• 한국재료학회지
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• 제14권9호
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• pp.655-658
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• 2004

Lithium ferrites are a low-cost material which have been prominent in the high frequency core industry because of their excellent temperature performance and high squareness ratio. In order to develope the lithium ferrites with the high squareness and low coercive force, the ferrites of $Li_{0.48}Bi_{0.02}Ni_{0.04}Fe_{2.46-x}O_4$ were investigated the by varying composition, temperature and frequency. Electric loss of the Li-ferrite was lowered with the substitution of $Mn_{2}O_3$. The addition of $Mn_{2}O_3$ increased the magnetic induction (Bm&Br) but decreased the coercive force (Hc) and the squareness ratio (R=Br/Bm). Also, the Br value was stable at environmental temperature variation.

• 한국표면공학회지
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• 제23권3호
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• pp.150-159
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• 1990

The magnetic properties of electrodeposited iron and cobalt films on porous aluminum oxide film were examined. There exists perpendicular magnetic anisotropy due to the shape anisotropy. The coercivity and squareness ratio of films were strongly dependent on deposited particle diameter. The effect of packing fraction on squareness ratio was also apprecible. Unlike the iron-deposited films, the magnetic properties of cobalt films were changed by preferred orientation because of it's large crystal ansotropy constant.(about 10 times of Fe) The Fe deposited films were found to be more suitable for perpendicular magenetic recording media bacause perpendicular coercivity, squareness ratio and the ratio of perpendicular coercivity to horizontal ones of iron films are greater than those of cobalt films.

• 한국자기학회지
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• 제9권5호
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• pp.234-238
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• 1999

각종 microwave용 통신기기 소자 및 고주파용 memory 소자로 사용하기 위해서 각형비가 크고 보자력이 작은 lithium ferrite를 개발하고 물리적인 특성을 조사하기 위하여 Li0.48-0.5xBi0.02Ni0.04ZnxFe2.46-0.5xO4의 조성식을 갖는 시편을 제조하였다. ZnO을 첨가하여 변화시킴에 따라 잔류자기(Bm)가 증가하고 보자력(Hc)이 낮아졌으나 각형비 R은 감소하였다. 105$0^{\circ}C$에서 소결한 시편의 경우 R=0.82, Hc=1.8Oe로 나타났고 110$0^{\circ}C$에서 소결한 시편의 경우 R=0.75 및 Hc=1.70Oe인 값을 얻었다. Tc는 463$^{\circ}C$로 측정되었고 주변온도 변화에 대한 Br값의 변화가 매우 안정된 0.09~0.11 값으로 나타났다.

• 한국자기학회지
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• 제4권2호
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• pp.89-93
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• 1994

Mg-페라이트에 있어서 B-H hysteresis loop 특성에 미치는 소결체의 밀도, 내부 응력, 입자 크기의 영향을 조사하였다. 밀도가 증가함에 따라서 보자력은 감소하였으며 각형비는 증가 하였다. 보자력은 내부 응력에 매우 의존적이었으며 시편 내부에 응력이 존재할때 보자력은 1.95 [Oe]에서 4.35[Oe]로 증가하였다. 그러나 각형비는 큰 차이가 없었다. 입자 크기가 6-11[um] 범위 내에서의 보자력 및 각형비는 입자 크기에 의존성을 갖지 않았다.

• 열처리공학회지
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• 제4권2호
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• pp.9-18
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• 1991

Among the many maunfactured processes of producing multi filamentary composites, in situ process is widely used owing tv its simplicity and easyness of mass production. In this study, the mechanical and electromagnetic properties of Cu-Fe composite materials was investigated. The tensile strength of the Cu-Fe wires increased as the Fe content and reduction ratio were increased. The Cu-30 wt%Fe composites had the best properties in terms of figure merits compared to the other Cu-Fe composites made in this study or the commercially manufactured 6/1 ACSR cables of Cu cable. The coercivity was decreased by increasing Fe content, but the squareness was increased greatly. As increasing reduction ratio, the coercivity and squareness increased up to the maximum points, and then decreased. For example, the maximum values were obtained at $0.09mm{\phi}$ for Cu-30 wt%Fe composites and at $0.066mm{\phi}$ for Cu-45 wt%Fe composites. The magnetic property of Cu-Fe wires produced by precipitation treatment was higher than that of Cu-Fe wires produced by thermomechanical treatment. By annealing Cu-Fe wires after drawing process, the coercivity, remanence and squareness were improved.

• 한국재료학회지
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• 제11권11호
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• pp.972-977
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• 2001

It was investigated the effect of ultrasonic treatment on magnetic property of ultra fine magnetic Fe powders ($\alpha$-Fe) for magnetic tape. The properties were characterized with vibrating sample magnetometer (VSM), particle size analyzer (PSA) and scanning electron microscope (SEM). At 4hours ultrasonic treatment of 70 kHz, magnetic properties such as squareness ratio (S.Q. : 0.8868), orientation ratio (O.R. : 2.45) and switching field distribution (S.F. D. : 0.394) before taping were relatively enhanced. Cumulative particle size distribution of less than 5$\mu\textrm{m}$ fine powder was above 90% below 1 hour leaving time after ultrasonic treatment and it was supposed that ultrasonic treatment prevent aggregation. The magnetic values of S.Q. and S.F.D. of tape manufactured at 70 kHz and 4hour ultrasonic treatment were improved from 0.7747, 0.3818 to 0.8037, 0.3706, respectively. Electro-magnetic property used as in-output signal characteristic was improved, which showed that ultrasonic treatment developed the magnetic properties.

