• Journal of Photoscience
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• 제9권2호
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• pp.296-298
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• 2002

Irreversible photobleaching of bacteriorhodopsin (bR), namely denaturation induced by illumination of visible light, was investigated by absorption kinetic measurements. The denaturation kinetics revealed that light illumination significantly enhanced the structural decay of bR. The kinetic analyses showed that the molecular structure of bR denatures according to a single-exponential decay, whereas irreversible photobleaching has two decay components. The decay constant of the slow component of photobleaching is almost same as that in the dark. An Arrhenius plot of the denaturation kinetic constants for the fast and slow components showed similar activation energies of approximately 19 kcal/mol.

• 대한화학회지
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• 제20권1호
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• pp.15-18
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• 1976

염화벤젠술페닐의 바람직한 형태를 EHMO법으로 구하였다. 이 형태의 안정도는 황원자와 벤젠고리 사이의 n-${\pi}$ 콘쥬게이션에 따른다는 것을 알았다. 또 염화벤젠술페닐의 가에탄올 분해반응을 연구하여 얻은 반응속도상수를 치환기 효과와 황원자의 d-궤도함수 기여로 논의하였다. 비선형 Hammett 그래프로 부터 쌍뿔형의 중간체를 제안할 수 있었다.

• 호남수학학술지
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• 제30권2호
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• pp.369-378
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• 2008

Modeling nonlinear friction effects is a challenging problem. In this paper, a tracking controller is proposed for a system with uncertain nonlinear friction dynamics. Instead of using a specific friction model, we assume that the friction dynamics are represented by a function, which is unknown except its being continuously differentiable and Lipschitz continuous with known Lipschitz constants. It is shown that the scheme results in friction identification and trajectory position and velocity tracking. The analysis is done using Lyapunov-based stability method.

• Journal of Microbiology
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• 제42권1호
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• pp.20-24
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• 2004

Cloned myo-inositol-1-phosphate synthase (INOS) of Drosophila melanogaster was expressed in Escherichia coli, and purified using a His-affinity column. The purified INOS required NAD$\^$+/ for the conversion of glucose-6-phosphate to inositol-1-phosphate. The optimum pH for myo-inositol-1-phosphate synthase is 7.5, and the maximum activity was measured at 40$^{\circ}C$. The molecular weight of the native enzyme, as determined by gel filtration, was approximately M$\_$r/ 271,000${\pm}$15,000. A single subunit of approximately M$\_$r/ 62,000${\pm}$5,000 was detected upon SDS-polyacrylamide gel electrophoresis. The Michaelis ($K_{m}$) and dissociation constants for glucose-6-phosphate were 3.5 and 3.7 mM, whereas for the cofactor NAD$\^$+/ these were 0.42 and 0.4 mM, respectively.

• Journal of Pharmaceutical Investigation
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• 제18권2호
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• pp.69-81
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• 1988

We studied on the synthesis of chloromethylated polystyrene as a precursor of optically active polymers for direct resolution of optical isomers. Changing the degree of crosslinking and the kind of crosslinking agents, several polystyrene resin matrices were synthesized. The matrices were chloromethylated with methylal and chlorosulfonic acid as chloromethylating agents. The effects of solvents of various dielectric constants on the chloromethylation were quantitavely examined. We also synthesized chloromethylated polystyrene of macroreticular type that retained large surface area and good physical stability. The differences between the macroreticular type and macroporous type were investigated.

• 한국재료학회:학술대회논문집
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• 한국재료학회 2003년도 추계학술발표강연 및 논문개요집
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• pp.121-121
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• 2003

NiO thin films are very attractive for use as an antiferromagnetic layer, p-type transparent conducting films, in electrochromic devices and functional sensor layer for chemical sensors, due to their excellent chemical stability, as well as optical, electrical and magnetic properties. In addition, (100)- and (111)-oriented NiO films can be used as buffer layers on which to deposit other oriented oxide films, such as c-axis-oriented perovskite-type ferromagnetic films and superconducting films, because of the similarity in symmetry of oxygen ion lattice and lattice constants between the NiO films and the oriented oxide films. Thus, controlling the crystallographic orientation and surface roughness of the NiO films for a buffer layer are very important.

