• Title/Summary/Keyword: structure stability

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Preparation and Anti-fouling Properties of PVDF Mixed Matrix Asymmetric Membranes Impregnated with 𝛽-cyclodextrin (𝛽-사이클로덱스트린을 함침시킨 PVDF 혼합기질 비대칭막의 제조와 내오염성 평가)

  • Shin, Sung Ju;Lee, Jong Sung;Lee, Jeong Gil;Youm, Kyung Ho
    • Membrane Journal
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    • v.31 no.6
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    • pp.434-442
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    • 2021
  • Poly(vinylidene fluoride) (PVDF) membrane has a good membrane durability because of its high mechanical resistance, thermal and chemical stability. However, the strong hydrophobic property of PVDF membrane can induce a low water permeability and easy fouling by proteins and organic matters. In order to improve the anti-fouling properties of PVDF membrane, the PVDF mixed matrix asymmetric membranes impregnated with biofunctional material 𝛽-cyclodextrin (𝛽-CD) in the membrane structure were prepared by phase inversion method. The membrane filtration experiments of pure water and BSA solution were performed using the PVDF/𝛽-CD mixed matrix asymmetric membranes prepared according to the 𝛽-CD contents. The experiments showed that the introduction of 𝛽-CD into the PVDF polymer matrix contributed to increase in the hydrophilic property of the PVDF membranes, and this led to the reduction of contact angles and improvement of anti-fouling properties. The PVDF/𝛽-CD membrane which was prepared using the dope solution with a 2 wt% 𝛽-CD content represented 64 L/m2·h of pure water flux, 95% of BSA rejection and maximum 80% of flux enhancements compared to flux results of the pristine PVDF membrane.

Nanostructured PVdF-HFP/TiO2 Composite as Protective Layer on Lithium Metal Battery Anode with Enhanced Electrochemical Performance (PVdF-HFP/TiO2 나노복합체 보호층을 통한 리튬금속전지 음극의 전기화학적 성능 향상)

  • Lee, Sanghyun;Choi, Sang-Seok;Kim, Dong-Eun;Hyun, Jun-Heock;Park, Young-Wook;Yu, Jin-Seong;Jeon, So-Yoon;Park, Joongwon;Shin, Weon Ho;Sohn, Hiesang
    • Membrane Journal
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    • v.31 no.6
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    • pp.417-425
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    • 2021
  • As the demand for high-capacity batteries increases, there has been growing researches on the lithium metal anode with a capacity (3,860 mAh/g) of higher than that of conventional one and a low electrochemical potential (-3.040 V). In this study, using the anatase phased TiO2 nanoparticles synthesized by hydrothermal synthesis, a PVdF-HFP/TiO2 organic/inorganic composite material was designed and used as an interfacial protective layer for a Li metal anode. As-formed organic/inorganic-lithium composite thin film was confirmed through the crystalline structure and morphological analyses. In addition, the electrochemical test (cycle stability and voltage profile) confirmed that the protective layer of PVdF-HFP/TiO2 composite (10 wt% TiO2 and 1.1 ㎛ film thickness) contributed to the enhanced electrochemical performance of the lithium metal anode (Colombic efficiency retention: 90% for 77 cycles). Based on comparative test with the untreated lithium electrode, it was confirmed that our protective layer plays an important role to stabilize/improve the EC performance of the lithium metal negative electrode.

Conservation Treatment of Leather Socks Housed in the National Museum of Korea (국립중앙박물관 소장 가죽버선의 보존처리)

  • Lee, Hyelin;Park, Seungwon
    • Conservation Science in Museum
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    • v.27
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    • pp.39-56
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    • 2022
  • The purpose of this project was to improve the stability of a pair of leather socks for use on snowy days in the collection of the National Museum of Korea (Namsan1567) by conducting conservation treatment and restoring the socks to their original form for use in research and exhibition. Leather socks are referred to in ancient documents with names combining the word "mal" for socks with a term indicating their material (e.g., pimal, meaning leather socks; nokpimal, meaning deer leather socks; jangpimal, meaning roe deer leather socks, or lipimal, meaning racoon dog leather socks) and are mentioned mostly in connection with Jeju Island. Related documents include the Seungjeongwon ilgi (Daily Record of the Grand Secretariat), Injaeilnok (Diary of Injae Jo Geukseon), and Hamel's Journal and a Description of the Kingdom of Joseon. Extant examples of ancient leather socks display the same form as beoseon (traditional Korean socks) and are made of either leather or a combination of leather and fabric. It is likely that such leather socks were worn on Jeju Island to protect the feet from the cold. A condition survey of the leather socks was first conducted to establish a plan for their conservation treatment. Since the socks were in rather poor condition, it was decided to identify their original form through an investigation of relics and pertinent previous studies. The socks were cleaned in consideration of results of the condition survey, and the missing parts around the necks of the socks were reinforced in a reversible manner using counting stitches with cloth dyed to match the original color. Since the bottoms of the socks had lost much of their original form due to deterioration and disintegration in the leather, supports were made and inserted inside the socks to help retain their shape. Through these processes, the structure and characteristics of the socks and the techniques used in their production could be analyzed, their condition was stabilized, and their original form was recovered.

