• Title/Summary/Keyword: state assignment

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The Formation of Metal (M=Co(II), Ni(II), and Cu(II)) Complexes by Aminosilanes Immobilized within Mesoporous Molecular Sieves

  • 박동호;박성수;최상준
    • Bulletin of the Korean Chemical Society
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    • v.20 no.3
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    • pp.291-296
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    • 1999
  • The immobilization of APTMS(3-(2-aminoethylamino)propyltrimethoxysilane) and AAPTMS(3-(2-(2-aminoethyl)aminoethylanino)propyltrimethoxysilane) on the surface of high quality mesoporous molecular sieves MCM-41 and MCM-48 have been confirmed by F.T.-IR spectroscopy, Raman spectroscopy, 29Si solid state NMR, and a surface polarity measurement using Reichardt's dye. The formation of metal (Co(Ⅱ), Ni(Ⅱ), and Cu(Ⅱ)) complexes by immobilized aminosilanes have been investigated by photoacoustic spectroscopy(PAS). The assignment of UV-Vis. PAS bands makes it possible to identify the structure of metal complexes within mesoporous molecular sieves. Co(Ⅱ) ion may be coordinated mainly in a tetrahedral symmetry by two APTMS onto MCM-41, and in an octahedral one by two AAPTMS. Both Ni(Ⅱ) and Cu(Ⅱ) coordinated by aminosilanes within MCM-41 form possibly the octahedral complexes such as [Ni(APTMS)2(H20)2]2+, [Ni(AAPTMS)2]2+, [Cu(APTMS)2(H2O)2]2+, and [Cu(AAPTMS)(H2O)3]2+, respectively. The PAS band shapes of complexes onto MCM-48 are similar to those of corresponding MCM-41 with the variation of PAS intensity. Most of metal ion(Ⅱ) within MCM-41 and MCM-48 are coordinated by aminosilanes without the impregnation on the surface.

Improvement of State Ownership of Excavated Cultural Heritage System and Establishment of Policy Direction (발굴매장문화재 국가귀속제도의 정책 개선방안 연구)

  • Kim, Jong soo
    • Korean Journal of Heritage: History & Science
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    • v.49 no.1
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    • pp.22-43
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    • 2016
  • State Ownership of Excavated Cultural Heritage System was originated from the legislations concerning cultural objects during the Japanese colonial period (1910~1945) and was succeeded by the present Buried Cultural Properties Act enacted in 2011. Despite the importance of the system that completes the outcomes of excavations and determines the state-owned cultural properties, the foundation of national heritage, it has been limitedly regarded as administrative area and neglected by the academic scholars or policy researchers. Recently the traditional culture has drawn increasing domestic interest and awareness that the cultural heritage contributes to building cultural identity and vitalizing tourism has led to increasing the demand of a local government's role in management of the state-designated cultural heritage and even fighting for hegemony in securing the cultural objects between the central and local governments. Despite the continuing efforts for improving the selection process of cultural heritage and its management institution, establishment of an advanced objective system has been requested. This paper is intended to suggest the policy direction through demonstrating the problem and assignment caused in the process of implementing the Buried Cultural Properties Act and reviews the State Ownership of Excavated Cultural Heritage System from the legal point of view accordingly. First, I suggest improving the selection process of the state-owned cultural properties. Even though current law states that Administrator of Cultural Heritage Administration reviews the research reports and selects the possible candidates for the state-owned cultural properties almost all the cultural objects listed on the reports are practically selected. In this regard, two possible resolutions can be made; newly establishing a separate process for selecting the state-owned cultural properties after publishing the report or adding the selection process of the state-owned cultural properties during the heritage selection meeting. Either way should contribute to strengthening the impartiality and objectivity of the policy. My second suggestion is improving the operating system of the heritage selection meeting in which the cultural properties to be listed on the reports are determined. Given the present extensive assessment criteria, there is much room for certain experts' subjective opinions. Therefore, in order to enhance the fairness and credibility of the heritage selection meeting, specifying the assessment criteria and advance review of the expert list are necessary. Third, this paper suggests increasing the local government's role in management of the state-owned cultural heritage and diversifying the heritage management institution. Development of a local self-governing system has led to the increased demand for delegating the authority of the state-owned heritage management to the local governments. Along with this, the gradual improvements of public museum management raises the need for expanding the cultural benefits through increasing the local government's role in management of the state-owned heritage. Considering the fact that overall majority of the art collections housed at national or public museums is owned by the central government, developing a variety of heritage contents and vitalizing the heritage tourism are crucial. The true meaning and value of the state-owned cultural heritage hidden at the storage of a museum can be found when they are shared together with the public.

