• Title/Summary/Keyword: standard SCR

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Optimal P-Well Design for ESD Protection Performance Improvement of NESCR (N-type Embedded SCR) device (NESCR 소자에서 정전기 보호 성능 향상을 위한 최적의 P-Well 구조 설계)

  • Yang, Jun-Won;Seo, Yong-Jin
    • Journal of Satellite, Information and Communications
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    • v.9 no.3
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    • pp.15-21
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    • 2014
  • An electrostatic discharge (ESD) protection device, so called, N-type embedded silicon controlled rectifier (NESCR), was analyzed for high voltage operating I/O applications. A conventional NESCR standard device shows typical SCR-like characteristics with extremely low snapback holding voltage, which may cause latch-up problem during normal operation. However, our modified NESCR_CPS_PPW device with proper junction/channel engineering such as counter pocket source (CPS) and partial P-well structure demonstrates highly latch-up immune current-voltage characteristics with high snapback holding voltage and on-resistance.

Characteristics of NOx and PN According to After-treatment for Light-duty Diesel Vehicles in WLTC Test Mode (WLTC 시험 모드에서 소형 경유자동차의 후처리 시스템에 따른 질소산화물 및 입자개수 배출 특성)

  • Lee, Dong In;Ko, Sangchul;Yu, Young Soo;Park, Junhong;Cha, Junepyo;Chon, Mun Soo
    • Journal of ILASS-Korea
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    • v.23 no.4
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    • pp.234-243
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    • 2018
  • Since September 2017, a small diesel vehicle certification test mode has been enhanced from NEDC to WLTC. The main reason for the change of the certification test mode is that the certification test mode of the emission control standard of the diesel vehicle does not sufficiently reflect various driving patterns of the actual roads. Several automakers have developed after-treatment systems such as LNT, SCR, and DPF to meet enhanced emissions regulations. In this study, four small diesel cars were selected for sale in Korea, and the exhaust gas measurement test was performed in the WLTC mode, which reflects the driving characteristics of the actual roads. As a result of test, LNT vehicle exceeded Euro 6 NOx regulation and SCR vehicle satisfied Euro 6 NOx regulation. In addition, both LNT and SCR systems showed high NOX emission characteristics due to speed, RPA and Vxa. For the PN, all test vehicles were fitted with a DPF and met the Euro 6 PN regulations, with similar PN emissions results in LNT and SCR system.

A Study of NH3 Adsorption/Desorption Characteristics and Model Based Control in the Urea-SCR System (Urea-SCR 시스템의 NH3 흡·탈착 특성 및 모델기반 제어 연구)

  • Ham, Yunyoung;Park, Suyeol
    • Transactions of the Korean Society of Automotive Engineers
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    • v.24 no.3
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    • pp.302-309
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    • 2016
  • Urea-SCR system is currently regarded as promising NOx reduction technology for diesel engines. SCR system has to achieve maximal NOx conversion in combination with minimal $NH_3$ slip. In this study, model based open loop control for urea injection was developed and assessed in the European Transient Cycle (ETC) for heavy duty diesel engine. On the basis of the transient modeling, the kinetic parameters of the $NH_3$ adsorption and desorption are calibrated with the experimental results performed over the zeolite based catalyst. $NH_3$ storage or surface coverage of SCR catalyst can not be measured directly and has to be calculated, which is taken into account as a control parameter in this model. In order to reduce $NH_3$ slip while maintaining NOx reduction, $NH_3$ storage control algorithm was applied to correct the basic urea quantity. If the actual $NH_3$ surface coverage is higher than the maximal $NH_3$ surface coverage, the urea injection quantity is significantly reduced in the ETC cycle. By applying this logic, the resulting $NH_3$ slip peak can be avoided effectively. With optimizing the kinetic parameters based on standard SCR reaction, it suggests that a simplified, less accurate model can be effective to evaluate the capability of model based control in the ETC cycle.

Comparison on Exhaust Gas of Heavy Duty Diesel Trucks; THC and CO Emission Affected by NOx Control Devices (EGR, SCR) (대형 경유트럭의 NOx 저감장치에 따른 배출가스 특성비교)

