• Journal of the Korean Recycled Construction Resources Institute
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• v.9 no.4
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• pp.529-536
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• 2021

In this study, nano-silica and nano-titanium were selected to determine the possibility of applying the binder to reactive nano materials. The basic characteristics of the nano material candidate group were reviewed. and the reactivity of nano materials was reviewed through K-value. The reactivity of the nano silicate materials was measured to be high. Therefore, as a final candidate group, nano silicate materials were selected. The finally selected reactive nano material was reviewed for its usability as a construction binder. The mechanical properties and unit weight of cement paste were reviewed using silica fume and blast furnace slag and nano materials. When cement composites with nano silicate materials, it was confirmed that it was effective in improving the mechanical performance and decrease the unit weight of cement composites.

• Journal of the Korea institute for structural maintenance and inspection
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• v.23 no.3
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• pp.56-64
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• 2019

Various approaches have been attempted to develop recycling technologies related to industrial waste resources containing metals. Among them, glass is not decomposed into microorganisms, so landfill is not suitable, and interest in the recycling of waste glass is increasing. In this paper, by incorporating chelate resin to suppress the elution of heavy metals in waste glass and using waste glass as a fine aggregate and we want to evaluate the strength, drying shrinkage, alkali-silica reaction and heavy metal leaching of shielded filler materials and to provide basic data for utilizing waste glass as an economical and environmentally friendly shielding filler. As a result of the test, it was found that the use of waste glass as a fine aggregate was effective in the development of strength, but the incorporation of chelate resin had an influence on the strength development. In addition, the addition of chelate resin was effective in improving drying shrinkage but it was found to affect the alkali - silica reaction. As a result of the heavy metal leaching test, the KSLP test method satisfies all the criteria for heavy metal leaching. However, in case of lead, the limit of US ANSI 67-2007a was exceeded and further study should be done.

• Journal of the Korea institute for structural maintenance and inspection
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• v.24 no.5
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• pp.95-102
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• 2020

For the purpose of developing a PE fiber-reinforced highly ductile cementitious composite having high tensile strain capacity more than 2% under the condition of containing aggregates with large particle size, this study investigated the tensile behavior of composites according to the particle size and distribution of aggregates in the composite. Compared with the mixture containing silica sand of which particle size is less than 0.6 mm, mixtures containing river sand and/or gravel with the maximum particle size of 2.36 mm, 4.75 mm, 5.6 mm, 6.7 mm were considered in the experimental design. The particle size distributions of aggregates were adjusted for the optimized distribution curves obtained from modified A&A model by blending different sizes of aggregates. All the mixtures presented clear strain-hardening behavior in the direct tensile tests. The mixtures with the blended aggregates to meet the optimum curves of aggregate size distributions showed higher tensile strain capacity than the mixture with silica sand. It was also found that the tensile strain capacity was improved as the maximum size of aggregate increased which resulted in wider particle size distribution. The mixtures with the maximum size of 5.6 mm and 6.7 mm presented very high tensile strain capacities of 4.83% and 5.89%, respectively. This study demonstrated that it was possible to use coarse aggregates in manufacturing highly ductile fiber-reinforced cementitous composite by adjusting the particle size distribution.

• Journal of the Korea institute for structural maintenance and inspection
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• v.26 no.2
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• pp.76-83
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• 2022

Since the 3D printing mortar is exposed to the atmosphere immediately after printing, moisture is largely evaporated from the surface of the layer. The evaporation of moisture on the surface of the layer greatly causes drying shrinkage and increases the risk of cracking and damage to the structure due to drying shrinkage. This study experimentally evaluated the shrinkage behavior of the initial age using the mortar used for 3D printing. The change in shrinkage was evaluated by comparing the shrinkage of the specimen cured by the sealing method and the atmospheric exposure method. In addition, compared with the case where type 1 cement was used 100%, the shrinkage amount was evaluated when 20% of fly ash was replaced and 10% of silica fume was used. In particular, the effect of three chemical admixtures applied using 3D printing on shrinkage was evaluated experimentally. When fly ash and silica fume were used, the shrinkage amount increased by 60 - 110% compared to the case when type 1 cement was used. The application of viscosity modifiers and shrinkage reducers reduced the shrinkage by at least 18% and at most 70% depending on the curing conditions. The temperature of the specimen temporarily decreased to 15 ℃ at the beginning of curing, and the correlation between the internal temperature of the specimen and the shrinkage behavior was observed.

• Journal of the Korea institute for structural maintenance and inspection
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• v.26 no.6
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• pp.139-147
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• 2022

In this study, we designed a high-strength, low-alkali type cement composite for artificial reef by mixing various binders and evaluated whether it is possible to manufacture it with an ME method 3D printer. As a result of the tests, it is found that it is important to control the water-binder ratio, the silica sand-binder ratio, and the type of silica sand in order to control the fluidity of the cement composites to enable 3D printing. The surface quality of 3D printer output can be achieved by adjusting the amount of viscosity agent added while obtaining printable fluidity. In the cement composites mixing proportion using the alpha-type hemihydrate gypsum, a setting control agent needs to be used to control the quick setting effect. It is also necessary to derive the time to maintain the fluidity, and to apply it when printing. To obtain the required strength, the mix proportion needs to be modified while satisfying the fluidity level of 3D-printable cement composites. In the present study, 3D-printable mix proportions were designed by the use of multi-component binders including alpha-type hemihydrate gypsum a for low-alkali type artificial reefs, and the printability was confirmed. A further study needs to be performed to quantitatively evaluate the alkali reduction effect.

