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http://dx.doi.org/10.3740/MRSK.2016.26.10.549

Effect of B2O3 Addition on Thermal, Structure, and Sealing Properties V2O5-P2O5-ZnO Glass  

Sung, Aram (Department of Materials Science and Engineering, Inha University)
Kim, Yurian (Department of Materials Science and Engineering, Inha University)
Kim, Hyungsun (Department of Materials Science and Engineering, Inha University)
Publication Information
Korean Journal of Materials Research / v.26, no.10, 2016 , pp. 549-555 More about this Journal
Abstract
We have investigated a glass-forming region of $V_2O_5-P_2O_5-ZnO$ glass and the effects of the addition of modifier oxides ($B_2O_3$) to the glass systems as a sealing material to improve the adhesion between the glass frits and a soda lime substrate. Thermal properties and coefficient of thermal expansion were measured using a differential scanning calorimetry, a dilatometer and a hot stage microscopy. Structural changes and interfacial reactions between the glass substrate and the glass frit after sintering (at $400^{\circ}C$ for 1 h) were measured by Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy and scanning electron microscope. The results showed that the adhesion strength increases as the content of $B_2O_3$ at 5 mol% increases because of changes in the structural properties. It seems that the glass structures change with $B_2O_3$, and the $Si^{4+}$ ions from the substrate are diffused to the sealing glass. From these results, we could understand the mechanism of strengthening of the adhesion of soda lime silica substrate by ion-diffusion from the substrate to the glass.
Keywords
glass sealing; vanadate glass; thermal properties; adhesion; glass substrate.;
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