A Four-Wheeled Mobile Robot with Omnidirectionality (전방향성을 갖는 네 바퀴 이동로봇)

  • Kang, Su Min;Sung, Young Whee
    • Journal of the Institute of Convergence Signal Processing
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    • v.23 no.1
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    • pp.21-27
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    • 2022
  • Traditional automobile or 2-wheeled robot have limitations on mobility because of their mechanical structure. As traditional automobile is being replaced by electric cars, robot technology is applied to the car industry. In robotics, many researchers worked on omnidirectional mobile robot and produced lots of noticeable results. However in many of the results, specialized wheels such as Mecanum wheels are required. That imposes restrictions on robot speed and outdoor driving. We proposed a 2-wheeled modular robot that has omnidirectional mobility without using specialized wheels. In this paper, we propose a 4-wheeled omnidirectional mobile robot that consists of those two modular robots. The proposed robot adopts electric brakes to combine wheel housings and the robot body or to separate wheel housings from the robot body. Two absolute-type encoders and four incremental encoders are used to control the position of the wheel housing and velocities of the wheels. The proposed robot has omnidirectional mobility and can move fast and outdoor with normal tire wheels. We implemented the proposed robot and the feasibility and stability of the robot is verified by two separate experiments.

Ultra-high Temperature EM Wave Absorption Behavior for Ceramic/Sendust-aluminosilicate Composite in X-band (X-Band 영역에서의 세라믹/샌더스트-알루미노실리케이트 복합재의 초고온 전자파 흡수 거동)

  • Choi, Kwang-Sik;Sim, Dongyoung;Choi, Wonwoo;Shin, Joon-Hyung;Nam, Young-Woo
    • Composites Research
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    • v.35 no.3
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    • pp.201-215
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    • 2022
  • This paper presents the development of thin and lightweight ultra-high temperature radar-absorbing ceramic composites composed of an aluminosilicate ceramic matrix-based geopolymer reinforced ceramic fiber and sendust magnetic nanoparticles in X-band frequency range (8.2~12.4 GHz). The dielectric properties with regard to complex permittivity of ceramic/sendust-aluminosilicate composites were proportional to the size of sendust magnetic nanoparticle with high magnetic characteristic properties as flake shape and its concentrations in the target frequency range. The characteristic microstructures, element composition, phase identification, and thermal stability were examined by SEM, EDS, VSM and TGA, respectively. The fabricated total thicknesses of the proposed single slab ultra-high temperature radar absorber correspond to 1.585 mm, respectively, exhibiting their excellent EM absorption performance. The behavior of ultra-high temperature EM wave absorption properties was verified to the developed free-space measurement system linked with high temperature furnace for X-band from 25℃ to 1,000℃.

Financial Status of Korean Ppuri Industry based on Credit Evaluation (2017-2019) (신용평가에 기반한 한국 뿌리기업 재무상황 (2017-2019))

  • Kim, Bo Kyung;Kim, Taek-Soo;Lee, Sangmok;Kim, Chang Kyung
    • Journal of Korea Foundry Society
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    • v.42 no.2
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    • pp.83-93
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    • 2022
  • Throughout this research course, we have analyzed the financial situation of more than 2,700 companies using credit evaluation disclosures from 2017 to 2019. The population was gathered based on the certification of Ppuri companies and Ppuri Expertise companies through the Korea National Ppuri Industry Center, accompanied by the NICE credit evaluation index. For the first time in Korea, we wanted to look at growth, profitability, and stability through financial analysis of the Ppuri industry. Through an indepth analysis, we identified operating income (rate), net income (rate), asset size, and debt ratio, along with three years of Ppuri company workers and total sales fluctuations, and looked at the financial structure per capita. In addition, financial status per person was compared by dividing Ppuri companies into six groups by employee size. Groups were 10 or fewer people, 11 to 20 people, 21 to 50 people, 51 to 200 people, 201-300 people, and 300 or more people; single individual companies were excluded for research convenience. Overall, the financial situation of Ppuri companies was judged to be in a very bad downturn, and financial indicators deteriorated over the course of the three years of investigation. In particular, the smaller the number of employees, the greater the financial fluctuations were and the worse the situations were. Among Ppuri companies, the casting industry, which is the technical starting point for the value chain of the industry, was found to also be in a very bad state, with continued workforce declines, total assets and sales reductions at severe levels, and operating income (rate) and net income (rate) also very poor. This is why we need a suitable and feasible policy direction, something that is difficult but must be allowed to develop.

