• Title/Summary/Keyword: structural characteristic

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Spectroscopic characterization of N,N'-bis(salicylidene)pentane-1,3-diamine nickel(II) complex

  • Kim, Gilhoon;Won, Hoshik
    • Journal of the Korean Magnetic Resonance Society
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    • v.18 no.2
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    • pp.74-81
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    • 2014
  • The $N_2O_2$ tetradentate Schiff base ligand, N,N'-bis(salicylidene)pentane-1,3-diamine (Salpn), coupled with 1:2 concentration ratio of 1,3-diaminopentane and salicylaldehyde was used to produce a series of macrocyclic Nikel(II) complexes. In the metal complexation, it was observed that Salpn macrocyclic ligand can adopt more than a metal ion giving an unique multinuclear metal complexes including Ni(II)Salpn and $Ni(II)_3(Salpn)_2$. Characteristic IR ${\upsilon}(M-O)$ peaks for Ni(II)Salpn and $Ni(II)_3(Salpn)_2$ were observed to be $1028cm^{-1}$ and $1024cm^{-1}$, respectively. Characteristic UV-Vis absorption ${\lambda}_{max}$ peaks for $Ni(II)_3(Salpn)_2$ were observed to be 241nm and 401 nm. Structural characterization of $Ni(II)_3(Salpn)_2$ by NMR exhibits that the salicylidene ring moiety has two different resonance signals originated from the magnetically asymmetric diligand and trinuclear bis complex. Complete NMR signal assignments and characterizations elucidating structural features of $Ni(II)_3(Salpn)_2$ were described in detail.

A Study on the Nonlinear Instability Behavior of Hybrid Structures(I) - Characteristic of Static In-Plane Torsional Buckling by Initial Shape Imperfection- (Hybrid 구조물의 비선형 불안정 거동에 관한 연구(I) -초기형상 불완전에 의한 정적 면내비틀림 좌굴 특성-)

  • Kim, Seung Deog;Son, Su Deok;Kim, Hyung Seok;Kang, Moon Myung
    • Journal of Korean Society of Steel Construction
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    • v.13 no.5
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    • pp.587-597
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    • 2001
  • The structural system that discreterized continuous shells is frequently used to make dome-type structures and these structures show the unstable phenomena by snap-through or bifurcation when a load level reaches certain critical value. The characteristic structural behaviour of a cable dome shows a strong nonlinearity and very sensitive according to the initial imperfection. In this study the shape finding problem by applying initial tension stress is investigated and using this the unstable phenomena of perfectly shaped and initially imperfected shape model by external forces are examined to grasp the unstable behavior of cable dome using the Geiger-type model.

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Design and Impact Testing of Cylindrical Composite-Antenna-Structures having High Mechanical Performanc (기계적 특성이 우수한 원통형 복합재료 안테나의 설계 및 충격 실험)

  • Kim, Dong-Seop;Jo, Sang-Hyeon;Hwang, Un-Bong;Lee, Jung-Hui
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2005.11a
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    • pp.35-38
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    • 2005
  • The Objective of this work was to design Composite Antenna Structures (CAS) and investigate impact behavior of CAS which was various curvature. This term, CAS, indicates that structural surface becomes antenna. Constituent materials were selected considering electrical properties, dielectric constants and tangent loss as well as mechanical properties. For the antenna performance, microstrip antenna layers inserted into structural layers were designed for satellite communication at the resonant frequency of 12.5 GHz and final demonstration article was. After making five kinds of curved CAS, which radii of curvature are flat, 200, 150, 100, 50 mm. The antenna performance changed in accordance with variation of curvature. The Reflection coefficient was independent of curvature but the gain decreased with the radius of curvature. The impact test equipment was Dyna-8250 drop weight tester. The impact characteristic in accordance with curvature is maximum absorb energy is same each other. The impact energy was 8.5 J. For various Impact energy test, five energy levels 3 J, 5 J, 7 J, 10 J, 20 J were used. The performance of impact damaged antenna was estimated by measuring the return loss and the radiation pattern. It was revealed that the performance of antenna was not related to the impact damage. Because the impactor did not damage the patch directly. CAS have good impact stability for the antenna performance.

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Seismic Performance Evaluation of Cone-type Friction Pendulum Bearing System Using Shaking Table Test (진동대실험을 통한 원추형 마찰진자베어링의 내진성능 평가)

  • Jeon, Bub-Gyu;Chang, Sung-Jin;Kim, Nam-Sik
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2011.04a
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    • pp.389-394
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    • 2011
  • Existing FPS(Friction Pendulum System) is isolation system which is possible to isolate structures by pendulum characteristic from ground vibration. Structural natural frequency could be decided by designing the radius of curvature of FPS. Thus, response vibration could be reduced by changing natural frequency of structures from FPS. But effective periods of recorded seismic wave were various and estimation of earthquake characteristic could be difficult. If effective periods of seismic wave correspond to natural frequency of structures with FPS, resonance can be occurred. Therefore, CFPBS(Cone-type Friction Pendulum Bearing System) was developed for controlling the response acceleration and displacement by the slope of friction surfaces. Structural natural frequency with CFPBS can be changed according to position of ball on the friction surface which was designed cone-type. Therefore, Divergence of response could be controlled by CFPBS which had constantly changing natural frequency with low modal participation factor in wide-range. In this study, Seismic performance of CFPBS was evaluated by numerical analysis and shaking table test.

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Dynamic Characteristic Analysis of Water Jet Loom Driving System (워터제트직기 구동시스템의 동특성 해석)

  • Kim, Sang-Yoon;Park, Dae-Kyu;Chun, Du-Hwan;Park, Myung-Kyu
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.21 no.5
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    • pp.459-464
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    • 2008
  • While high speed / precision investigating for maximization of Textile Machinery business is requesting a machine which has highly endurance, stability and reliance abilities following customer request. In this research, load volume that gives influence on loom is measured and analyzed for water jet loom in real operation time to driving system adhered torque sensor to each a module. As well, measurement and analysis technology are developed about torque and vibration of driving systems for textile machinery by comparing dynamical analysis of water jet loom with gained result, basic materials about development of high value added textile machinery which has endurance and stability are presented.