  • Mun, SunHee;Yoo, Heung-Min;Son, JiHwan;Yun, Changwan;Park, Gyu Tae;Kim, JeongSoo;Lee, Jongtae
    • Journal of ILASS-Korea
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    • v.20 no.3
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    • pp.149-155
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    • 2015
  • With increasing of GDP, the registration number of passenger cars has exceeded 20 million last year in Korea. Especially, the registration number of the diesel engine vehicles has been increasing. However, the WHO(World Health Organization) IARC (International Agency for Research on Cancer) has reported that diesel engine exhaust gas is an one of HAPs, which has carcinogenic for human, and they have designated it to Group 1. To solve this problem, exhaust gas from diesel engines has to be controlled. Thus, it has been controlling by European regulatory standard in Korea. On the other hand, in order to meet the enhanced emission regulations, all manufacturing company applied $NO_x$ control device to vehicles such as EGR (Exhaust Gas Recirculation), SCR (Selective Catalytic Reduction) and so on. However, these devices (EGR, SCR) were operated by difference reaction mechanism respectively, and the composition of exhaust gas would be differenced from that of them. In this study, it was conducted to evaluate variety characteristics on changing of exhaust gas composition by each $NO_x$ control device, and the heavy duty diesel trucks were chosen as experimental vehicles. From the result, it revealed that vehicles (with EGR) were discharged higher THC as 52.5% than that of others (with SCR). However, it did not followed that trend, in the case of CO; it was discharged as 57.2% lower than that of others (with SCR). In the future, these data would be used to apply to efficient $NO_x$ control device for meeting to EURO 6.

An Experimental Study on the NH3-SCR of NOx over a Vanadium-based Catlayst (바나듐 계열 촉매를 통한 NOx의 NH3-SCR에 관한 실험적 연구)

  • Jeong, Hee-Chan;Sim, Sung-Min;Kim, Young-Deuk;Jeong, Soo-Jin;Kim, Woo-Seung
    • Transactions of the Korean Society of Automotive Engineers
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    • v.20 no.1
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    • pp.20-27
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    • 2012
  • The $NH_3$-SCR characteristics of $NO_X$ over a V-based catalyst are experimentally examined over a wide range of operating conditions, i.e., $170-590^{\circ}C$ and $30,000-50,000h^{-1}$, with a simulated diesel exhaust containing $NH_3$, NO, $NO_2$, $O_2$, $H_2O$, and $N_2$. The influences of the space velocity and oxygen concentration on the standard-SCR reaction are analyzed, and it is shown that the low space velocity and high oxygen concentration promote the SCR activity by ammonia. The best $deNO_X$ efficiency is obtained with a $NO_2/NO_X$ ratio of 0.5 because of an enhanced chemical activity induced by the fast-SCR reaction, while at the $NO_2/NO_X$ ratios above 0.5 the $deNO_x$ activity decreases due to the slow-SCR reaction. The oxidation of ammonia begins to take place at about $300^{\circ}C$ and the reaction products, such as $N_2$, NO, $NO_2$, $N_2O$, and $H_2O$, are produced by the undesirable oxidation reactions of ammonia, particularly at high temperatures above $450^{\circ}C$. Also, $NO_2$ decomposes to NO and $O_2$ at temperatures above $240^{\circ}C$. Therefore, $NO_2$ decomposition and ammonia oxidation reactions deteriorate significantly the SCR catalytic activity at high temperatures.

An Experimental and Modeling Study on the Oxidation Kinetics of Nitric Oxide over Platinum-based Catalysts (백금계 촉매상에서 산화질소(NO)의 산화반응속도에 관한 실험 및 모델링 연구)

  • Kim, Young-Deuk;Jeong, Soo-Jin;Kim, Woo-Seung
    • Transactions of the Korean Society of Automotive Engineers
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    • v.20 no.5
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    • pp.71-80
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    • 2012
  • To improve the $NO_X$ conversion over a SCR (selective catalytic reduction) catalyst, the DOC (diesel oxidation catalyst) is usually placed upstream of the SCR catalyst to enhance the fast SCR reaction ($4NH_3+2NO+2NO_2{\rightarrow}4N_2+6H_2O$) using equimolar amounts of NO and $NO_2$. Here, a ratio of $NO_2/NO_X$ above 50% should be avoided, because the reaction with $NO_2$ only ($4NH_3+4NO+O_2{\rightarrow}4N_2+6H_2O$) is slower than the standard SCR reaction ($4NH_3+4NO+O_2{\rightarrow}4N_2+6H_2O$). In order to accurately predict the performance characteristics of SCR catalysts, it is therefore desired to develop a more simple and reliable mathematical and kinetic models on the oxidation kinetics of nitric oxide over a DOC. In the present work, the prediction accuracy and limit of three different chemical reaction kinetics models are presented to describe the chemicophysical characteristics and conversion performance of DOCs. Steady-state experiments with DOCs mounted on a light-duty four-cylinder 2.0-L turbocharged diesel engine then are performed, using an engine-dynamometer system to calibrate the kinetic parameters such as activation energies and preexponential factors of heterogeneous reactions. The reaction kinetics for NO oxidation over Pt-based catalysts is determined in conjunction with a transient one-dimensional (1D) heterogeneous plug flow reactor (PFR) model with diesel exhaust gas temperatures in the range of 115~$525^{\circ}C$ and space velocities in the range of $(0.4{\sim}6.5){\times}10^5\;h^{-1}$.