• 한국재료학회지
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• 제4권1호
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• pp.117-124
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• 1994

마이크로웨이브 Mg-Mn훼라이트에서 비자성 이온인 알루미늄으로 Fe 이온을 치환하여 포화자화를 낮출 수 있다. 이것은 마이크로웨이브 훼라이트의 사용 주파수 영역의 확장을 위해 필요하다. 이때 다른 특성의 변화가 수반되는 것은 검토해 봐야 할 점중의 하나이다. 본 연구에서는 MgO: MnO : $Fe_2O_3$를 1.0:0.1:0.95몰비로 제조한 마이크로 웨이브 훼라이트[화학식:$(MgO)_{1.0}(MnO)_{0.1}(Al_xFe_{1.9-x}O_{2.85}$]에서 AI을 0.1에서 0.4까지 첨가한 경우의 전기적.자기적 특성을 미세조직과 아울러 조사하였다. 포화자화 값은 첨가량에 따라 감소하였으며 강자성공명 선폭도 마찬가지였다. $H_c$ 값은 첨가량 0.2이상에서 103.48A/m(1.3Oe)이하로 나타났으며 각형비는 모두 우수하였다. 공명자기장은 첨가량에 따라 거의 변화가 없었다. 이상고 같은 실험결과로부터 적절한 조성범위에서 각각의 물성을 조합하여 넓은 범위의 마이크로웨이브 소자에 응용할 수 있는 제반 물성을 얻을 수 있었다.

• 한국세라믹학회지
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• 제39권8호
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• pp.758-763
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• 2002

초음파 에너지(28 kHz, 40 kHz, 70 kHz)를 사용하여 수직자기기록용 Ba-ferrite의 자기적 특성 향상에 대하여 조사하였다. 한편, 분산된 Ba-ferrite를 sheet에 수직으로 배향시키기 위해 다양한 형태의 배향기들을 사용하여 실험을 행하였다. Ba-ferrite가 도포된 sheet 중 초음파 에너지가 40 kHz이고 초음파 처리 시간이 2시간에서 자기적 특성인 S. Q. (Squareness Ratio)와 O. R. (Orientation Ratio)값이 각각 0.7831과 2.87로 비교적 좋은 값을 얻을 수 있었다. 이때 얻어진 sheet의 표면 형상을 SEM(Scanning Electron Microscopy)으로 분석한 결과 Ba-ferrite가 자화용이축인 c 축에 수직방향으로 배향되어 수직자기기록용으로서의 응용에 가능성을 보였다. 또한, VSM(Vibrating Sample Magnetometer)으로 자기장의 각도변화에 따른 S. Q.의 측정시, 자기장의 각도가 증가함에 따라 S. Q. 값이 감소하였고 이는 수직자기기록용으로써 가능성을 재확인 시켜주었다.

• 열처리공학회지
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• 제2권2호
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• pp.38-45
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• 1989

The Cu-Fe permanent magnet were prepared in situ process, which has economic and mass productive merits in producing multi filamentary composites. The purpose of this research was to study the effect of reduction ratio and heat treatment on magnetic property. As the reduction ratio of Cu-Fe wire increased, the filament structure became finer and interfilament distances decreased and the morphology of filament cross section became ribbon shape. As Fe content increased significantly. The coercivity and squareness of Cu-55 wt%Fe composite increased as a reduction ratio became higher, whereas they increased to maximum values at 0.09 mm ${\phi}$ for Cu-30 wt%Fe, and 0.066 mm ${\phi}$ for CU-45 wt%Fe respectively, and decreased for further reduction. The magnetic properties of Cu-Fe composites can be more enhanced by intermediate heat treatment. The best magnetic properties were obtained from Cu-55 wt%Fe composite deformed to 0.054 mm ${\phi}$ and annealed.

• 한국자기학회:학술대회 개요집
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• 한국자기학회 1991년도 춘계연구발표회 논문개요집
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• pp.73-74
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• 1991

The films with ferromagnetic fine particles dispersed in nonmagnetic matrix, such as $Fe-Al_2O_3$ and Fe-Cu have been studied for use of magnetic recording medium, optically device and sensor. Their magnetic properties depend strongly on structural parameter such as size and volume fraction of ferromagnetic particles. Fe-Cr-Ni alloy sputtered films also have microstructure with ferromagnetic -- b.c.c phase and nonmagnetic f.c.c phase grains. Magnetic properties of these films depend strongly on such a unique structure. These are depend on the ratio in volume of ferromagnetic particles to nonmagnetic ones $V_F/V_N$, the saturation magnetization Ms increased with increase of $V_F/V_N$. The coercivity Hc of the as-deposited films took maximum value of about 200 Oe at adequate $V_F/V_N$ and then Ms and Squareness S were 500 emu/cc and 0.5, respectively.(omitted)