Performance Analysis of a Statistical Packet Voice/Data Multiplexer (통계적 패킷 음성 / 데이터 다중화기의 성능 해석)

  • 신병철;은종관
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.11 no.3
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    • pp.179-196
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    • 1986
  • In this paper, the peformance of a statistical packet voice/data multiplexer is studied. In ths study we assume that in the packet voice/data multiplexer two separate finite queues are used for voice and data traffics, and that voice traffic gets priority over data. For the performance analysis we divide the output link of the multiplexer into a sequence of time slots. The voice signal is modeled as an (M+1) - state Markov process, M being the packet generation period in slots. As for the data traffic, it is modeled by a simple Poisson process. In our discrete time domain analysis, the queueing behavior of voice traffic is little affected by the data traffic since voice signal has priority over data. Therefore, we first analyze the queueing behavior of voice traffic, and then using the result, we study the queueing behavior of data traffic. For the packet voice multiplexer, both inpur state and voice buffer occupancy are formulated by a two-dimensional Markov chain. For the integrated voice/data multiplexer we use a three-dimensional Markov chain that represents the input voice state and the buffer occupancies of voice and data. With these models, the numerical results for the performance have been obtained by the Gauss-Seidel iteration method. The analytical results have been verified by computer simylation. From the results we have found that there exist tradeoffs among the number of voice users, output link capacity, voic queue size and overflow probability for the voice traffic, and also exist tradeoffs among traffic load, data queue size and oveflow probability for the data traffic. Also, there exists a tradeoff between the performance of voice and data traffics for given inpur traffics and link capacity. In addition, it has been found that the average queueing delay of data traffic is longer than the maximum buffer size, when the gain of time assignment speech interpolation(TASI) is more than two and the number of voice users is small.

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A WATM MAC Protocol for the Efficient Transmission of Voice Traffic in the Multimedia Environment (멀티미디어 환경에서 효율적인 음성 전송을 위한 WATM MAC 프로토콜)

  • 민구봉;최덕규;김종권
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.25 no.1A
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    • pp.96-103
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    • 2000
  • The voice traffic is one of the most important real-time objects in WATM(Wireless Asynchronous Transfer Mode) networks. In this paper, we propose a new MAC(Medium Access'Control) protocol for the efficienttransmission of voice traffic over WATM networks in the multimedia environment and compare the performanceto existing similar protocols. The new protocol separates the reservation slot period for voice and that for data toguarantee some level of QoS(Quality of Service) in voice traffic. This is denoted by a slot assignment functiondepending on the frame size. According to the characteristics of voice traffic which is repeatedly in silent states,the protocol allocates voice reservation request slots dynamically with respect to the number of silent(off state)voice sources and also sends the first block of talkspurt restarted after silent period with a reservation requestslot to reduce the access delay.The simulation results show that the proposed protocol has better performance than Slotted Aloha in bandwidthefficiency, and can serve a certain level of QoS by the given slot assignment function even when the number ofvoice terminals varies dynamically. This means we can observe that the new MAC protocol is much better thanthe NC-PRMA(None Collision-Packet Reservation Multiple Access) protocol.

