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http://dx.doi.org/10.7316/KHNES.2022.33.2.148

Material Life Cycle Assessment on Mg2NiHx-CaF2 Composites  

HWANG, JUNE-HYEON (Department of Energy Materials and Engineering, Korea National University of Transportation)
SHIN, HYO-WON (Department of Energy Materials and Engineering, Korea National University of Transportation)
HONG, TAE-WHAN (Department of Energy Materials and Engineering, Korea National University of Transportation)
Publication Information
Transactions of the Korean hydrogen and new energy society / v.33, no.2, 2022 , pp. 148-157 More about this Journal
Abstract
Research on hydrogen storage is active to properly deal with hydrogen, which is considered a next-generation energy medium. In particular, research on metal hydride with excellent safety and energy efficiency has attracted attention, and among them, magnesium-based hydrogen storage alloys have been studied for a long time due to their high storage density, low cost, and abundance. However, Mg-based alloys require high temperature conditions due to strong binding enthalpy, and have many difficulties due to slow hydrogenation kinetics and reduction in hydrogen storage capacity due to oxidation, and various strategies have been proposed for this. This research manufactured Mg2Ni to improve hydrogenation kinetics and synthesize about 5, 10, 20 wt% of CaF2 as a catalyst for controlling oxidation. Mg2NiHx-CaF2 produced by hydrogen induced mechanical alloying analyzed hydrogenation kinetics through an automatic PCT measurement system under conditions of 423 K, 523 K, and 623 K. In addition, material life cycle assessment was conducted through Gabi software and CML 2001 and Eco-Indicator 99' methodology, and the environmental impact characteristics of the manufacturing process of the composites were analyzed. In conclusion, it was found that the effects of resource depletion (ARD) and fossil fuels had a higher burden than other impact categories.
Keywords
Magnesium hydride; Hydrogen storage; $CaF_2$; MLCA; Life cycle impact analysis;
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