• Title/Summary/Keyword: substitution matrix

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Effect of n-type Dopants on CoSb3 Skutterudite Thermoelectrics Sintered by Spark Plasma Sintering (Spark Plasma Sintering 법으로 제조한 CoSb3 Skutterudite계 열전소재의 n형 첨가제 효과)

  • Lee, Jae-Ki;Choi, Soon-Mok;Lee, Hong-Lim;Seo, Won-Seon
    • Korean Journal of Materials Research
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    • v.20 no.6
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    • pp.326-330
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    • 2010
  • $CoSb_3$ Skutterudites materials have high potential for thermoelectric application at mid-temperature range because of their superior thermoelectric properties via control of charge carrier density and substitution of foreign atoms. Improvement of thermoelectric properties is expected for the ternary solid solution developed by substitution of foreign atoms having different valances into the $CoSb_3$ matrix. In this study, ternary solid solutions with a stoichiometry of $Co_{1-x}Ni_xSb_3$ x = 0.01, 0.05, 0.1, 0.2, $CoSb_{3-y}Te_y$, y = 0.1, 0.2, 0.3 were prepared by the Spark Plasma Sintering (SPS) system. Before the SPS synthesis, the ingots were synthesized by vacuum induction melting and followed by annealing. For phase analysis X-ray powder diffraction patterns were checked. All the samples were confirmed as single phase; however, with samples that were more doped than the solubility limit some secondary phases were detected. All the samples doped with Ni and Te atoms showed a negative Seebeck coefficient and their electrical conductivities increased with the doping amount up to the solubility limit. For the samples prepared by SPS the maximum value for dimensionless figure of merit reached 0.26, 0.42 for $Co_{0.9}Ni_{0.1}Sb_3$, $CoSb_{2.8}Te_{0.2}$ at 690 K, respectively. These results show that the SPS method is effective in this system and Ni/Te dopants are also effective for increasing thermoelectric properties of this system.

A Study on the U(VI), Ca(II) and Lu(III) Metal Ions Utilizing Nitrogen-Donator Synthetic Resin (질소-주게 합성수지를 이용한 U(VI), Ca(II) 및 Lu(III) 금속 이온들에 관한 연구)

  • 정만태
    • Journal of environmental and Sanitary engineering
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    • v.15 no.1
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    • pp.25-33
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    • 2000
  • The new ion exchange resin was synthesized from chloromethylated styrene-1,4-divinylbenzene(DVB) with 1-aza-15-crown-5 macrocyclic ligand by substitution reaction. The effect of pH, time, dielectric constant of solvent and cross-linked of the matrix on the adsorption for $UO_2^{2+}$, $Ca^{2}$ and $Lu^{3+}$ was investigated. The metal ion was not adsorbed on the resins below pH 3 but above pH 4 fast adsorption behavior was showed. The optimum equilibrium time for adsorption of metallic ions was two hours. The adsorption selectivity determined in ethanol matrix was in increasing order $UO_2^{2+}>Ca^{2}>Lu^{3+}$. The adsorption power was in the order of 1%, 2%, 10% and 20% -crosslinked resin, but adsorption properties of resins decreased in proportion to the order of dielectric constant of solvents used. In addition, these metal ions could be separated in the column packed with 1% crosslinked resin by pH2.5 $HNO_3$ as an eluent.

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Alveolar socket preservation with demineralised bovine bone mineral and a collagen matrix

  • Maiorana, Carlo;Poli, Pier Paolo;Deflorian, Matteo;Testori, Tiziano;Mandelli, Federico;Nagursky, Heiner;Vinci, Raffaele
    • Journal of Periodontal and Implant Science
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    • v.47 no.4
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    • pp.194-210
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    • 2017
  • Purpose: The aim of the present study was to evaluate the healing of post-extraction sockets following alveolar ridge preservation clinically, radiologically, and histologically. Methods: Overall, 7 extraction sockets in 7 patients were grafted with demineralised bovine bone mineral and covered with a porcine-derived non-crosslinked collagen matrix (CM). Soft tissue healing was clinically evaluated on the basis of a specific healing index. Horizontal and vertical ridge dimensional changes were assessed clinically and radiographically at baseline and 6 months after implant placement. For histological and histomorphometric analysis, bone biopsies were harvested from the augmented sites during implant surgery 6 months after the socket preservation procedure. Results: Clinically, healing proceeded uneventfully in all the sockets. A trend towards reduced horizontal and vertical socket dimensions was observed from baseline to the final examination. The mean width and height of resorption were 1.21 mm (P=0.005) and 0.46 mm (P=0.004), respectively. Histologically, residual xenograft particles ($31.97%{\pm}3.52%$) were surrounded by either newly formed bone ($16.02%{\pm}7.06%$) or connective tissue ($50.67%{\pm}8.42%$) without fibrous encapsulation. The CM underwent a physiological substitution process in favour of well-vascularised collagen-rich connective tissue. Conclusions: Socket preservation using demineralised bovine bone mineral in combination with CM provided stable dimensional changes of the alveolar ridge associated with good reepithelialisation of the soft tissues during a 6-month healing period.

