• Title/Summary/Keyword: sub-solution

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Isolation and Characterization of Polysaccharides Purified from Brown Alga Sargassum horneri (괭생이모자반(Sargassum horneri)으로부터 추출한 다당의 이화학적 특성)

  • Koo, Jae-Geun;Jeong, Seongwoo
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.53 no.5
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    • pp.681-687
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    • 2020
  • Physicochemical properties of fucoidan and alginate extracted from Sargassium horneri were investigated. The alginates were extracted and purified via three different routes (CaCl2, HCl and ethanol routes), and their rheological properties at various concentrations and temperatures were determined. The yield of fucoidan was 3.08%, and it was mainly composed of fucose and galactose. Fourier-transform infrared spectrum of fucoidan showed strong absorption band at 1,254 and 827 cm-1 corresponding to the sulfate group. Flow behavior of the alginate solution was characterized using the power-law model. The consistency index increased with increasing concentrations. The sodium alginate solution (1.5%) exhibited Newtonian behavior when extracted via the CaCl2 and HCl routes, while it exhibited pseudoplastic behavior when extracted via the ethanol route. The effect of temperature on the flow behavior was investigated in terms of the activation energy (Ea), which was obtained using the Arrhenius equation. The Ea value corresponding to the alginate solution decreased with increasing shear rates. The Ea values corresponding to the alginate solutions purified via the CaCl2, HCl, and ethanol routes were 13.54-18.64 kJ/mol, 13.42-19.21 kJ/mol, and 9.51-10.67 kJ/mol, respectively. The low Ea values corresponding to the solutions extracted via the ethanol route suggest that the flow behavior does not depend significantly on temperature.

Self-patterning Technique of Photosensitive La0.5Sr0.5CoO3 Electrode on Ferroelectric Sr0.9Bi2.1Ta2O9 Thin Films

  • Lim, Jong-Chun;Lim, Tae-Young;Auh, Keun-Ho;Park, Won-Kyu;Kim, Byong-Ho
    • Journal of the Korean Ceramic Society
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    • v.41 no.1
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    • pp.13-18
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    • 2004
  • $La_{0.5}Sr_{0.5}CoO_3$ (LSCO) electrodes were prepared on ferroelectric $Sr_{0.9}Bi_{2.1}Ta_2O_9$(SBT) thin films by spin coating method using photosensitive sol-gel solution. Self-patterning technique of photosensitive sol-gel solution has advantages such as simple manufacturing process compared to photoresist/dry etching process. Lanthanum(III) 2-methoxyethoxide, Stronitium diethoxide. Cobalu(II)2-methoxyethoxide were used as starting materials for LSCO electrode. UV irradiation on LSCO thin films lead to decrease solubility by M-O-M bond formation and the solubility difference allows us to obtain self-patternine. There was little composition change of the LSCO thin films between before leaching and after leaching in 2-methoxyethanol. The lowest resistivity of LSCO thin films deposited on $SiO_2$/Si substrate was $1.1{\times}10^{-2}{\Omega}cm$ when the thin film was ennealed at $740^{\circ}C$. The values of Pr/Ps and 2Pr of LSCO/SBT/Pt capacitor on the applied voltage of 5V were 0.51, 8.89 ${\mu}C/cm^2$, respectively.

The Effects of a Solution Focused Group Counseling Program on the Peer Relation and School Life Adaption of Elementary school children (해결중심적 집단상담 프로그램이 초등학교 아동의 교우관계 및 학교생활 적응에 미치는 효과)

  • Hong, Sung-Mi
    • The Korean Journal of Elementary Counseling
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    • v.7 no.1
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    • pp.67-90
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    • 2008
  • The purpose of this study was to examine the effects of solution focused group counseling program on peer relationship and school life adaption of elementary school children. The subjects in this study were the 4th graders at S Elementary School in Ansan, Gyeonggi-do. 20 students were selected through the preliminary test of peer relationship and school life adaption, that is to say, each 10 students of experimental group and control group. A solution focused group counseling program was provided by researcher to the experimental group in six sessions once or twice a week, 60 minutes each. but control group was not conducted for any program. In verifying of the program effects in this study, KOREAN SPSS/WIN(version 12.0) is used for statistical analysis. The major findings of this study are as follows: First, solution focused group counseling program has a positive effect on all parts of sub-factors of peer relationship except to union life between friends. Second, solution focused group counseling program has a effect on the school life adaption of elementary and its all parts of sub-factors except to school rules. As noted above, it is proved that solution focused group counseling program has a positive effect to improve parts of sub-factors of peer relationship and school life adaption. Accordingly, it is necessary to feel satisfaction and Qualitative improvement in peer relationship and help school life adaptation of elementary school children through solution focused group counseling program.

