to each experimental groups as balance to be 100%. Control group was a MgO 0% group. Working time, setting time, elastic recovery strain in compression, compressive strength and tear resistance were measured were measured. Sample size for each groups were 10. Arithmetic means were used as each groups representative values. Regression test between MgO contents and results, Duncan's multiple range test, and One-way ANOVA test were done between groups at level of 0.05. Results : 1 Magnesium oxide made the working time and setting time as longer(p<0.0001). 2 Magnesium oxide did not alter the elastic recovery(p>0.05). 3. Magnesium oxide contents between 2% and 4% exhibited the lowest strain in compression on alginates(p<0.0001). 4. Magnesium oxide made the compressive strength and the tear resistance stronger(p<0.0001). Conclusion : These results mean that setting time of alginate maybe controlled and that mechanical properties maybe improved by the incorporation of magnesium oxide into alginate, without any reduction of elasticity.

Investigation of Ni/Cu Contact for Crystalline Silicon Solar Cells (결정질 실리콘 태양전지에 적용하기 위한 도금법으로 형성환 Ni/Cu 전극에 관한 연구)

  • Kim, Bum-Ho;Choi, Jun-Young;Lee, Eun-Joo;Lee, Soo-Hong
    • 한국신재생에너지학회:학술대회논문집
    • /
    • 2007.06a
    • /
    • pp.250-253
    • /
    • 2007
  • An evaporated Ti/Pd/Ag contact system is most widely used to make high-efficiency silicon solar cells, however, the system is not cost effective due to expensive materials and vacuum techniques. Commercial solar cells with screen-printed contacts formed by using Ag paste suffer from a low fill factor and a high shading loss because of high contact resistance and low aspect ratio. Low-cost Ni and Cu metal contacts have been formed by using electroless plating and electroplating techniques to replace the Ti/Pd/Ag and screen-printed Ag contacts. Ni/Cu alloy is plated on a silicon substrate by electro-deposition of the alloy from an acetate electrolyte solution, and nickel-silicide formation at the interface between the silicon and the nickel enhances stability and reduces the contact resistance. It was, therefore, found that nickel-silicide was suitable for high-efficiency solar cell applications. The Ni contact was formed on the front grid pattern by electroless plating followed by anneal ing at $380{\sim}400^{\circ}C$ for $15{\sim}30$ min at $N_{2}$ gas to allow formation of a nickel-silicide in a tube furnace or a rapid thermal processing(RTP) chamber because nickel is transformed to NiSi at $380{\sim}400^{\circ}C$. The Ni plating solution is composed of a mixture of $NiCl_{2}$ as a main nickel source. Cu was electroplated on the Ni layer by using a light induced plating method. The Cu electroplating solution was made up of a commercially available acid sulfate bath and additives to reduce the stress of the copper layer. The Ni/Cu contact was found to be well suited for high-efficiency solar cells and was successfully formed by using electroless plating and electroplating, which are more cost effective than vacuum evaporation. In this paper, we investigated low-cost Ni/Cu contact formation by electroless and electroplating for crystalline silicon solar cells.

  • PDF

Heterologous Transformation of Saccharomyces cerevisiae by Glucoamylase Gene of Saccharomyces diastaticus (Saccharomyces diastaticus Glucoamylase Gene에 의한 Saccharomyces cerevisiae의 Transformation)

  • Kim, Young-Ho;Jun, Do-Youn;Seu, Jung-Hwn
    • Microbiology and Biotechnology Letters
    • /
    • v.16 no.6
    • /
    • pp.489-493
    • /
    • 1988
  • To obtain a new yeast strain that is able to efficiently produce ethanol from starch, the glucoamylase gene of Saccharomyces diastaticus was transformed into S. cerevisiae without a cloning vector. The competent cells of S. cerevisiae, induced by the treatment of Li$_2$SO$_4$, were transformed with the partial BamHI-digests of chromosomal DNA of S. diastaticus, and the transformants were selected by their abilities to utilize and ferment starch. The transformants, which appeared at a frequency of 8.5$\times$10$^{-7}$, were able to withstand up to 800 ppm of copper sulfate like the recipient and retained the phenotypic expression of the recipient with the exception of the acquisition of STA gene and MAL gene, as regards fermentation of carbohydrates. The enzymatic properties of glucoamylases produced by transformants were very similar to those produced by S. diastaticus as based on optimium pH and temperature.