Study on the Optimal CPS Implant for Improved ESD Protection Performance of PMOS Pass Structure Embedded N-type SCR Device with Partial P-Well Structure (PMOS 소자가 삽입된 부분웰 구조의 N형 SCR 소자에서 정전기 보호 성능 향상을 위한 최적의 CPS 이온주입에 대한 연구)

  • Yang, Jun-Won;Seo, Yong-Jin
    • Journal of Satellite, Information and Communications
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    • v.10 no.4
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    • pp.1-5
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    • 2015
  • The ESD(electrostatic discharge) protection performance of PPS(PMOS pass structure) embedded N-type silicon controlled rectifier(NSCR_PPS) device with different partial p-well(PPW) structure was discussed for high voltage I/O applications. A conventional NSCR_PPS standard device shows typical SCR-like characteristics with low on-resistance, low snapback holding voltage and low thermal breakdown voltage, which may cause latch-up problem during normal operation. However, our proposed NSCR_PPS devices with modified PPW_PGM(primary gate middle) and optimal CPS(counter pocket source) implant demonstrate the stable ESD protection performance with high latch-up immunity.

Simulation-based ESD protection performance of modified DDD_NSCR device with counter pocket source structure for high voltage operating I/O application (고전압 동작용 I/O 응용을 위해 Counter Pocket Source 구조를 갖도록 변형된 DDD_NSCR 소자의 ESD 보호성능 시뮬레이션)

  • Seo, Yong-Jin;Yang, Jun-Won
    • Journal of Satellite, Information and Communications
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    • v.11 no.4
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    • pp.27-32
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    • 2016
  • A conventional double diffused drain n-type MOSFET (DDD_NMOS) device shows SCR behaviors with very low snapback holding voltage and latch-up problem during normal operation. However, a modified DDD_NMOS-based silicon controlled rectifier (DDD_NSCR_CPS) device with a counter pocket source (CPS) structure is proven to increase the snapback holding voltage and on-resistance compare to standard DDD_NSCR device, realizing an excellent electrostatic discharge protection performance and the stable latch-up immunity.

A Study on the Improvement in Productivity and Safetiness for Calcination Process of Automotive Catalyst by Using Design of Experiment (실험계획을 통한 자동차 촉매 소성 공정의 생산성 향상과 안정성 증대 연구)

  • Jung, Chule-kyou;Lee, Chang-Ho
    • Journal of the Korea Safety Management & Science
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    • v.21 no.1
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    • pp.17-23
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    • 2019
  • The diesel engine generate many pollutants such as PM(Particulate matter) and NOx(Nitrogen oxide). So the SCR(Selective catalytic reduction) must be required to meet the emission standard. The SCR catalyst market is growing rapidly, and the automobile markets using alternative energy sources are growing rapidly. This study deals with optimization of the calcination process the manufacturing process of SCR catalyst to be competitive. The calcination process is a bottleneck and it is required to optimize productivity and accept to be safety, But we cannot trade off anything in terms of safety. We applied DOE(Design of experiments) among many research methods performed in various fields. In order to achieve quality and productivity optimization. The dependent variables in the DOE were selected as NO Conversion(%). The independent variables were selected as the calcination temperature, soaking time and fan speed RPM. the CCD(Central composite designs) constructs response surface using the data onto experience and finds optimum levels within the fitted response surfaces. Our tests are our stability guarantee and efficient together with operation.

A Study on the Installation of SCR System for Generator Diesel Engine of Existing Ship (기존 선박의 디젤발전기용 SCR 시스템 설치에 관한 연구)

  • Ryu, Younghyun;Kim, Hongryeol;Cho, Gyubaek;Kim, Hongsuk;Nam, Jeonggil
    • Journal of Advanced Marine Engineering and Technology
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    • v.39 no.4
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    • pp.412-417
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    • 2015
  • The IMO MEPC has been increasingly strengthening the emission standard for marine environment protection. In particular, nitrogen oxide (NOx) emissions of all ocean-going ships built from 2016 will be required to comply with the Tier-III regulation. In this study, a vanadia based SCR (Selective Catalytic Reduction) system developed for ship application was installed on a diesel engine for power generation of the training ship T/S SAENURI in Mokpo National Maritime University. For the present study, the exhaust pipeline of the generator diesel engine was modified to fit the urea SCR system. This study investigated the NOx reduction performance according to the two kind of injection method of urea solution (40%): Auto mode through the PLC (Programable Logic Control) and Manual mode. We were able to find the ammonia slip conditions when in manual mode method. So, the optimal urea injection quantity can be controlled at each engine load (25, 35, 50%) condition. It was achieved 80% reduction on nitrogen oxide. Furthermore, we found that the NOx reduction performance was better with the load up-down (while down to 25% from 50%) than the load down-up (while up to 50% from 25%) test.