• 제목/요약/키워드: structural stabilization

검색결과 162건 처리시간 0.027초

계면안정화를 통한 Si-SiO2-흑연 복합재 음극의 전기화학적 특성 개선 (Improved Cycling Ability of Si-SiO2-graphite Composite Battery Anode by Interfacial Stabilization)

  • 민정혜;배영산;김성수;송승완
    • 전기화학회지
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    • 제15권3호
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    • pp.154-159
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    • 2012
  • Si계 음극소재는 리튬 삽입-탈착 중 일어나는 큰 구조적 부피변화와 입도변화로 인해 빠른 성능 퇴화가 일어나는 단점이 있다. 산화물 SiO 음극소재는 리튬과의 반응 중 비활성상인 $Li_2O$ 및 lithium silicate가 형성되어 Si의 부피변화를 완화시키는 버퍼 역할을 하므로 용량은 Si보다 적으나 개선된 용량 유지 특성을 보이는 것으로 알려져 있다. 본 연구에서는 Si의 부피변화 완화를 위하여 저가의 $SiO_2$와 입자간 전기전도성을 향상시키는 흑연을 구조안정화 기재로서 사용하여 Si-$SiO_2$-흑연 복합재 음극을 제작하였다. 구조안정화 뿐만 아니라 silane계 전해액 첨가제를 이용하여 Si-$SiO_2$-흑연 복합재 음극과 전해액간 계면을 안정화시킴으로써 용량 유지 특성이 개선되는 효과에 대해 보고하고자 한다.

구조적 불확실성을 갖는 비선형 시스템의 안정화 역최적제어 (Stabilization Inverse Optimal Control of Nonlinear Systems with Structural Uncertainty)

  • 조도현;이철;이종용
    • 전자공학회논문지 IE
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    • 제46권4호
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    • pp.49-56
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    • 2009
  • 본 논문에서는 구조적 불확실성을 갖는 비선형 시스템에 대한 안정화 역 최적 제어를 고려하였다. 제어 Lyapunov 함수를 기초로, 대역적 점근적 안정도를 제안한다. 이로부터 역 최적 제어를 위한 최소의 제약조건을 유도한다. 이 결과를 이용하여 불확실성을 갖는 비선형시스템의 역 최적 제어기에 적용하였으며, 기존의 결과를 확장한 것이다. 본 연구에서 고려된 비선형 시스템은 가장 많이 표현되며 제안된 방법의 효율성을 검증하기 위하여 시뮬레이션을 하였다.

횡분류(流)(橫噴流)에서 난류 비예흔합 화염의 화염날림에 대한 거대 와(渦)구조 혼합 모텔 적용 (A Large-scale Structural Mixing Model applied to Blowout of Turbulent Nonpremixed Jet Flames in a Cross Jet Flow)

  • 이기만;박정
    • 대한기계학회논문집B
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    • 제26권1호
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    • pp.133-140
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    • 2002
  • This article presents an application of a large-scale structural mixing model(Broadwell et at. 1984) to the blowout of turbulent reacting cross flow jets. Experimental observations, therefore, aim to identify the existence of large-scale vortical structure exerting an important effect upon the flame stabilization. In the analysis of common stability curve, it is seen that the phenomenon of blowout are only related to the mixing time scale of the two flows. The most notable observation is that the blowout distance is traced at a fixed positions according to the velocity ratio at all times. Measurements of the lower blowout limits in the liftable flame are qualitatively in agreement with the blowout parameter $\xi$, proposed by Broadwell et al. Good agrement between the results calculated by a modified blowout parameter $\xi$'and the present experimental results confirms the important effect of large-scale structure in the stabilization feature of blowout.

Effect of carbonization temperature on crystalline structure and properties of isotropic pitch-based carbon fiber