  • PDF

Effect of Au-ionic Doping Treatment on SWNT Flexible Transparent Conducting Films

  • Min, Hyeong-Seop;Jeong, Myeong-Seon;Choe, Won-Guk;Kim, Sang-Sik;Lee, Jeon-Guk
    • Proceedings of the Materials Research Society of Korea Conference
    • /
    • 2012.05a
    • /
    • pp.111.1-111.1
    • /
    • 2012
  • Interest in flexible transparent conducting films (TCFs) has been growing recently mainly due to the demand for electrodes incorporated in flexible or wearable displays in the future. Indium tin oxide (ITO) thin films, which have been traditionally used as the TCFs, have a serious obstacle in TCFs applications. SWNTs are the most appropriate materials for conductive films for displays due to their excellent high mechanical strength and electrical conductivity. In this work, the fabrication by the spraying process of transparent SWNT films and reduction of its sheet resistance on PET substrates is researched Arc-discharge SWNTs were dispersed in deionized water by adding sodium dodecyl sulfate (SDS) as surfactant and sonicated, followed by the centrifugation. The dispersed SWNT was spray-coated on PET substrate and dried on a hotplate. When the spray process was terminated, the TCF was immersed into deionized water to remove the surfactant and then it was dried on hotplate. The TCF film was then was doped with Au-ionic doping treatment, rinsed with deionized water and dried. The surface morphology of TCF was characterized by field emission scanning electron microscopy. The sheet resistance and optical transmission properties of the TCF were measured with a four-point probe method and a UV-visible spectrometry, respectively. This was confirmed and discussed on the XPS and UPS studies. We show that 87 ${\Omega}/{\Box}$ sheet resistances with 81% transmittance at the wavelength of 550nm. The changes in electrical and optical conductivity of SWNT film before and after Au-ionic doping treatments were discussed. The effect of Au-ion treatment on the electronic structure change of SWNT films was investigated by Raman and XPS.

  • PDF

Investigation of Plated Contact for Crystalline Silicon Solar Cells (결정질 실리콘 태양전지에 적용될 도금전극 특성 연구)

  • Kim, Bum-Ho;Choi, Jun-Young;Lee, Eun-Joo;Lee, Soo-Hong
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2007.06a
    • /
    • pp.192-193
    • /
    • 2007
  • An evaporated Ti/Pd/Ag contact system is most widely used to make high-efficiency silicon solar cells, however, the system is not cost effective due to expensive materials and vacuum techniques. Commercial solar cells with screen-printed contacts formed by using Ag paste suffer from a low fill factor and a high shading loss because of high contact resistance and low aspect ratio. Low-cost Ni and Cu metal contacts have been formed by using electro less plating and electroplating techniques to replace the Ti/Pd/Ag and screen-printed Ag contacts. Ni/Cu alloy is plated on a silicon substrate by electro-deposition of the alloy from an acetate electrolyte solution, and nickel-silicide formation at the interface between the silicon and the nickel enhances stability and reduces the contact resistance. It was, therefore, found that nickel-silicide was suitable for high-efficiency solar cell applications. Cu was electroplated on the Ni layer by using a light induced plating method. The Cu electroplating solution was made up of a commercially available acid sulfate bath and additives to reduce the stress of the copper layer. In this paper, we investigated low-cost Ni/Cu contact formation by electro less and electroplating for crystalline silicon solar cells.

  • PDF

Development of Acid Resistance Velocity Sensor for Analyzing Acidic Fluid Flow Characteristics (산성 용액 내 유속 측정을 위한 내산성 센서 개발)

  • Choi, Gyujin;Yoon, Jinwon;Yu, Sangseok
    • Transactions of the Korean Society of Mechanical Engineers B
    • /
    • v.40 no.10
    • /
    • pp.629-636
    • /
    • 2016
  • This study presents the development of an acid resistance velocity sensor that is used for measuring velocity inside a copper sulfate plating bath. First, researchers investigated the acid resistance coating to confirm the suitability of the anti-acid sensor in a very corrosive environment. Then, researchers applied signal processing methods to reduce noise and amplify the signal. Next, researchers applied a pressure-resistive sensor with an operation amplifier (Op Amp) and low-pass filter with high impedance to match the output voltage of a commercial flowmeter. Lastly, this study compared three low-pass filters (Bessel, Butterworth and Chebyshev) to select the appropriate signal process circuit. The results show 0.0128, 0.0023, and 5.06% of the mean square error, respectively. The Butterworth filter yielded more precise results when compared to a commercial flowmeter. The acid resistive sensor is capable of measuring velocities ranging from 2 to 6 m/s with a 2.7% margin of error.

Quality Evaluation of Basalt Aggregates from JEJU Island (제주산 현무암의 콘크리트용 골재 사용을 위한 품질 특성 평가)

  • Jang, Myung-Houn;Choi, Hee-Bok
    • Journal of the Korea Institute of Building Construction
    • /
    • v.13 no.5
    • /
    • pp.449-456
    • /
    • 2013
  • This study was carried out to assess the suitability in terms of the standards of material quality of basalt aggregates from JEJU Island as a source for concrete aggregate. Quality assessments on the basalt aggregates were performed to assess the soundness of coarse aggregates using sodium sulfate solution, aggregate crushing test, and Los Angeles abrasion test. In addition, XRD, XRF, porosity, and compressive and tensile strength tests were performed to analyze the chemical components and the mechanical properties. In general, the mechanical properties of basalt aggregates from some areas did not meet the Korea Standards (KS), but the levels of compressive and tensile strength were higher than those of granite, andesite, and sandstone of other regions.