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Fundamental Study on the CO2 fixation method using the Cement-saturated solution (시멘트 수용액을 이용한 CO2 고정화 방안에 관한 기초적 연구)

  • Kwack, Jae-Seok;Kang, Chang-Soo;Ahn, Hee-Sung;Lee, Han-Seung
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2011.11a
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    • pp.41-42
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    • 2011
  • The purpose of this study is not only fixation of carbon dioxide using the cement-saturated solution by wet carbonating reaction but also evaluate the possibility of storage technology of Carbon dioxide. wet carbonation is reaction of CO2 injection by CO2 reactor. As a result of experiment, the carbon dioxide is fixed, and high-purity Calcium Carbonate is eluted.

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Fundamental Study on the CO2 gas Fixation Method using the Cement-Paste Solution's Calcium ion (시멘트 페이스트 수용액의 칼슘 이온을 이용한 CO2 가스 고정화에 관한 기초적 연구)

  • Kwack, Jae-Seok;Kang, Chang-Soo;Lee, Han-Seung
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2012.05a
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    • pp.71-72
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    • 2012
  • The purpose of this study is not only fixation of carbon dioxide using the cement-Paste solution's calcium ion by wet carbonating reaction but also quantitatively evaluate the possibility of storage technology of Carbon dioxide. wet carbonation is reaction of CO2 injection by CO2 reactor. As a result of experiment, the carbon dioxide is fixed, and high-purity Calcium Carbonate is eluted.

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Effect of Dispersion Stability of Particles on Detergency of Particulate Soil(Part 1) - The Dispersion Stability of α-Fe2O3 Particles in the Nonyl Phenol Polyoxyethylene Ether Solution - (입자의 분산안정성이 고형오구의 세척성에 미치는 영향(제1보) - Nonyl Phenol Polyoxyethylene Ether 용액 내에서 α-Fe2O3 입자의 분산안정성 -)

  • Kang, In-Sook
    • Fashion & Textile Research Journal
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    • v.4 no.1
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    • pp.86-91
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    • 2002
  • To estimate dispersion stability of particles, suspending power and particle size were examined as functions of pHs, surfactants, electrolytes and ionic strengths using ${\alpha}-Fe_2O_3$ particle as the model of particulate soil. Suspending power and particle size were determined by UV-Vis spectrumeter and by light scattering using the polarization ratio method, respectively. The suspending power was relatively high with polyanion electrolytes and was low with neutral salts. The suspending power was biphasis, minimum pH 6~7, and the effect of surfactant on the suspending power was insignificant. Generally suspending power increased with decreasing the particle size governed aggregation of dispersed particles regardless of solution conditions. Hence the suspending power was inversely related to the particle size.

Development of a MEMS-based H2S Sensor with a High Detection Performance and Fast Response Time

  • Dong Geon Jung;Junyeop Lee;Dong Hyuk Jung;Won Oh Lee;Byeong Seo Park;Daewoong Jung
    • Journal of Sensor Science and Technology
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    • v.32 no.4
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    • pp.207-212
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    • 2023
  • H2S is a toxic and harmful gas, even at concentrations as low as hundreds of parts per million; thus, developing an H2S sensor with excellent performance in terms of high response, good selectivity, and fast response time is important. In this study, an H2S sensor with a high response and fast response time, consisting of a sensing material (SnO2), an electrode, a temperature sensor, and a micro-heater, was developed using micro-electro-mechanical system technology. The developed H2S sensor with a micro-heater (circular type) has excellent H2S detection performance at low H2S concentrations (0-10 ppm), with quick response time (<16 s) and recovery time (<65 s). Therefore, we expect that the developed H2S sensor will be considered a promising candidate for protecting workers and the general population and for responding to tightened regulations.

