• Title/Summary/Keyword: structural reaction

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Mapping Between Models for Pathway Dynamics and Structural Representations of Biological Pathways

  • Yavas, Gokhan;Ozsoyoglu, Z. Meral
    • Proceedings of the Korean Society for Bioinformatics Conference
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    • 2005.09a
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    • pp.415-420
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    • 2005
  • Mathematical modeling and simulation of biochemical reaction networks gained a lot of attention recently since it can provide valuable insights into the interrelationships and interactions of genes, proteins and metabolites in a reaction network. A number of attempts have been made for modeling and storing biochemical reaction networks without their dynamical properties but unfortunately storing and efficiently querying of the dynamic (mathematical) models are not yet studied extensively. In this paper, we present a novel nested relational data schema to store a pathway with its dynamic properties. We then show how to make the mapping between this dynamic pathway schema with the corresponding static pathway representation.

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Synthesis of Graphene Oxide Based CuOx Nanocomposites and Application for C-N Cross Coupling Reaction

  • Choi, Jong Hoon;Park, Joon B.
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.176.1-176.1
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    • 2014
  • Graphene has attracted an increasing attention due to its extraordinary electronic, mechanical, and thermal properties. Especially, the two dimensional (2D) sheet of graphene with an extremely high surface to volume ratio has a great potential in the preparation of multifunctional nanomaterials, as 2D supports to host metal nanoparticles (NPs). Copper oxide is widely used in various areas as antifouling paint, p-type semiconductor, dry cell batteries, and catalysts. Although the copper oxide(II) has been well known for efficient catalyst in C-N cross-coupling reaction, copper oxide(I) has not been highlighted. In this research, CuO and Cu2O nanoparticles (NPs) dispersed on the surface of grapehene oxide (GO) have been synthesized by impregnation method and their morphological and electronic structures have been systemically investigated using TEM, XRD, and XAFS. We demonstrate that both CuO and Cu2O on graphene presents efficient catalytic performance toward C-N cross coupling reaction. The detailed structural difference between CuO and Cu2O NPs and their effect on catalytic performance are discussed.

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Dynamic Stress Analysis of Structural Connection using FRF-based Substructuring Method (구조물의 연결부에서 전달함수합성법을 이용한 동응력 해석)

  • 공태식;김찬묵;이두호;서세영
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2002.05a
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    • pp.1195-1201
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    • 2002
  • Researches on the FRF-based substructuring method have been mainly focused on vibratory response analysis. Present study Is concerned about the application of the method to the dynamic stress analysis of a air-conditioner compressor mounting bracket in a passenger car. This is performed by using reaction forces that can be obtained by the FRF-based substructuring method. The air-conditioner system, composed of a compressor and bracket, Is analyzed by using the FRF-based substructuring method. The experimental and numerical FRFs are combined to calculate the system responses and reaction forces at the connection point. The dynamic reaction forces plugged into the bracket FE model to compute the stresses of the bracket Dynamic strains by the present method are compared with those from strain-gage test for bracket system on shaker. The comparison shows possibility of practical usage of the method for the real problem

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A Study on the Firing Reaction and Calcination Characteristics of Waste Shellfish (폐 패각류의 소성 및 하소 특성에 관한 연구)

  • Yoon, Cheol-Hun
    • Journal of the Korean Applied Science and Technology
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    • v.21 no.4
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    • pp.352-358
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    • 2004
  • The firing reaction and calcination characteristics of the waste shellfish were examined for the future use as absorbent. The weight variation was measured according to thermal-decomposition using TGA and observed variation of the phase. The qualitative and quantitative analysis of the sample were performed using XRD and the structural analysis, SEM. The results of TGA and XRD experiments showed that the almost all of the raw Corbicula Japonica and Ostrea virginjca were changed from calcite to lime by firing and calcination reaction. The result of SEM experiment showed that the plate type of the raw sample was changed to circle type, so the surface area ratio was increased. Above results suggested that waste shellfish were usable as absorbent in the viewpoint of the reuse of resource and the decrease of environmental pollution.

The Reaction between Organothioenamine Phosphonate and Styrene Oxide (유기 티오엔아민 포스포네이트와 산화스티렌과의 반응)

  • Keun Jae Kim;Chi Sun Han
    • Journal of the Korean Chemical Society
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    • v.20 no.4
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    • pp.295-298
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    • 1976
  • The fact that a reaction between organothioenamine phosphonate and styrene oxide produces a derivative of cyclopropane has been proved by structural identification. This suggests that an anionic oxygen atom from the ring opening of the styrene oxide by nucleophilic attack of thioenamine phosphonate links to the phosphorous atom to from a betaine as an intermediate which is followed by cleavage of the weak P-C bond. The dextrorotatory optical activity of the product showed that the reaction was under the control of steric stability of the benzyl carbon in styrene which leads to the product through a sterically stable pathway.