• 한국해양공학회지
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• 제15권4호
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• pp.86-91
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• 2001

In lateral ground flow, slope stability, and land slide problems, H-piles have been often used for a horizontally deforming ground to prevent the failure of mass of soil in a downward and outward movement of a slope. Here, Theoretical equations are derived to estimate the lateral force, assuming that the Mohr-coulomb's Plastic states occures in the ground just around H-piles. In this study, the mechanism of lateral force acting on passive pile that is in a row, situated in the ground undergoing plastic deformation was discussed, and its theoretical analysis was carried out considering the interval between H-piles. The solution of the theoretical equation derived from here showed resonable characteristic for constants of soil as well as for the interval, widths, and heights of H-pile.

• 대한수학회논문집
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• 제19권1호
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• pp.119-127
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• 2004

Suppose that $\psi{\;}\in{\;}L^2(\mathbb{R})$ generates a wavelet frame (resp. Riesz basis) with bounds A and B. If $\phi{\;}\in{\;}L^2(\mathbb{R})$ satisfies $$\mid$\^{\psi}(\xi)\;\^{\phi}(\xi)$\mid${\;}<{\;}{\lambda}\frac{$\mid$\xi$\mid$^{\alpha}}{(1+$\mid$\xi$\mid$)^{\gamma}}$ for some positive constants $\alpha,{\;}\gamma,{\;}\lambda$ such that $1{\;}<1{\;}+{\;}\alpha{\;}<{\;}\gamma{\;}and{\;}{\lambda}^2M{\;}<{\;}A$, then $\phi$ also generates a wavelet frame (resp. Riesz basis) with bounds $A(1{\;}-{\;}{\lambda}\sqrt{M/A})^2{\;}and{\;}B(1{\;}+{\;}{\lambda}\sqrt{M/A})^2$, where M is a constant depending only on $\alpha,{\;}\gamma$ the dilation step a, and the translation step b.

• Journal of Pharmaceutical Investigation
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• 제5권3호
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• pp.58-65
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• 1975

In the preparation of prednisolone tablets, when microfine cellulose$(Elcema^{\circledR})$ was used as diluents, stability and physical characteristics of prednisolone tablets are as follows; 1. Weight of the plain $Elcema^{\circledR}$ tablets increased by 75% of relative humidity and hardness was weakend, but the temperature $(60^{\circ}C)$ caused no change of thickness and decreased the weight and hardness. 2. In experimental tableting of prednisolone tablets, the addition of $Elcema^{\circledR}$ caused no difficulty in direct compression method, and the shortening of the disintegration time and increase of the hardness were satisfactory. 3. Dissolution rate test exhibited the result similiar to disintegration test. 4. In the comparison test of $Elcema^{\circledR}$ and $Avicel^{\circledR}$ as adjuvants the physical constants of prednisolone tablets showed nearly a similar tendency.

• Macromolecular Research
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• 제15권4호
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• pp.357-362
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• 2007

Polyimide/carbon nanotube (CNT) composite films, for potential use in high performance microelectronics and aerospace applications, were prepared by mixing a polyisoimide (PII) solution and a CNT suspension in NMP, followed by casting, evaporation and thermal imidization. The CNTs were modified by a nitric acid treatment to improve the thermal and electrical properties, as well as to provide good dispersion of the CNTs in a polymer matrix. The formation of functional groups on the modified CNT was confirmed by Raman spectroscopy. Scanning electron microscopy revealed the modified CNTs to be well dispersed in the polyimide matrix, with a uniform diameter of ca. 50 nm. The thermal stability of the films containing the CNTs was improved due to the enhanced interfacial interaction and good dispersion between the polyimide matrix and modified CNTs. In addition, the thermal expansion coefficient of the composites films was slightly decreased, but the dielectric constants increased linearly with increasing CNT content.