• Title/Summary/Keyword: sub-cycle

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Design and Evaluation of Small-scale Supercritical Carbon Dioxide System with Solar Heat Source (태양열 적용을 위한 소형 초임계 이산화탄소 실험설비 설계 및 평가)

  • Choi, Hundong;So, Wonho;Lee, Jeongmin;Cho, Kyungchan;Lee, Kwon-yeong
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.21 no.6
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    • pp.403-410
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    • 2020
  • This paper focuses on the design of a 12-kW small-scale supercritical CO2 test loop. A theoretical study, stabilization, and optimization of carbon dioxide were carried out with the application of a solar heat source based on solar thermal data in Pohang. The thermodynamic cycle of the test facility is a Rankine cycle (transcritical cycle), which contains liquid, gas, and supercritical CO2. The system is designed to achieve 6.98% efficiency at a maximum pressure of 12 MPa and a maximum temperature of 70℃. In addition, the optimum turbine inlet temperature and pressure were calculated to increase the cycle efficiency, and the application of an internal heat exchanger (IHX) was simulated. It was found that the maximum efficiency increases to 18.75%. The simulation confirmed that the efficiency of the cycle is 6.7% in May and 6.26% in June.

A study on the economic feasibility and the LCCO2 of Main floor covering materials in day care centers (어린이집 주요 바닥마감재의 경제성 및 LCCO2 분석에 관한 연구)

  • Kim, Dong-Pil;Cho, Kyu-Man
    • The Journal of Sustainable Design and Educational Environment Research
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    • v.12 no.1
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    • pp.25-34
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    • 2013
  • As the construction industry develops, environmental pollution gets increasingly serious, giving damage including the increase of incidence of respiratory diseases and skin diseases among children with weakened immune systems, rather than adults. In daycare centers, infants and children spending much of their time, have high frequency of contact with the interior floor finish material. However, the majority of the child care centers don not use eco-friendly flooring but ordinary monorium flooring, because the initial investment cost of the eco-friendly flooring is higher than ordinary monorium flooring. Therefore, in this study, life cycle costs including the initial investment cost of the eco-friendly flooring and ordinary monorium flooring were calculated, demonstrating that the eco-friendly flooring is more economical than ordinary monorium flooring in terms of life-cycle cost. In addition, the analysis of the environmental performance also showed the excellence of the eco-friendly floor finishes. It is expected that the use of the eco-friendly floor finishes will increase due to their excellence in the aspect of life cycle cost and eco-friendly performance, through this study.

Electrode Characteristics of the (Mm)Ni5-Based Hydrogen Storage Alloys ((Mm)Ni5계 수소저장합금의 전극 특성)

  • Han, D.S.;Choi, S.J.;Chang, M.H.;Choi, J.;Park, C.N.
    • Transactions of the Korean hydrogen and new energy society
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    • v.6 no.1
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    • pp.35-41
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    • 1995
  • The MmNi-based alloy electrode was studied for use as a negative electrode in Ni-MH battery. Alloys with $MmNi_5-_xM_x$(M=Co,Al,Mn) composition were synthesized, and their electrode charateristics of activation rate, temperature dependence, electrode capacity and cycle life were investigated. With increasing Al content and decreasing Mn content in the alloys, the discharge capacity increased while the cycle life decreased. As x in $MmNi_5-_xM_x$ increased from 1.5 to 2.0, decreasing the Ni content, the discharge capacity, the low temperature property and the rate capability decreased. However its cycle life was improved. Increasing Co content resulted in a prolonged cycle life and decrease of high rate discharge capacity. It can be concluded that the most promising alloy in view of discharge capacity and cycle life is $MmNi_{3.5}Co_{0.7}Al_{0.5}Mn_{0.3}$.

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Improvement on Surface and Electrical Properties of Polymer Insulator Coated TiO2 Thin Film by Atomic Layer Deposition (원자층 증착장치에 의한 TiO2 박막 코팅된 폴리머 절연체의 표면 및 전기적 특성의 향상)

  • Kim, Nam-Hoon;Park, Yong Seob
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.29 no.7
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    • pp.440-444
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    • 2016
  • Titanium oxide ($TiO_2$) thin films were synthesized on polymer insulator and Si substrates by atomic layer deposition (ALD) method. The surface and electrical properties of $TiO_2$ films synthesized at various ALD cycle numbers were investigated. The synthesized $TiO_2$ films exhibited higher contact angle and smooth surface. The contact angle of $TiO_2$ films was increased with the increase of ALD-cycle number. Also, the rms surface roughness of films was slightly rough with the increase of ALD-cycle number. The leakage current on $TiO_2$ film surface synthesized at various conditions were uniformed, and the values were decreased with the increase of ALD-cycle number. In the results, the performance of $TiO_2$ films for self-cleaning critically depended on a number of ALD-cycle.

