• 제목/요약/키워드: sulfate corrosion

검색결과 104건 처리시간 0.024초

Deterioration of tensile behavior of concrete exposed to artificial acid rain environment

  • Fan, Y.F.;Hu, Z.Q.;Luan, H.Y.
    • Interaction and multiscale mechanics
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    • 제5권1호
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    • pp.41-56
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    • 2012
  • This study is focused on evaluation of the tensile properties of concrete exposed to acid rain environment. Acid rain environment was simulated by the mixture of sulfate and nitric acid in the laboratory. The dumbell-shaped concrete specimens were submerged in pure water and acid solution for accelerated conditioning. Weighing, tensile test, CT, SEM/EDS test and microanalysis were performed on the specimens. Tensile characteristics of the damaged concrete are obtained quantitatively. Evolution characteristics of the voids, micro cracks, chemical compounds, elemental distribution and contents in the concrete are examined. The deterioration mechanisms of concrete exposed to acid rain are well elucidated.

황환원 세균의 quorum-sensing 유사 현상

  • 박지은;장덕진
    • 한국생물공학회:학술대회논문집
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    • 한국생물공학회 2001년도 추계학술발표대회
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    • pp.545-548
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    • 2001
  • Microbiologically influenced corrosion (MIC) of metal is common in the natural environment and sulfate reducing bacteria are representative microorganisms for MIC. We found that biofilm fomlation by SRB on the metal surface might be controlled by quorum sensing, which is a cell density dependent regulation of cell metabolism. As cell free culture fluids (spent media) of Desulfovibrio vulgaris and D. desulfuricans were tested for quontrn sensing related test strains, it was found that spent media of two SRB induced increased luminescence of Vibrio harveyi BB886 (sensor 1+, sensor 2-) and BB170 (sensor 1-, sensor 2+). Quorum activities of D. vulgaris and D. desulfuricans appeared to be parallel to growth patterns, i.e., it was low in the lag phase, highly increased in the exponential phase, and reached maximum in the stationary phase. Interestingly, however, luminescence of V. harveyi BB886 and BB170 induced by a unit cell mass of the SHB showed a maximal peak in the late lag phase. Hence, it was suspected that quorum sensing of these two SHB play unknown roles in shifting cells from dormant to growth stages.

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2배농도 인공해수에 대한 시멘트모르터의 저항성 (The Resistance of Cement Mortar in Artificial Seawater)

  • 문한영;김진철;김홍삼;이승태
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 1998년도 봄 학술발표회논문집(II)
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    • pp.637-640
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    • 1998
  • Generally, the durability of the reinforced concrete structures reduce when they are constructed in marine environments. The Mg ions and sulfate ions in seawater cause chemical attacks in concrete and the cracks in concrete result from corrosion of steel due to chlorides. In this study, the mortar specimens made from 5 different types of cement were immersed in artificial seawater of 2 times concentration and then we measured the compressive strength, the length change and the weight change. As a result of this study, we found that the compressive strength ratio decreased in the immersed 56days. We also found the longer the immersed days were, the more the increase of weight ratio and the length change were.

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Application of Biotechnology to Wastewater Treatments in Japan

  • Mori, Tadahiro
    • 한국미생물생명공학회:학술대회논문집
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    • 한국미생물생명공학회 1986년도 추계학술대회
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    • pp.510.2-511
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    • 1986
  • The biotechnology including genetic engineering is expected to be applied to various fields of wastewater treatments in order to promote biological reaction rate, to grade up the effluent quality and to advance the stability of microorganisms against temperature, pH and toxic substances. The current topics in Japan on application of biotechnology to wastewater treatment will be reviewed at the beginning of the presentation. Next, the research of Biochemical Engineering Laboratory is to be presented, especially focused on the following subjects ; (1) Application of genetic engineering to the investiation of heavy metal uptake by the resistant bacteria of Hg Cd or Zn. (2) Relationship between sulfate reducing bacteria and wastewater treatment, offensive odor and corrosion of sewer tranks.

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Desalting System for Excavated Metal Objects Using High Temperature, High Pressure Deoxygenated Water

  • IMAZU, Setsuo;KOEZUKA, Takayasu
    • 보존과학회지
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    • 제5권2호
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    • pp.35-44
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    • 1996
  • We propose a new method to remove salts that have permeated into excavated metal objects. This method cleans the excavated metal objects by using high temperature, high pressure deoxvgenated water containing inhibitors for corrosion of metals. The method greatly reduces the washing time compared with previous methods. Waste water from the method does not need treatment, nor do chemicals need to be removed from the metal objects. Furthermore, this method is applicable to some kind of metals(for example iron objects, bronze objects). We measured quantitatively the soluble salts dissolved from actual metal objects and found that there was a large difference between soluble chloride ions and sulfate ions.