  • Kim, Jung Dam;Roh, Jae-Seung;Kim, Myung-Soo
    • Carbon letters
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    • 제21권
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    • pp.51-60
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    • 2017
  • Isotropic pitch-based fibers produced from coal tar pitch with the melt-blowing method were carbonized at temperatures ranging from 800 to $1600^{\circ}C$ to investigate their crystalline structure and physical properties as a function of the carbonization temperature. The in-plane crystallite size ($L_a$) of the carbonized pitch fiber from X-ray diffraction increased monotonously by increasing the carbonization temperature resulting in a gradual increase in the electrical conductivity from 169 to 3800 S/cm. However, the variation in the $d_{002}$ spacing and stacking height of the crystallite ($L_c$) showed that the structural order perpendicular to the graphene planes got worse in carbonization temperatures from 800 to $1200^{\circ}C$ probably due to randomization through the process of gas evolution; however, structural ordering eventually occurred at around $1400^{\circ}C$. For the carbonized pitch powder without stabilization, structural ordering perpendicular to the graphene planes occurred at around $800-900^{\circ}C$ indicating that oxygen was inserted during the stabilization process. Additionally, the shear stress that occurred during the melt-blowing process might interfere with the crystallization of the CPF.

근대건축의 구조시스템과 건축적 특성에 관한 연구 (A Study on The Structural Systems of Modern Architecture and Architectural Characteristics)

  • 조성현
    • 한국디지털건축인테리어학회논문집
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    • 제10권1호
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    • pp.49-56
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    • 2010
  • The purpose of this study is to examine the relationship between the structural system used in modern architecture and the form and spatial composition of the buildings. The principle in stabilization of structures is closely related to the architectural form. That is, in order to stabilize a building, a special type of structural system is required and consequently shows up with consistent characteristics in the architectural form. Modern architecture can be classified into skeleton structure, trusses structure, and space structure according to the structural characteristics. Skeleton structure is then divided into a perpendicular form and tapered form. Trusses structure is categorized as dome-shaped structure and slab-shaped structure, and space structure can be divided into compressible space structure and tensile space structure. When classifies the modern building with the aspect of architectural effect, there is a possibility of trying to divide with effect of production, and its expression. Effect of production mean structural system and effect of expression mean space and plan.

Molecular analysis of c-terminus structure for elucidating the stabilization effect of site-specific immobilization

  • 백승필;유영재
    • 한국생물공학회:학술대회논문집
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    • 한국생물공학회 2001년도 추계학술발표대회
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    • pp.886-889
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    • 2001
  • C-terminus specific immobilization often results in a increased structural stability resistant to various denaturation factors. In order to elucidate the immobilization effect on the c-terminus in molecular level, we made over 200 protein data set from Protein Data Bank(PDB), analyzed c-terminus structure of each protein, and investigated the structural relationship with the stabilizing factors such as hydrogen bond, ion pairs, cation pi, disulfide bond, solvation free energy, surface area, flexibility and so on.

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산림작업로의 지속적 활용을 위한 간이 사면안정처리 효과분석 (Analysis of the Effectiveness of Simplified Slope Stabilization Methods for the Continuous Utilization of Skid Trails)

  • 이관희;황진성;지병윤
    • 한국산림과학회지
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    • 제108권4호
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    • pp.582-591
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    • 2019
  • 본 연구는 산림작업로의 사용이후에 존치시켜 지속적으로 활용하기 위하여 필요한 저비용 구조의 간이 사면안정구 조물을 개발하고, 그 시공효과를 살펴보고자 실시하였다. 국립산림과학원 산림기술경영연구소 관내에 시설된 산림작업로의 성토사면에 안정구조물을 시공하였다. 성토사면 간이 안정구조물에 대하여 차량의 통행으로 인한 노면 침하량 및 지지력 분석을 실시하였고, 모든 사면안정구조물에 대해서는 차량통행으로 인한 안정구조물의 변위량을 측정하여 안정성을 판정하였다. 성토사면 간이 사면안정구조물을 대상으로 한 소운재 차량(총 중량 17톤)을 최대 100회(목재운송량 780 ㎥)까지 통행 후 운송횟수별 노면의 지지력과 침하량을 분석한 결과, 안정처리공법별로 노면의 침하량은 최대 150 mm 이하로 양호한 것으로 나타났으나, 노면지지력의 효과는 크게 없는 것으로 나타났다. 또한, 안정구조물의 안정성을 평가한 결과, 뿌리쌓기 공법에서 안정성이 다소 낮았으나, 대체로 모든 구조물의 평균 변위량이 약 20 mm이하로 구조적 안정성에는 큰 문제가 없는 것으로 나타났다. 이와 같이 목재생산 이후에 존치되는 산림작업로를 대상으로 간이한 사면안정구조물을 적용한다면 효율적 목재생산이 가능할 뿐만 아니라, 부족한 임도를 보완할 수 있는 영구적인 생산기반시설로 활용이 가능할 것으로 사료된다.