Hydrogen Production with High Temperature Solar Heat Thermochemical Cycle using CeO2/ZrO2 Foam Device (CeO2/ZrO2 Foam Device를 이용한 고온 태양열 열화학 싸이클의 수소 생산)

  • Lee, Jin-Gyu;Seo, Tae-Beom
    • Journal of the Korean Solar Energy Society
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    • v.34 no.6
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    • pp.11-18
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    • 2014
  • Two-step water splitting thermochemical cycle with $CeO_2$ foam device was investigated by using a solar simulator composed of 2.5 kW Xe-Arc lamp and mirror reflector. The hydrogen production of $CeO_2$ foam device depending on reaction temperature of Thermal-Reduction step and Water-Decomposition step was analyzed, and the hydrogen production of $CeO_2$ and $NiFe_2O_4/ZrO_2$ foam devices was compared. As a result, the amount of reduced $CeO_2$ considerably varies according to the reaction temperature of Thermal-Reduction step. and hydrogen production was not much when the amount of reduced $CeO_2$ decreased even if the reaction temperature of Water-Decomposition step was high. Therefore, it is very important to keep the reaction temperature of Thermal-Reduction step high in two-step thermochemical cycle with $CeO_2$.

Design of Non-flammable Mixed Refrigerant Joule-Thomson Refrigerator for Semiconductor Etching Process (반도체 식각공정을 위한 비가연성 혼합냉매 줄톰슨 냉동기 설계)

  • Lee, Cheonkyu;Kim, Jin Man;Lee, Jung-Gil
    • Journal of the Semiconductor & Display Technology
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    • v.21 no.2
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    • pp.144-149
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    • 2022
  • A cryogenic Mixed Refrigerant Joule-Thomson refrigeration cycle was designed to be applied to the semiconductor etching process with non-flammable constituents. 3-stage cascade refrigerator, single mixed refrigerant Joule-Thomson refrigerator, and 2-stage cascade type mixed refrigerant Joule-Thomson refrigerator are analyzed to figure out the coefficient of performance. Non-flammable mixture of argon(Ar), tetrafluoromethane(R14), trifluoromethane (R23) and octafluoropropane(R218) were utilized to analyze the refrigeration cycle efficiency. The designed refrigeration cycle was adapted to cool down the coolant of HFE7200(Ethoxy-nonafluorobutane, C4F9OC2H5) with certain constraints. Maximum coefficient of performance of the refrigeration system is obtained as 0.289 for the cooling temperature lower than -100℃. The detailed result of the coefficient of performance according to the mixture composition is discussed in this study.

Comparison of sodium permanganate and sodium hypochlorite on algae-containing water: algae cell integrity and byproduct formation (조류가 발생한 수질에 과망간산나트륨과 차아염소산나트륨이 세포 손상도 및 부산물 발생에 미치는 영향 비교)

  • Yang, Boram;Hong, Seok Won;Choi, Jae-Woo
    • Journal of Korean Society of Water and Wastewater
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    • v.36 no.5
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    • pp.249-260
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    • 2022
  • The effect of permanganate oxidation was investigated as water treatment strategy with a focus on comparing the reaction characteristics of NaOCl and sodium permanganate (NaMnO4) in algae (Monoraphidium sp., Micractinium inermum, Microcystis aeruginosa)-contained water. Flow cytometry explained that chlorine exposure easily damaged algae cells. Damaged algae cells release intracellular organic matter, which increases the concentration of organic matter in the water, which is higher than by NaMnO4. The oxidation reaction resulted in the release of toxin (microcystin-LR, MC-LR) in water, and the reaction of algal organic matter with NaOCl resulted in trihalomethanes (THMs) concentration increase. The oxidation results by NaMnO4 significantly improved the concentration reduction of THMs and MC-LR. Therefore, this study suggests that NaMnO4 is effective as a pre-oxidant for reducing algae damage and byproducts in water treatment process.