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A Study on Inspection Status of Port State Control and Improvement Measures in Korea (우리나라 항만국통제 점검 실태와 문제점 개선에 관한 연구)

  • Kim, Sun-Tai;Gang, Sang-Geun;Jeong, Jae-Yong;Kim, Deug-Bong
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.20 no.6
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    • pp.671-676
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    • 2014
  • Based on the data of PSC information management system of MOF(Ministry of oceans and fisheries) and APCIS(Asia-Pacific Computerized Information System) of Tokyo-MOU information system, the result of the evaluation on the reality of PSC was done, and base on 2009, it showed a trend of decrease in every DFR(Deficiency Rate) and DTR(Detention Rate). But for vessels built for more than 30 years, flags of convenience vessels, RO-RO ferry and general cargo vessel, small size vessels with gross tonnage less than 1,000 ton showed a high DFR and DTR. Each harbours is classified by the total harbours' average DFR which was 82.5 % and the average DTR was 5.1 %, excluding the Jeju harbour, showing a hugh deviation for classification of each harbour. Classification of each harbour has to be inspected by PSC and it showed a great unbalance of the number of vessels for each territory for inspection. the biggest problem with our country's PSC, where it was pointed out by the PSCO was lack of workers and independent inspection by just one worker. To strength the substantiality of the inspection of our country is to have concentrated inspection on the high risk cautious vessels, forming a human network each classified by four different sectors of the area, recalculating the amount of assignment of inspection classified by each harbour and securing workforce the PSCO improvements are necessary.

A Study on the Storage Allocation of Container in Automated Container Terminals (자동화 컨테이너터미널에서 컨테이너의 장치 위치 결정에 관한 연구)

  • Jung Bong Jin;Choi Hyung Rim;Park Nam Kyu;Kwon Rae Kyoung
    • Proceedings of the Korean Institute of Navigation and Port Research Conference
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    • 2004.11a
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    • pp.281-286
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    • 2004
  • It's important to operate the yard for improving to the productivity in container terminal effectively. Because the automated container terminal(ACT) has storage yard of automation and horizon, it's character is different from conventional terminal. As the automation yard in ACT is operated by the automated equipments, it needs to an efficient storage plan which is connected the automated equipment, the external truck, the shipment etc.. Hut the traditional method of storage plan is the space assignment problem. The efficiency of yard decreases and it is brought about increase of shipment time, because real-time automated equipments and present yard status is not reflected in. In order to solve this problems, we propose the algorithm for real-time storage location of container considering shipment plan, yard status and the state of ATC.

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Short-Time Production Scheduling and Parts Routing for Flexible Assembly Lines (유연한 조립 시스템의 단기 생산 스케듈링과 라우팅에 관한 연구)

  • Sin, Ok-Geun
    • The Transactions of the Korea Information Processing Society
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    • v.2 no.6
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    • pp.823-830
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    • 1995
  • A reactive piloting policy for Flexible Assembly Lines (FAL) is proposed, where the sequencing of the operations as well as the assignment of tasks to manipulators are not predetermined but driven by the actual state of the FAL For all work-in-process coming from a manipulator, the next destination is determined by minimizing a temporal criterion taking into account the time needed to reach the destination, the load of the manipulator to reach, the durati on of the operation to be completed in the destination manipulator, and the availability of product components in this manipulator. The purpose of proposed piloting policy is to manufacture a given quantity of products as rapidly as possible by balancing the amount of work allocated to manipulators and to reduce the efforts required for scheduling the production of short series of diversified products. After introducing the characteristics of assembly processes and FAL modelization, the proposed algorithm is evaluated by simulations. The simulations of the proposed algorithm showed satisfactory results.

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SPECTROSCOPIC AND CHEMOMETRIC ANALYSIS OF SW-NIR SPECTRA OF SUGARS AND FRUITS