Design and Implementation of FPGA Based Real-Time Adaptive Beamformer for AESA Radar Applications (능동위상배열 레이더 적용을 위한 FPGA 기반 실시간 적응 빔 형성기 설계 및 구현)

  • Kim, Dong-Hwan;Kim, Eun-Hee;Park, Jong-Heon;Kim, Seon-Joo
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.26 no.4
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    • pp.424-434
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    • 2015
  • Adaptive beamforming algorithms have been widely used to remove interference and jamming in the phased array radar system. Advances in the field programmable gate array(FPGA) technology now make possible the real time processing of adaptive beamforming (ABF) algorithm. In this paper, the FPGA based real-time implementation method of adaptive beamforming system(beamformer) in the pre-processor module for active electronically scanned array(AESA) radar is proposed. A compact FPGA-based adaptive beamformer is developed using commercial off the shelf(COTS) FPGA board with communication via OpenVPX(Virtual Path Cross-connect) backplane. This beamformer comprises a number of high speed complex processing including QR decomposition & back substitution for matrix inversion and complex vector/matrix calculations. The implemented result shows that the adaptive beamforming patterns through FPGA correspond with results of simulation through Matlab. And also confirms the possibility of application in AESA radar due to the real time processing of ABF algorithm through FPGA.

Mechanical Properties of Ternary Blended Cement Containing PAC (PAC을 포함한 삼성분계 시멘트의 역학적 특성)

  • Kim, Taewan;Cheung, Jin-Hwan;Kim, Seong-Do;Kim, In-Tae
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.8 no.2
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    • pp.245-253
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    • 2020
  • The present study is an experimental study to investigate the characteristics of strength by mixing polyaluminum chloride(PAC) with OPC-slag-FA ternary blended cement. There are three types of binders: 80% OPC + 10% slag + 10% FA, 60% OPC + 20% slag + 20% FA, and 40% OPC + 30% slag + 30% FA. PACs used 0, 2, 4, 6, 8, and 10% of the mixing-water weight. Experimental results show that PAC improves compressive strength regardless of the amount of OPC. PAC consumes portlandite, forms Friedel's salt, and reduces the diameter of the pores, making the matrix compact, contributing to the improvement of compressive strength. However, porous FA particles had an effect of delaying hydration by absorbing PAC in the initial hydration step. Therefore, the use of FA needs to determine the substitution rate in consideration of the hydration delay effect.

Microstructure and Magnetic Characteristics of Mn-doped Finemet Nanocomposites

  • Le, Anh-Tuan;Kim, Chong-Oh;Chau Nguyen;Tho Nguyen Duc;Hoa Nguyen Quang;Lee, Hee-Bok
    • Journal of Magnetics
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    • v.11 no.1
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    • pp.30-35
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    • 2006
  • A thorough study about the influences of Mn substitution for Fe on the microstructure and magnetic characteristics of $Fe_{73.5-x}Mn-{x}Si_{13.5}B_{9}Nb_{3}Cu_1$ (x = 1, 3, 5) alloys prepared by the melt-spinning technique has been performed. Nanocomposites composed of nanoscale $(Fe,Mn)_{3}Si$ magnetic phase embedded in an amorphous matrix were obtained by annealing their amorphous alloys at $535^{\circ}C$ for 1 hour. The addition of Mn causes a slight increase in the mean grain size. The Curie temperatures of the initial amorphous phase and of the nanocrystals phase decreased, while the Curie temperature of the remaining amorphous phase remained nearly constant with increasing Mn content. Soft magnetic properties of the crystallized samples have been significantly improved by a proper thermal treatment. Accordingly, the giant magnetoimpedance effect is observed and ascribed to the increase of the magnetic permeability, and the decrease of the coercivity of the samples. The increased magnetic permeability is resulted from a decrease in the magnetocrystalline anisotropy and saturation magnetostriction.