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삼성분계 시멘트를 사용한 콘크리트의 내구성 (Durability of Concrete Using Ternary Blended Cement)

  • 심은철;배수호;박광수;이준구;임병탁;하재담
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2003년도 가을 학술발표회 논문집
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    • pp.78-81
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    • 2003
  • Recently, physical properties of concrete containing ternary blended cement were actively researching to develop durability, mobility, and atc. as well as strength increase of concrete. In this study, durability of concrete such as the resistance against chloride ion penetration, rebar corrosion, freeze and thaw, and sulfate were researched for concrete containing ordinary portland cement(OPC) and ternary blended cement(TBC), respectively. For this purpose, concrete specimens containing OPC and TBC, respectively, were made for 37.5% of W/C, and then various durability experiments described above were carried out. As a result, it was observed from the test that concrete containing TBC showed excellent durability than concrete containing OPC.

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동적 나노압칩법을 이용한 수소유기균열분위기에서 생성된 X65-석유수소용 강관의 산화막 분석 (Analysis of Oxide Film on X65-Line Pile Steel Formed in Hydrogen Induced Cracking Environment by Dynamic Nano-indentation Method)

  • 오세범;강보경;이상헌;최용;김완근;고성웅;정환교;이창선
    • 한국표면공학회:학술대회논문집
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    • 한국표면공학회 2014년도 추계학술대회 논문집
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    • pp.155-155
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    • 2014
  • The oxide film was formed in hydrogen induced cracking (HIC) environment by potentio-dynamic method. Corrosion potentials and rates of the X-65 and X-80 line pipe steels were -0.3495 $V_{SHE}$, $2.833{\times}10^{-3}A/cm^2$ and 0.2716 $V_{SHE}$ and $2.533{\times}10^{-3}A/cm^2$, respectively. Surface composition analysis of the oxide film contained sulfur. Thermodynamic analysis of the HIC solution chemistry suggested that the oxide phase consisted of iron sulfate. Dynamic nano-indentation method applied to determine nano-hardnesses of the oxide film and base metal hardness.

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해양 콘크리트 구조물에서 에폭시 도막철근의 부착성능에 관한 연구 (An Experimental Study for the Bond Performance of the Epoxy-coated Reinforcement in Marine Concrete Structures)

  • 조병완;유태호
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 1996년도 가을 학술발표회 논문집
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    • pp.122-126
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    • 1996
  • In recent years, plenty of problems in the large-scaled bridges, piers…have been reported to the public due to the severe environment factors. The use of Epoxy-Coated reinforcement against salt and sulfate corrosion is considered as a reasonable solution and tested to study the bond performance between the thickness of coating and bond stresses. The results are that the strength of bond was decreased by 10 to 13 percent in the case of 100$\mu\textrm{m}$ of coating thickness and by 15 to 25 percent in the case of 200$\mu\textrm{m}$ to 300$\mu\textrm{m}$ and significantly fell down when the thickness was above 300$\mu\textrm{m}$. Accordingly, a 200$\mu\textrm{m}$ coating-thickness to the reinforcement is suggested to maintain the acceptable bond mechanism and goes well with the ASTM(item NO.A775) and those of Korean Concrete Institute.

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Degradation mechanisms of concrete subjected to combined environmental and mechanical actions: a review and perspective

  • Ye, Hailong;Jin, Nanguo
    • Computers and Concrete
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    • 제23권2호
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    • pp.107-119
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    • 2019
  • In-service reinforced concrete structures are simultaneously subjected to a combination of multi-deterioration environmental actions and mechanical loads. The combination of two or more deteriorative actions in environments can potentially accelerate the degradation and aging of concrete materials and structures. This paper reviews the coupling and synergistic mechanisms among various deteriorative driving forces (e.g. chloride salts- and carbonation-induced reinforcement corrosion, cyclic freeze-thaw action, alkali-silica reaction, and sulfate attack). In addition, the effects of mechanical loads on detrimental environmental factors are discussed, focusing on the transport properties and damage evolution in concrete. Recommendations for advancing current testing methods and predictive modeling on assessing the long-term durability of concrete with consideration of the coupling effects are provided.

금속 및 금속염계 항균제가 혼입된 항균 콘크리트 개발 (Development on Antibiotic Concrete Mixed with Antibacterial Metals and Metallic Salts)

  • 최홍식;허권;이호범;이시우;곽홍신
    • 한국건설순환자원학회논문집
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    • 제1권2호
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    • pp.136-143
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    • 2013
  • 하수시설 및 복개 구조물 등은 용해 시 산성으로 작용하는 황화수소에 크게 노출되어, 황산화균의 작용에 의해 강산성의 황산이온이 생성된다. 이에 따라 콘크리트의 생화학적 부식에 의한 열화가 촉진되며, 콘크리트 손상을 더욱 가속화하여 내구성이 크게 저하될 수 있다. 본 연구에서는 콘크리트에서 황산화균이 유기 생체적으로 사용하는 황화수소를 제거하기 위해, 금속의 살균성을 이용하여 금속 및 금속염 분말을 콘크리트에 혼입한 후, 황산화 억제 성능을 평가하였다. 이를 위해 중성화한 콘크리트 시편의 황산화균에 대한 항균 성능을 비교 평가하였고, 급속 염소이온 침투시험을 통해 금속 및 금속염계 항균제 첨가량에 따른 콘크리트 염화물 침투깊이 및 확산계수를 측정하였다. 또한 야외에서 폭로시킨 콘크리트 시편의 표면 상태의 생화학적 상태를 관측하여, 항균콘크리트의 성능 및 적용성을 확인하였다.