Stabilization of oily contaminated clay soils using new materials: Micro and macro structural investigation

  • Ghiyas, Seyed Mohsen Roshan;Bagheripour, Mohammad Hosein
    • Geomechanics and Engineering
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    • 제20권3호
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    • pp.207-220
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    • 2020
  • Clay soils have a big potential to become contaminated with the oil derivatives because they cover a vast area of the earth. The oil derivatives diffusion in the soil lead to soil contamination and changes the physical and mechanical properties of the soil specially clay soils. Soil stabilization by using new material is very important for geotechnical engineers in order to improve the engineering properties of the soil. The main subjects of this research are a- to investigate the effect of the cement and epoxy resin mixtures on the stabilization and on the mechanical parameters as well as the microstructural properties of clay soils contaminated with gasoline and kerosene, b- study on the phenomenon of clay concrete development. Practical engineering indexes such as Unconfined Compressive Strength (UCS), elastic modulus, toughness, elastic and plastic strains are all obtained during the course of experiments and are used to determine the optimum amount of additives (cement and epoxy resin) to reach a practical stabilization method. Microstructural tests were also conducted on the specimens to study the changes in the nature and texture of the soil. Results obtained indicated that by adding epoxy resin to the contaminated soil specimens, the strength and deformational properties are increased from 100 to 1500 times as that of original soils. Further, the UCS of some stabilized specimens reached 40 MPa which exceeded the strength of normal concrete. It is interesting to note that, in contrast to the normal concrete, the strength and deformational properties of such stabilized specimens (including UCS, toughness and strain at failure) are simultaneously increased which further indicate on suitability and applicability of the current stabilization method. It was also observed that increasing cement additive to the soil has negligible effect on the contaminated soils stabilized by epoxy resin. In addition, the epoxy resin showed a very good and satisfactory workability for the weakest and the most sensitive soils contaminated with oil derivatives.

An attitude control of stabilizing system using indirect adaptive fuzzy control

  • Kim, Jae-Hoon;Kim, Jong-Hwa
    • Journal of Advanced Marine Engineering and Technology
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    • 제38권10호
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    • pp.1318-1326
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    • 2014
  • The purpose of a tracking control system is to track a moving target and to find the exact information of the target. If the platform of the tracking control system is equipped on a moving vehicle such as a ship, the tracking control system will treat even the additional platform motion. In order to avoid the complexity comprising the tracking control system, a process to treat the platform motion, named stabilizing system, must be separated from the tracking control system. In this paper, a method to comprise an attitude control system for the platform stabilization is proposed using an adaptive fuzzy control which is applicable to the system with structural and parametric uncertainty. The suggested adaptive fuzzy control algorithm is the 2nd/1st-type indirect adaptive fuzzy control algorithm using the advantages of 1st-type and 2nd-type indirect adaptive fuzzy control algorithm. Several experiments using the implemented stabilizing system are executed for verifying the effectiveness of the suggested method.

Electrochemical Performances of the Fluorine-Substituted on the 0.3Li2MnO3·0.7LiMn0.60Ni0.25Co0.15O2 Cathode Material

  • Kim, Seon-Min;Jin, Bong-Soo;Park, Gum-Jae;Kim, Hyun-Soo
    • Journal of Electrochemical Science and Technology
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    • 제5권3호
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    • pp.87-93
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    • 2014
  • The fluorine-substituted $0.3Li_2MnO_3{\cdot}0.7Li[Mn_{0.60}Ni_{0.25}Co_{0.15}]O_{2-x}F_x$ cathode materials were synthesized by using the transition metal precursor, $LiOH{\cdot}H_2O$ and LiF. This was to facilitate the movement of lithium ions by forming more compact SEI layer and to reduce the dissolution of transition metals. The $0.3Li_2MnO_3{\cdot}0.7Li[Mn_{0.60}Ni_{0.25}Co_{0.15}]O_{2-x}F_x$ cathode material was sphere-shaped and each secondary particle had $10{\sim}15{\mu}m$ in size. The fluorine-substituted cathodes initially delivered low discharge capacity, but it gradually increased until 50th charge-discharge cycles. These results indicated that fluorine substitution gave positive effects on the structural stabilization and resistance reduction in materials.