An Empirical Analysis on the Diffusion Impact of IT Technological Knowledge (정보통신 기술지식의 파급효과에 대한 실증분석)

  • 조형곤;박광만;이영용;박용태;김문수
    • Journal of Technology Innovation
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    • v.8 no.1
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    • pp.73-94
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    • 2000
  • The main objective of this research is to examine the spillover effects of technological knowledge from IT industry to other industrial sectors and, based on empirical findings, to draw policy implications and suggest policy directions. To this end, we divide IT industry into IT equipment and IT service, assuming that these two sub-sectors are considerably different each other in terms of technology knowledge flow. Other industries are classified into 17 different sectors based on the KSIC of 1990. As the proxy measure of technological knowledge, the notion of R&D stock is employed. The Input/output(I/O) Table is used to define the inter-industrial flow pattern and to draw the knowledge flow matrix. As the research methodology, cost function model is employed to gauge the spillover effects of technological knowledge of IT industry. Based on the results of analysis, it is found that the economic impact of technology diffusion also exhibits a different pattern between IT equipment and IT service. The diffusion of IT equipment tends to show labor-substitution effect whereas IT service displays labor-creation effect. This fact should be considered in devising industry, education, and labor policy. The expectations from this research are as follows. First, the sectoral pattern, difference between IT equipment and service in particular, identified from this research may shed light on the sector-specific policy direction. It is emphasized that a sector-specific approach, rather than an aggregate approach, is relevant for formulating IT policy. Second, it is expected that the importance of technology diffusion programs and policy measures are recognized among policy makers in IT industry.

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Diffusion Behaviors of B and P at the Interfaces of Si/$SiO_2$ Multilayer System After the Annealing Process

  • Jang, Jong-Shik;Kang, Hee-Jae;Hwang, Hyun-Hye;Kim, Kyung-Joong
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.08a
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    • pp.232-232
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    • 2012
  • The doping of semiconducting elements is essential for the development of silicon quantum dot (QD) solar cells. Especially the doping elements should be activated by substitution at the crystalline sites in the crystalline silicon QDs. However, no analysis technique has been developed for the analysis of the activated dopants in silicon QDs in $SiO_2$ matrix. Secondary ion mass spectrometry (SIMS) is a powerful technique for the in-depth analysis of solid materials and the impurities analysis of boron and phosphorus in semiconductor materials. For the study of diffusion behaviour of B and P by SIMS, Si/$SiO_2$ multilayer films doped by B or P were fabricated and annealed at high temperatures for the activated doping of B and P. The distributions of doping elements were analyzed by SIMS. Boron found to be preferentially distributed in Si layer rather than the $SiO_2$ layer. Especially the B in the Si layers was separated to two components of an interfacial component and a central one. The central component was understood as the activated elements. On the other hand, phosphorus did not show any preferred diffusion.

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A Study on the characteristics of the Signals of AE according to Fracture mode of CFRP under Tensile load (탄소섬유강화플라스틱(CFRP)의 인장하중하에서의 파괴거동에 따른 음향방출신호 특성에 관한 연구)

  • Lee, Kyung-Won;Lee, Sang-Yun;Nam, Jun-Young;Lee, Jong-Oh;Lee, Sang-Yul;Lee, Bo-Young
    • Journal of the Korean Society for Aviation and Aeronautics
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    • v.18 no.4
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    • pp.51-58
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    • 2010
  • Recently, aerospace structures have lightweight trend in order to reduce the cost of fuel and system, Carbon Fiber Reinforced Plastic (CFRP) can give the ability to reduce weight at 20~50% as the substitution of metal alloy, and there are advantages such as high Non-rigid, specific strength and anti-corrosion, but it is difficult to prove its destruction properties due to heterogeneous structure and anisotropy. In this study we designed specimen, inducing distinguishing destructions of material (for example, matrix crack, fiber breakage, and delamination) by using the Carbon Fiber Reinforced Plastic (CFRP) which is used in a real aircraft, to apply acoustic emission technique to aerospace structures. And we gained data via tensile testing and acoustic emission technique, from which each fault signal was classified respectively by using AE parameters and waveform.

A Study on The Relationship between TSC Properties and Structural Changes of Epoxy Composites Materials (에폭시 복합체의 TSC특성파 구조변화사이의 상관성 연구)

  • 왕종배;박준범;박경원;신철기;이준웅
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1993.11a
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    • pp.75-79
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    • 1993
  • The Thermally Stimulated Current(TSC) method has been allied to study the influence of the structural change and interface on the electrical properties of epoxy composites. Three DGBA- MeTHPA matrix model samples mixed different ratios arts silica(SiO$_2$) filled sample and silaln treating-filled sample have been studied. Above room temperature, the relaxation mode ${\alpha}$ peak associated with T$\_$g/ has been located at 110$^{\circ}C$. Below glass transition temperature(T$\_$g/), three relaxation modes are observed in all samples : a ${\beta}$ mode situated at 10$^{\circ}C$, a ${\gamma}$ mode located at -40$^{\circ}C$ and a $\delta$mode appeared in -120$^{\circ}C$, which may be due to segmental motion, side chains, substitution and terminal groups. The analysis of its fine structure indicates that constitution of elementary processes is characterized by the activation energy and relaxation time. Also the change of the molecular structure and their thermal motion are compared with the relaxation mode and conduction mechanism in TSC spectra through the dielectric properties and FTIR measurements.

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