• 한국염색가공학회지
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• 제15권2호
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• pp.76-85
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• 2003

In this study, a continuous stabilization process is used to make high-performance carbon fiber from polyacrylonitrile(PAM)-based fibers. The effect of oxygen content of PAN-based fiber on the stabilization process and the properties of the resultant carbon fibers is investigated. In order to research the progress of stabilization reaction FT-IR, elemental analysis, density, DSC, etc are used. Stabilization is carried out in air atmosphere from the 200 to $300^\circ{C}$ temperature range. An increase of PAN-based fibers diameter reduces the oxygen content during the continuous stabilization process. A higher oxygen content increase the density, tensile strength and modulus in the resultant carbon fibers. The most appropriate oxygen content in the stabilized fiber should be about 12%. Fibers having more than 2% oxygen content yield carbon fibers with inferior properties. Those carbon fibers also have sufficient commercial availability.

• 방사선산업학회지
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• 제5권1호
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• pp.41-46
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• 2011

Polyacrylonitrile (PAN) fibers are the most widely used precursor of the materials for carbon fibers. The conventional process of carbon fibers from PAN precursor fiber includes two step; stabilization at low temperature and carbonization at high temperature. Compared to thermal stabilization, the stabilization process by electron beam (E-beam) irradiation is a advanced and brief method. However, a stabilization by E-beam irradiation was required a high dose (over 5,000 kGy) and spend over 1.5 hr (1.14 MeV, 1 mA). In the present work the main goal is exploring a quick stabilization process by cotrolling E-beam currents. The effect of various E-beam currents on stabilization of PAN precursor fiber was studied by gel fraction test, thermo gravimertic analysis (TGA), differential scanning calorimetry (DSC), tensile strength, and scanning electron microscopy (SEM) images.

• 접착 및 계면
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• 제14권1호
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• pp.21-27
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• 2013

셀룰로오스계 레이온섬유 또는 레이온직물은 좁은 온도범위의 안정화공정 동안에 열분해가 매우 빠르게 진행된다. 그러므로 레이온계 탄소섬유를 제조하는데 있어 안정화단계는 매우 중요한 핵심공정이다. 따라서 본 연구에서는 셀룰로오스계 레이온직물의 중량감소, 화학조성, 미세구조 및 texture 변화에 미치는 등온 안정화공정과 초음파세척의 영향을 조사하였다. $200{\sim}240^{\circ}C$ 영역에서 행한 등온 안정화공정의 온도는 레이온직물을 안정화 소요시간, 탄소함량, 산소함량, 셀룰로오스 구조 변화 그리고 직물 texture에 큰 영향을 주었다. 등온 안정화공정 전에 물을 이용한 초음파세척은 레이온직물의 안정화공정 시간을 단축하고, 안정화 후 직물의 탄소함량을 증가하고, 산소함량을 감소시키며, XRD 분석 패턴을 변화시키는데 역할을 하는 것으로 조사되었다. 또한 초음파세척은 등온 안정화공정시 발생하는 레이온직물의 빠른 중량감소 현상을 더디게 하고, 열수축을 감소시켜, 직물의 급격한 물리적 변화의 완화에도 기여하는 것으로 사료된다.

• Carbon letters
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• 제2권3_4호
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• pp.170-175
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• 2001

A petroleum-based isotropic pitch fiber spun by melt-blown method was oxidized in air flow at various conditions. The oxidized pitch fiber obtained was tested for its infusibility and its elemental composition during the process of stabilization. The structural changes were traced by using solvent solubility, FT-IR spectroscopy, and elemental analysis. The samples showed a gradual increase in weight with increasing the oxidization temperature. The weight gain of sample oxidized at $320^{\circ}C$ for 10 min was about 4.5%. The concentration of the pyridine and toluene soluble fraction decreased with an increase in stabilization temperatures. The oxygen uptaken in the stabilization process converted aliphatic side chains into the carbonyl groups. As stabilization proceeded, the more ether and carboxylic acid groups were formed through the oxidations of aldehyde and primary alcohol, and then the carboxylic acid was dehydrated to be aromatic anhydride.

• 한국전기전자재료학회논문지
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• 제35권2호
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• pp.172-177
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• 2022

The quench voltage of the second-generation superconducting wire is affected by the resistivity characteristics of the stabilization layer. The specific resistance of the stabilization layer can be changed by the deposition process using RF magnetron sputtering. In this paper, a thin film made of a homogeneous material (Ag) and a dissimilar material (Cu) was deposited on the stabilization layer of the second-generation superconducting wire through RF magnetron sputtering. We found that the specific resistance was reduced by increasing the thickness of the stabilization layer. The reduction in the resistivity of the stabilization layer led to a decrease in the quench voltage of the second-generation superconducting wire. We suggest that various characteristic changes of the second-generation superconducting wire can be expected through the successful change in the resistivity of the stabilization layer of the proposed deposition process.