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Studies on Tropolones (Ⅲ) Structures and Reaction Mechanisms of the Adducts of Dichloroketene and Cyclopentadienes (Tropolone 類에 關한 硏究 (III) Dichloroketene과 Cyclopentadiene 類의 添加物의 構造와 그 反應機構)

  • Jae Hu Shim
    • Journal of the Korean Chemical Society
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    • v.13 no.1
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    • pp.89-95
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    • 1969
  • The structural investigations on the adducts, formed from dichloroketene with cyclopentadiene, methyl and ethylcyclopentadiene, have been carried out by means of infrared and nuclear magnetic resonance spectroscopy and also by their chemical behaviors. It was confirmed by this study that the adducts were formed by 1, 2-cycloaddition reaction and had the fundamental structure of bicyclo [3. 2. 0]-7,7-dichloro-2-heptene-6-one. These results were well agreed with the hypothesis that a diradical intermediate was formed as the first step in 1, 2-cycloaddition. The reaction mechanism for the process in which tropolones were formed from these adducts was also discussed.

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Synthesis of Heteroarylferrocenes by FriedlanderReaction and Their Spectral Properties

  • Lee, Woo-Jin;Chea, Jong-Myoung;Jahng, Yurng-Dong
    • Bulletin of the Korean Chemical Society
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    • v.30 no.12
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    • pp.3061-3065
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    • 2009
  • A series of mono- and 1,1'-bis(heteroaryl)-substituted ferrocenes were prepared by employing Frielander reaction of acetyl- and 1,1'-diacetylferrocene with a series of o-aminoaldehydes. Reactions of 1,1'-diacetylferrocene with two equivalents of 1-aminonaphthalene-2-carbaldehyde and 8-aminoquinoline-7-carbaldehyde afforded a mixture of mono- and 1,1'-bis(heteroaryl)-substituted ferrocenes in a ratio of 1 : 3.1 - 3.8, while the reaction with 4-aminoacridine-3-carbaldehyde did not provide any characterizable product presumably due to the redox instability of the product induced by low reduction potential of benzo[b]-1,10-phenanthroline. Structural and optical properties of the compounds prepared were described.

Analysis of elastic foundation plates with internal and perimetric stiffening beams on elastic foundations by using Finite Differences Method

  • Orbanich, C.J.;Ortega, N.F.
    • Structural Engineering and Mechanics
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    • v.45 no.2
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    • pp.169-182
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    • 2013
  • The mechanical behavior of rectangular foundation plates with perimetric beams and internal stiffening beams of the plate is herein analyzed, taking the foundation design into account. A series of dimensionless parameters related to the geometry of the studied elements were defined. In order to generalize the problem statement, an initial settlements was considered. A numeric procedure was developed for the resolution by means of the Finite Differences Method that takes into account the stiffness of the plate, the perimetric and internal plate beams and the soil reaction module. Iterative algorithms were employed which, for each of the analyzed cases, made it possible to find displacements and reaction percentages taken by the plate and those that discharge directly into the perimetric beams, practically without affecting the plate. To enhance its mechanical behavior the internal stiffening beams were prestressed and the results obtained with and without prestressing were compared. This analysis was made considering the load conditions and the soil reaction module constant.

Synthesis of Hole Transport Materials for Organic Light Emitting Device (유기발광디바이스용 정공수송재료의 합성)

  • Chung, Pyung-Jin;Cho, Min-Ju
    • Korean Journal of Materials Research
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    • v.15 no.7
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    • pp.448-452
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    • 2005
  • This study was based on organic electroluminescence display. Especially, TPD and $\alpha-NPD$ for the hole transport materials were synthesized by Ullmann reaction. This reaction was conducted between 3­methylphenylamine, 1-naphthylamine and 4,4'-diiodobiphenyl in toluene containing CuCl catalyst and KOH base. The structural property of reaction products were analyzed by FT-IR, $^1H-NMR$ spectroscopy, and thermal stability, reactivity and PL property were analyzed by melting point, yield and emission spectrum, respectively. The photoluminescence spectra of a pure TPD and $\alpha-NPD$ were observed at approximately 416nm and 438nm respectively. In this study, it was known that the melting point, yield, PL properties of TPD and $\alpha-NPD$ were changed by substituent group of amines.

Study on Transient Structural Load Analysis of Aircraft Suspension Equipment (항공기용 서스펜션 장비의 천이구조하중해석에 대한 연구)

  • Cha, Jinhyun;Chung, Sangjun;Choi, Kwanho
    • Journal of Aerospace System Engineering
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    • v.9 no.3
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    • pp.23-30
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    • 2015
  • In this study, a transient structural load analysis system was constructed to calculate the applied load on the suspension equipment corresponding to the aircraft flight conditions based on military specifications. Aircraft flight data (altitude, velocity, acceleration, angle of attack and etc. at aircraft center of gravity) were used as input parameters and the calculated load of the suspension equipment at wings on the left and right side was printed out for the structural load analysis. As a calculation procedure, first of all, load analysis was carried out at the center of gravity of the external store, Secondly, a trial reaction force analysis was conducted on hook and swaybrace of suspension equipment. All procedure of calculations was programed to analyze the structural load automatically. To verify the numerical results, structural load analysis using the experimental flight data was performed.