Study on Structural Stability Analysis of Excavation Stage Considering Excavation Process and Supporting Materials in Room-and-Pillar Underground Space (격자형 지하공간에서 굴착 공정과 지보재를 고려한 굴착 단계별 구조 안정성 해석 연구)

  • Soon-Wook, Choi;Soo-Ho, Chang;Tae-Ho, Kang;Chulho, Lee
    • Journal of the Korean Geosynthetics Society
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    • v.21 no.4
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    • pp.21-29
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    • 2022
  • The room-and-pillar method or grid-type underground space is a method of forming a space by excavating the excavation part at regular intervals so that it is orthogonal and using natural rock mass as a structure. Such excavation may appear different in size from the excavation stage where the maximum displacement occurs depending on the excavation direction and sequence. In this study, considering the installation of support materials such as shotcrete and rock bolts for the optimal design of the excavation process, the safety and constructability of the design and construction of the grid-type underground space under specific ground conditions were analytically reviewed. The ground conditions were set using an numerical method, and the stress at pillar and displacement at center of room were considered for each excavation stage and construction type under a constant surcharge. The height of the space was 8m, which was set higher than the size of a general office, and was reviewed in consideration of equipment and plant facilities. In addition, the degree of displacement control according to the installation of support materials was reviewed in consideration of shotcrete and rock bolts.

The Effect of Structure and Acidity of Fluorinated HZSM-5 on Ethylene Aromatization (불소화 HZSM-5의 구조 및 산도가 에틸렌 방향족화에 미치는 영향)

  • Kyeong Nan, Kim;Seok Chang, Kang;Geunjae, Kwak
    • Applied Chemistry for Engineering
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    • v.34 no.1
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    • pp.15-22
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    • 2023
  • Recent studies have actively investigated ways to improve the economic feasibility and efficiency of the Fischer-Tropsch process by increasing the yields of the monocyclic aromatic compounds (BTEX). In this study, ethylene was selected as a model of F-T-derived hydrocarbons, and the ethylene-to-aromatics (ETA) reaction was investigated according to changes in acid characteristics, mesopores, and crystallinity of HZSM-5 (HZ5). Fluorinated HZ5 was prepared by calcination followed by impregnation of an aqueous NH4F solution having different molar concentrations in HZ5, and the structural and chemical properties of F/HZ5 were investigated through Brunauer-Emmett-Teller (BET), solid-state nuclear magnetic resonance (NMR), X-ray photoelectron spectroscopy (XPS), NH3-temperature-programmed desorption (TPD), and pyridine-IR spectroscopy. The ETA reactions were performed at 673 K under 0.1 MPa, and fluorinating HZ5 by an aqueous NH4F solution of 0.17 M improved ethylene conversion, BTEX selectivity, and catalytic stability due to acidity, mesopore fraction, and crystallinity.

Detection of Cavities Behind Concrete Walls Using a Microphone (마이크로폰을 이용한 콘크리트 벽체 배면의 공동 탐사)

  • Kang, Seonghun;Lee, Jong-Sub;Han, WooJin;Kim, Sang Yeob;Yu, Jung-Doung
    • Journal of the Korean Geotechnical Society
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    • v.38 no.12
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    • pp.19-28
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    • 2022
  • Cavities behind concrete walls can adversely affect the stability of structures. Thus study aims to detect cavities behind concrete structures using a microphone in a laboratory model test. A small-scale concrete wall is constructed in a chamber, which is composed of a reinforced concrete plate and dry soil. A plastic bowl is then placed between the plate and soil to simulate a cavity behind the concrete structure. Leaky surface acoustic waves are generated by impacting the concrete plate using a hammer and are measured using a microphone. The measured signals are analyzed using natural frequencies, and cavity-free sections are evaluated. The test results show that the first natural frequency decreases at the cavity section due to the flexural vibration behavior of the plate. In addition, the amplitude corresponding to the first natural frequency decreases as the measurement location becomes farther from the cavity center and significantly decreases at the measurement locations near the rebars. This study demonstrates that a microphone may be useful to detect cavities behind concrete walls.

Performance Evaluation of Multi-Friction Dampers for Seismic Retrofitting of Structures (구조물 내진보강을 위한 다중 마찰댐퍼의 성능 평가)

  • Kim, Sung-Bae;Kwon, Hyung-O;Lee, Jong-Suk
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.26 no.6
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    • pp.54-63
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    • 2022
  • This paper is a study on the friction damper, which is one of the seismic reinforcement devices for structures. This study developed a damper by replacing the internal friction material with ultra high molecular weight polyethylene (UHMWPE), a type of composite material. In addition, this study applied a multi-friction method in which the internal structure where frictional force is generated is laminated in several layers. To verify the performance of the developed multi-friction damper, this study performed a characteristic analysis test for the basic physical properties, wear characteristics, and disc springs of the material. As a result of the wear test, the mass reduction rate of UHMWPE was 0.003%, which showed the best performance among the friction materials based on composite materials. Regarding the disc spring, this study secured the design basic data from the finite element analysis and experimental test results. Moreover, to confirm the quality stability of the developed multi-friction damper, this study performed an seismic load test on the damping device and the friction force change according to the torque value. The quality performance test result showed a linear frictional force change according to the torque value adjustment. As a result of the seismic load test, the allowable error of the friction damper was less than 15%, which is the standard required by the design standards, so it satisfies the requirements for seismic reinforcement devices.