• 산업경영시스템학회지
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• 제39권1호
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• pp.140-152
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• 2016

It is very important for the competitiveness and sustainable management of enterprises that the rapid changes in the managerial environments quickly and accurately are responded. For example, the large-scale investment accompanied by bad alternatives in accordance with misunderstanding of the managerial environments yields the huge cost and effort to modify and improve. In firm management, the quality of products and the productivity are influenced by changes of the endogenous factors yielded in manufacturing process and the exogenous factors as market, etc. These changes include not only changes in 4M (man, machine, material, method) but also those in the market, competitors, and technologies in the process of commodification, i.e., first, such disturbances make dispersion of the process big and odd. By Shewhart chart it can be checked that the process monitored is control-in or out. Business administration executes activities for input stabilization by monitoring changes in 4Ms, comparing with the standards, and taking measures for any abnormality. Second, TRM (technology road map) is to prospect product deployment and technological trend by predicting technologies in the competitive environment as the market, and to suggest the future directions of business. So, TRM must be modified and improved according to DR (design review) stages and changes in mass-production like input material change. Therefore, a role of TRM in input stabilization for reducing cost and man-hour is important. This study purposed to suggest that the environment changes are classified into endogenous factors and exogenous factors in production process, and then, quality and productivity should be stabilized efficiently through connection between TRM and input stabilization, and to prove that it is more effective for the display industry to connect TRM with input stabilization rather than to use TRM separately.

• 대한토목학회논문집
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• 제4권2호
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• pp.101-112
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• 1984

접촉안정법(接觸安定法)의 mechanism과 모델을 간단히 문헌검토하였다. 본(本) 연구(硏究)에서는 접촉안정법(接觸安定法)의 설계(設計)를 위한 순서(順序)와 더욱 합리적(合理的)이며 실용적(實用的)인 모델을 제안하였다. 이들 모델은 접촉조(接觸槽)에서의 MLSS 증가(增加)와 안정조(安定槽)에서의 MLSS 감소(減少)를 토대로 하여 시스템에 물질수지(物質收支)를 적용하여 유도하였다. 또한 제안된 모델들을 실험(實驗) data와 관련시켜 고찰(考察)하여 합리적(合理的)인 결과를 얻었다.

• 한국분말재료학회지
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• 제29권5호
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• pp.418-423
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• 2022

Carbon fibers (CFs) are considered promising composite materials for various applications. However, the high cost of CFs (as much as $26 per kg) limits their practical use in the automobile and energy industries. In this study, we developed a continuous stabilization process for manufacturing low-cost CFs. We employed a textile-grade polyacrylonitrile (PAN) fiber as a low-cost precursor and UV irradiation technique to shorten the thermal stabilization time. We confirmed that UV irradiation on the textile-grade PAN fibers could lower the initial thermal stabilization temperature and also lead to a higher reaction. These resulted in a shorter overall stabilization time and enhancement of the tensile properties of textile-grade PAN-based CFs. Our study found that only 70 min of stabilization time with UV irradiation was required to prepare textile-grade PAN-based low-cost CFs with a tensile strength of 2.37 ± 0.22 GPa and tensile modulus of 249 ± 5 GPa.

• 한국세라믹학회지
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• 제34권8호
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• pp.817-824
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• 1997

Stabilization is a key stage in the production of advanced carbon/carbon composites (ACC) from mesophase pitch, to render the mesophase infusible and the prevention of puffing during the subsequent carbonization. It is generally known that stabilization process as well as properties of mesophase pitch has a great deal of influence on the properties of the resultant ACC. Hence, it is possible to infer the properties of ACC by examing the stabilized mesophase pitch. In this study, extractions by solvents or acidified solvents extraction were carried out from the A-240 petroleum pitch. The extracted pitches were made into mesophase by heat treatments. Oxidative stabilization by air and non-oxidative stabilization by a chemical free radical initiator were performed. When a soluble polymer is fully stabilized, it should become insoluble in solvents. This phenomenon was used to estimated the degree of stabilization. The non-oxygen stabilized mesophase pitch powder was compared with the air stabilized mesophase pitch powder. FTIR provided additional information on the functional groups.

• 한국안전학회지
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• 제31권1호
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• pp.66-73
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• 2016

Lyocell fibers were used as a precursor in order to improve yield and strength of cellulose-based precursor while manufacturing activated carbon fiber(ACF). Lyocell fibers as a precursor for the preparation of ACF were surface-modified by reaction with 3-aminopropyltriethoxysilane(APTES) and pre-treated with KOH and H3PO4. Using aforementioned precursor, ACFs were prepared by a series of stabilization, carbonization and activation process at high temperatures. On each process, FT-IR, TGA, UTM and SEM were used to observe fibers' physical properties including structure and porous surfaces. FT-IR results proved that surface modification was achieved during stabilization, carbonization and activation process. TGA results during carbonization process found that surface modified fibers with APTES 0.02 mol(A2) showed higher thermostability, and extended pre-treatment increased yield. Especially, yield was found to have an increase of 10~20 wt% with surface modification during activation process. UTM results showed that tensile strength has the same order of concentration of APTES after surface modification, however, was found to show lower tensile strength than lyocell fibers after stabilization process. SEM results revealed that more homogeneous porosity control could be proceed after modifying the surface for the effective removal of hazardous substances.