Material Life Cycle Assessment on Mg2NiHx-CaF2 Composites (Mg2NiHx-CaF2 수소 저장 복합체의 물질 전과정 평가)

  • HWANG, JUNE-HYEON;SHIN, HYO-WON;HONG, TAE-WHAN
    • Transactions of the Korean hydrogen and new energy society
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    • v.33 no.2
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    • pp.148-157
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    • 2022
  • Research on hydrogen storage is active to properly deal with hydrogen, which is considered a next-generation energy medium. In particular, research on metal hydride with excellent safety and energy efficiency has attracted attention, and among them, magnesium-based hydrogen storage alloys have been studied for a long time due to their high storage density, low cost, and abundance. However, Mg-based alloys require high temperature conditions due to strong binding enthalpy, and have many difficulties due to slow hydrogenation kinetics and reduction in hydrogen storage capacity due to oxidation, and various strategies have been proposed for this. This research manufactured Mg2Ni to improve hydrogenation kinetics and synthesize about 5, 10, 20 wt% of CaF2 as a catalyst for controlling oxidation. Mg2NiHx-CaF2 produced by hydrogen induced mechanical alloying analyzed hydrogenation kinetics through an automatic PCT measurement system under conditions of 423 K, 523 K, and 623 K. In addition, material life cycle assessment was conducted through Gabi software and CML 2001 and Eco-Indicator 99' methodology, and the environmental impact characteristics of the manufacturing process of the composites were analyzed. In conclusion, it was found that the effects of resource depletion (ARD) and fossil fuels had a higher burden than other impact categories.

Effective problem mitigation strategy of lithium secondary battery silicon anode utilized liquid precursor (에틸벤젠을 이용한 실리콘 산화물 음극재의 효과적인 카본 코팅 전략)

  • Sangryeol Lee;Seongsu Park;Sujong Chae
    • Journal of the Korean institute of surface engineering
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    • v.56 no.1
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    • pp.62-68
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    • 2023
  • Silicon (Si) is considered as a promising substitute for the conventional graphite due to its high theoretical specific capacity (3579 mAh/g, Li15Si4) and proper working voltage (~0.3V vs Li+/Li). However, the large volume change of Si during (de)lithiation brings about severe degradation of battery performances, rendering it difficult to be applied in the practical battery directly. As a one feasible candidate of industrial Si anode, silicon monoxide (SiOx) demonstrates great electrochemical stability with its specialized strategy, downsized Si nanocrystallites surrounded by Li+ inactive buffer phase (Li2O and Li4SiO4). Nevertheless, SiOx inherently has the initial irreversible capacity and poor electrical conductivity. To overcome those issues, conformal carbon coating has been performed on SiOx utilizing ethylbenzene as the carbon precursor of chemical vapor deposition (CVD). Through various characterizations, it is confirmed that the carbon is homogeneously coated on the surface of SiOx. Accordingly, the carbon-coated SiOx from CVD using ethylbenzene demonstrates 73% of the first cycle efficiency and great cycle life (88.1% capacity retention at 50th cycle). This work provides a promising synthetic route of the uniform and scalable carbon coating on Si anode for high-energy density.

A Analysis of Turning Point of Fashion Cycle -Compare 1997 and 2002- (패션 주기의 터닝 포인트 분석 -Vogue 1997년과 2002년도를 중심으로-)

  • 유지헌
    • The Research Journal of the Costume Culture
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    • v.12 no.3
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    • pp.327-338
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    • 2004
  • This study was attempted to check period of a fashion cycle and to suggest its main-stream and sub-stream by analyzing the fashion trends presented in Vogue Korea between 1997 and 2002. A content analysis method was used to analyze 24 volumes. The result showed that the fashion trend of 1997's was a turning point from the simplicity, which was a trend up to 1996's, to the romanticism. The fashion trends of 2002 seemed to be also a turning point from the new-romanticism which was added the hippism to the romanticism continued from 1997, to the sporticism. The result confirmed that the main-stream of fashion theme have been continued for 5 years as a regular cycle system and could be repeated. It also verified that some sub-stream which was affected by social, cultural and political situation led the fashion changes. The results of this study could be expected to reflect not only fashion design, merchandising and marketing strategy but also consumer purchase behavior of the future.

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