• International Journal of Highway Engineering
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• v.11 no.2
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• pp.111-120
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• 2009

This paper presents a fundamental findings of the functional and structural performance of the porous asphalt concrete coated with MMA resin. To evaluate the structural performance, cantabro, wheel tracking, moisture sensitivity and indirect tensile fatigue tests are performed. The tests results show that the cantabro loss is reduced three times and fatigue resistance is significantly increased after the specimens are coated with MMA resin. However there are little changes in the rutting and moisture damage resistances before and after the coating. Air voids, permeability and BPT(British Pendulum Test) tests are conducted to study the functional performance. It is observed form the tests that the air voids and permeability are slightly decreased after the coating. However, the changes in the air voids and permeability are negligible. The skid resistance of the coated specimens is lower than reference specimens. However, the skid resistance is maintained beyond the level of the reference specimens when silica sands are chipped on top of the coated surface.

• Journal of the Korea Concrete Institute
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• v.23 no.4
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• pp.441-448
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• 2011

In this study, experimental tests of chemical and autogenous shrinkage were performed to evaluate the early age shrinkage behaviors of ultra high performance cementitious composites (UHPCC) with various replacement ratios of silica fume (SF), shrinkage reducing agent (SRA), expansive admixture (EA), and superplasticizer (SP). Starting time of self-desiccation, was analyzed by comparing the setting times and the deviated point of chemical and autogenous shrinkage strains. The test results indicated that both SF and SRA augment the early age chemical shrinkage, whereas SP delays the hydration reaction between cement particles and water, and reduces chemical shrinkage. About 49% of autogenous shrinkage was depleted by synergetic effect of SRA and EA. The hardening of UHPCC was catalyzed by containing EA. Self-desiccation of UHPCC occurred prior to the initial setting due to the high volume fraction of fibers and low water-binder ratio (W/B).

• Korean Journal of Materials Research
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• v.26 no.10
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• pp.549-555
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• 2016

We have investigated a glass-forming region of $V_2O_5-P_2O_5-ZnO$ glass and the effects of the addition of modifier oxides ($B_2O_3$) to the glass systems as a sealing material to improve the adhesion between the glass frits and a soda lime substrate. Thermal properties and coefficient of thermal expansion were measured using a differential scanning calorimetry, a dilatometer and a hot stage microscopy. Structural changes and interfacial reactions between the glass substrate and the glass frit after sintering (at $400^{\circ}C$ for 1 h) were measured by Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy and scanning electron microscope. The results showed that the adhesion strength increases as the content of $B_2O_3$ at 5 mol% increases because of changes in the structural properties. It seems that the glass structures change with $B_2O_3$, and the $Si^{4+}$ ions from the substrate are diffused to the sealing glass. From these results, we could understand the mechanism of strengthening of the adhesion of soda lime silica substrate by ion-diffusion from the substrate to the glass.

• Journal of the Korean Ceramic Society
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• v.30 no.6
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• pp.433-440
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• 1993

The bioactivity of glasses in the CaO-SiO2 system and CaO-P2O5-SiO2 system with less than 10mol% of P2O5 was investigated by in vitro test in simulated body flood(SBF). The formation of Ca.P film and hydroxyapatite on the surface of glasses after in vitro test was analysed by X-ray photoelectron spectoscopy (XPS), fourier transform infrared reflection spectroscopy (FT-IRRS), energy dispersive X-ray spectroscopy (EDS), and scanning electron microscopy (SEM) observation. In the early stage of Ca.P film formation after in vitro test for CaO-SiO2 and CaO-P2O5-SiO2 glasses, the rate of Ca.P film formation on the surface of the glasses was dependent of structural parameter (Y) evaluated from the glass composition. First, in the case of the glasses having Y value below 2, Ca.P film and SiO2-rich layer were formed simultaneously, and there were no differences of the rate of Ca.P film formation in terms of the Y values. Second, in the case of the glasses having Y value above 2, the SiO2-rich layer was formed, and then Ca.P.Si mixed layer was formed in the silica gel structure of the SiO2-rich layer, and finally the Ca.P film on the surface of SiO2-rich layer. The rate of Ca.P film formation delayed as the Y values increased. The rate of hydroxyapatite formation of glasses (the rate of transformation from Ca.P film to hydroxyapatite) seems to be propotional to the rate of Ca.P film formation and Y value. The rate of hydroxyapatite formation of glasses belonging to the second group was delayed as structural parameter increased, and the hydroxyapatite crystal showed spherical growth in the early reaction stage, and then showed silkworm-like linear growth as the reaction time increased.

• Journal of the Korea institute for structural maintenance and inspection
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• v.22 no.5
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• pp.127-132
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• 2018

The amount of generated Circulating Fluidized Bed Combustion ash (CFBC ash) is annually increasing, but most CFBC ash has been landfilled and discarded due to the limited utilization. The major chemical compositions of CFBC ash are $SiO_2$, CaO and $CaSO_4$, which could form hydration products by reacting with water as self-cementing property such as cement. The purpose of the this study is to derive the optimal mix proportions to improve polymer-modified mortar with the use of CFBC ash which has the self-cementing property. In order to develop polymer-modified mortar, three mix proportions were determined, and fundamental properties for the mixtures were obtained. As a result, the optimal mixture containing 10 percent of silica fume, 1.0 percent of polymer and 3.5 percent of expansive additives were proposed in this study.