  • Golic, Mirta;Walsh, Kerry;Lawson, Peter
    • Proceedings of the Korean Society of Near Infrared Spectroscopy Conference
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    • 2001.06a
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    • pp.1133-1133
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    • 2001
  • Fruit sweetness, as indexed by total soluble solids (TSS), and fruit acidity are key factors in the description of the fruit eating quality. Our group has been using short wave NIR spectroscopy (SW-NIR; 700-1100 nm) in combination with chemometric methods (PLS and MLR) for the non-invasive determination of the fruit eating quality (1,2). In order to further improve calibration performance, we have investigated SW-NIR spectra of sucrose and D-glucose. In previous reports on the band assignment for these sugars in the 1100-2500 nm spectral region (3-7), it has been established that change in concentration, temperature and physical state of sugars reflects on the shape and position of the spectral bands in the whole NIR region(5-7). The effect of change in concentration and temperature of individual sugar solutions and sugar spiked Juice samples was analysed using combined spectroscopic (derivative, difference, 2D spectroscopy) and linear regression chemometric (PLS, MLR) techniques. The results have been compared with the spectral data of a range of fruit types, varying in TSS content and temperature. In the 800-950 nm spectral region, the B-coefficients for apples, peaches and nectarines resemble those generated in a calibration of pure sucrose in water (Fig. 1). As expected, these fruits exhibit better calibration and prediction results than those in which the B-coefficients were poorly related to those for sugar.(Figure omitted).

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A Study on Smoking Area Guidelines that Respect the Rights of the People - With a Focus on Independent Outdoor Smoking Areas - (국민 권리존중을 위한 흡연공간 가이드라인 연구 - 실외 독립형을 중심으로 -)

  • Lee, Byoung-Ho
    • Korean Institute of Interior Design Journal
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    • v.22 no.3
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    • pp.154-163
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    • 2013
  • Current principles of designating a smoking area within a non-smoking area rely on mere compartmentalization. This causes non-smokers aversion against smokers and smokers complaints about anti-smoking policies, which means both of them are not satisfied with the current scheme. In addition, such a system, far from the original intent of the law, does not provide appropriate respect for people's rights. The biggest problem of the current scheme is that smoking areas are not separated from non-smoking areas. Japan has continued installing independent smoking areas since 2002 and witnessed a decrease in the smoking rate. The country's success is attributable to: the state's active intervention in connection with enterprises; continuous environmental improvements and creation of goods; 'smoking etiquette' campaigns; and the sociality and group consciousness of Japanese people. It is recognized that the synergy of the designation of independent smoking areas and such multi-faceted efforts has led to the nation's accomplishment. Hence, it is required to install independent smoking areas in non-smoking areas in Seoul in order to respect the rights of smokers and non-smokers and resolve conflicts between them. It is not suitable to merely model after Japan's case, however, studies and guidelines that are tailored to Korea's own environment and social atmosphere are required. To ensure that the people recognize the necessity for smoking areas, a social consensus is formed and proper smoking areas are established in a systemic manner, a system for that purpose should connote a symbol of the social consensus and consequent guidelines should take physical elements, human activities and semantic assignment into consideration. This study aims to present basic guidelines to install separated smoking areas, which will keep distance between smokers and non-smokers, form a social consensus and establish a sound smoking culture. These would ensure that the rights of both smokers and non-smokers are fully respected and that government policies are trusted by the people.

QoS-Aware Bounded Flooding RWA Algorithm in the Next Generation Optical Internet based on DWDM Networks (DWDM기반의 차세대 광인터넷에서 QoS 기반의 제한적 플러딩 RWA 알고리즘에 관한 연구)

  • Kim Yong-Seong;Lee Jae-Dong;Hwang Jin-Ho;Woo Chong-Ho
    • Journal of the Institute of Electronics Engineers of Korea TC
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    • v.43 no.8 s.350
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    • pp.1-14
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    • 2006
  • Multi-constraint QoS routing has been seen as crucial network property in the next generation optical Internet based on DWDM Networks. This paper proposes a new QoS routing algorithm based on flooding method, called bounded flooding routing (BFR) algorithm which can meet multi-constraint QoS requirements. Primarily, the BFR algorithm tries to reduce network overhead by accomplishing bounded-flooding to meet QoS requirements, and improve blocking probability and wavelength utilization. Also, as one effort to improve routing performance, we introduce a new concept, ripple count, which does not need any link-state information and computational process. For extensive analysis and simulation study, as a critical concern, in DWDM-based networks we deploy limited wavelength conversion capability within DWDM nodes. And the simulation results demonstrate that the BFR algorithm is superior to other predominant routing algorithms (both original flooding method and source-directed methods) in terms of blocking probability, wavelength channels required and overhead.