NOx-removal and Sound-absorption Performances of Photocatalytic Porous Concrete Prepared by Various TiO2 Application Methods (TiO2 적용방법에 따른 포러스 콘크리트의 질소산화물 제거성능 및 흡음특성)

  • Yoon, Hyunno;Seo, Joonho;Kim, Seonhyeok;Jang, Daeik;Bae, Jinho;Lee, Haeng-Ki
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.42 no.2
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    • pp.163-170
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    • 2022
  • The present study investigates NOx-removal and sound-absorption performances of photocatalytic porous concrete prepared by various TiO2 application methods. Photocatalytic porous concrete samples were prepared by one of the following: 1) mechanically mixing TiO2 during casting; 2) mixing bottom ash aggregate pretreated with TiO2 during casting; and 3) spraying TiO2 solution to the normally fabricated porous concrete. The test results indicated that the mechanical mixing of TiO2 decreased the compressive strength as the added TiO2 content increased. The use of pretreated bottom ash aggregate reduced the porosity, yet the compressive strength of the concrete was similar to that measured from the former method. Porous concrete samples sprayed with the TiO2 solution exhibited enhanced compressive strength, while the porosity was analogous to those measured from other methods. The NOx-removal performance was the highest in the samples sprayed with the TiO2 solution, followed by the samples using pretreated bottom ash aggregate and mechanically mixed TiO2. The samples with mechanically mixed TiO2 identified a relationship between soundabsorption performance and porosity. However, no particular tendency was observable in the samples with other TiO2 application methods.

Effect of Silicate Ions on the Hydration of 4CaO · Al2O3 · Fe2O3 with Gypsum

  • You, Kwang-Suk;Ahn, Ji-Whan;Kim, Hwan;Goto, Seishi
    • Journal of the Korean Ceramic Society
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    • v.41 no.9
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    • pp.642-646
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    • 2004
  • Na$_2$Si$_2$O$_{5}$ added to the solution affects the hydration of 4CaOㆍAl$_2$O$_3$ㆍFe$_2$O$_3$ with calcium sulfate. The reaction between 4CaOㆍAl$_2$O$_3$ Fe$_2$O$_3$and CaSO$_4$ㆍ 2$H_2O$ decrease with increasing amount of Na$_2$Si$_2$O$_{5}$ in solution, owing to low hydraulic reactivity of 4CaOㆍAl$_2$O$_3$ㆍFe$_2$O$_3$by the adsorption of silicate ions on the surface of 4CaOㆍAl$_2$O$_3$ㆍ Fe$_2$O$_3$ particles. The dissolution rate of 4CaOㆍAl$_2$O$_3$ㆍ Fe$_2$O$_3$ particles deceased with the increase of the concentration of silicate ion in solution. When the 4CaOㆍAl$_2$O$_3$ㆍFe$_2$O$_3$ particles was hydrated in gypsum - Na$_2$Si$_2$O$_{5}$ solution, the hydration was retarded and the rate could not discriminate between formation of ettringite and that of monosulfate, and it stopped in high concentration of silicate ions. However, silicate ion did not any effect on the dissolution rate of gypsum.ypsum.

Photocatalytic and Antipathogenic Effects of TiO2/CuxO (1 (TiO2/CuxO (1)

  • Cho, Sungwoo;Lee, Yong-Im;Kim, Lee-Han;Jung, Dongwoon
    • Journal of the Korean Chemical Society
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    • v.57 no.4
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    • pp.483-488
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    • 2013
  • Copper oxide (CuO) was synthesized from $CuCl_2$ by solution method. Anatase $TiO_2$ particle was dispersed into the solution before preparing CuO, so that $TiO_2$/CuO heterojunction was created through the nucleation of CuO onto the $TiO_2$ surface. Some amount of CuO was reduced to $Cu_2O$ by treating glucose into the solution, thereby preparing $TiO_2/Cu_xO$ complex. The obtained $TiO_2/Cu_xO$ complex showed advanced phtocatalytic activity under the sun light compared with the P-25 sample. In addition, the the $TiO_2/Cu_xO$ complex showed excellent antipathogenic effect.