• Journal of the Korean Ceramic Society
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• v.54 no.3
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• pp.222-227
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• 2017

Flake-type micro hollow silica was synthesized by precipitation method using an $Mg(OH)_2$ inorganic template and sodium silicate and ammonium sulfate as the silica precursors. We investigated the effects of the silica precursor concentration on the shape, shell thickness, and surface of the hollow silica. When the concentration of the silica precursor was 0.5 M, the hollow silica had a smooth and translucent thin shell, but the shell was broken. On the other hand, the shell thickness of the hollow silica changed in the range of 12 nm to 18 nm with the increase of the precursor concentration from 0.7 M to 1.1 M. Simultaneously, unintended spherical silica satellites were created on the shell surface. The number of satellites and the size rose according to the increased concentration of silica precursor. The reason for the formation of spherical silica satellites is that the $NH_4OH$ nucleus generated in the synthesis of hollow silica acted as another silica reaction site.

• Journal of Electrochemical Science and Technology
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• v.12 no.1
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• pp.74-81
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• 2021

Silicon (Si) is recognized as a promising anode material for high-energy-density lithium-ion batteries. However, under a condition of electrode comparable to commercial graphite anodes with low binder content and a high electrode density, the practical use of Si is limited due to the huge volume change associated with Si-Li alloying/de-alloying. Here, we report a novel core-shell composite, having a reversible capacity of ~ 500 mAh g-1, by forming a shell composed of a mixture of nano-Si, graphite nanosheets and a pitch carbon on a spherical natural graphite particle. The electrochemical measurements are performed using electrodes with 2 wt % styrene butadiene rubber (SBR) and 2 wt.% carboxymethyl cellulose (CMC) binder in an electrode density of ~ 1.6 g cm-3. The core-shell composites having the reversible capacity of 478 mAh g-1 shows the outstanding capacity retention of 99% after 100 cycles with the initial coulombic efficiency of 90%. The heterostructure of core-shell composites appears to be very effective in buffering the volume change of Si during cycling.

• Proceedings of the Materials Research Society of Korea Conference
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• 2011.10a
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• pp.31.2-31.2
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• 2011

We studied a method of manufacturing an anode to restrict contraction in reducing NiO/YSZ by uniformly mixing. In order to mix Ni and YSZ, a sub-micron Ni core surface was coated at high-speed by a mixture of nano-sized YSZ and a spherical core-shell was subsequently formed. The micron-sized core-shell anode powder was then heat treated at $400{\sim}1,450^{\circ}C$ in an air atmosphere and Ni was extruded and synthesized in nano-size. Subsequently, when the nano-sized mixture of the anode was heat treated and maintained at a temperature of $1,450^{\circ}C$, the anode was manufactured, where Ni and YSZ were uniformly distributed with the nano-structure. According to the nano-sized anode powder synthesis process, Ni particles were oxidized at $400{\sim}500^{\circ}C$ and became spherical by surface tension. In the case of the spherical core Ni powder, the heat treatment temperature rose to $1,250^{\circ}C$ and then a gap between the internal and external pressures occurred due to thermal and tensile stresses. A crack subsequently appeared on the surface, and the heat treatment temperature was increased continuously to increase the pressure gap and then the core Ni extruded as a nano-sized powder, Ni and YSZ uniformly distributed. It was found that the anode of 50~200 nm with a consistent structure obtained in this study has electric conductivity that is approximately 3 times larger than that of a commercial anode.

• The Journal of the Acoustical Society of Korea
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• v.38 no.5
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• pp.549-557
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• 2019

The acoustical scattering characteristics of a target are influenced by the material properties and structural characteristics of the target, which are critical information for acoustic detection and identification of underwater target. In particular, for thin elastic target, unique scattered signals are generated around the target by the Lamb wave. In this paper, the results of scattered signal measurement of aluminum spherical shell in the water tank using the stepped frequency sweep sine signal are presented. In particular, the scattering of the water-filled aluminum spherical shell is compared with that of the air-filled one both theoretically and experimentally. The difference of the scattered signals are analyzed using the pseudo Wigner-Ville distribution in terms of average frequency, frequency distribution, and energy of the scattered signal. The result shows that all observed parameters increased when the aluminum sphere was water-filled, and it is well matched to the theoretical expectation.

• The Bulletin of The Korean Astronomical Society
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• v.39 no.1
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• pp.60.2-60.2
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• 2014

The dust cloud around ${\lambda}$-Orionis is seen to be circular symmetric with the large angular extent (${\sim}8^{\circ}$). However, whether the three dimensional structure of the cloud is shell or torus ring is not yet fully resolved. We studied the structure of the dust cloud using a three-dimensional Monte-Carlo simulation code, MoCafe (Monte Carlo radiative transfer). The dust density structure of the cloud was inferred based on the star-count method. We assumed that the cloud is a spherical shell or a torus ring and calculated the radial profiles of scattered light originating from a central OB association. Comparison of the results with the S2/68 ultraviolet observations indicates that the cloud is a spherical shell. We also compared the Av map around ${\lambda}$-Orionis with the optical depth obtained based on the star-count.

• Journal of the Korea Institute of Military Science and Technology
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• v.7 no.3 s.18
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• pp.157-164
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• 2004

This is a boundary integral formulation for elastic shallow shell structures subjected to both membrane and bending loads. Fundamental solutions for shell actions are determined from the plate solutions and, finally the corresponding kernel functions for shell BIEs can be constructed. It is illustrated by solving an example of uniform load of spherical cap.

• Journal of the Korea Institute of Information and Communication Engineering
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• v.2 no.1
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• pp.37-43
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• 1998

This article describes the application of a coupled finite element-boundary element method to obtain the steady-state response of a sonar transducer. The particular structure considered is a flooded piezoelectric spherical shell. The sonar shell is simulated to be driven by electrical charges applied onto inner and outer surfaces of the shell. It is shown that at relatively low input frequency a beam pattern which is almost close to omnidirection can be obtained. The coupled FE-BE method is described in detail.

• Proceedings of the Korean Vacuum Society Conference
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• 2011.02a
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• pp.467-467
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• 2011

Reflecting the growing importance of nanomaterials in science and technology, controlling the porosity combined with well-defined structural properties has been an ever-demanding pursuit in the related fields of frontier researches. A number of reports have focused on the synthesis of various nanoporous materials so far and, recently, the nanomaterials with multimodal porosity are getting an emerging importance due to their improved material properties compared with the mono porous materials. However, most of those materials are obtained in bulk phases while the spherical nanoparticles are one of the most practical platforms in a great number of applications. Here, we report on the synthesis of the core-shell silica nanoparticles with double mesoporous shells (DMSs). The DMS nsnoparticles are spherical and monodispersive and have two different mesoporous shells, i.e., the bimodal porosity. It is the first example of the core-shell silica nanoparticles with the different mesopores coexisting in the individual nanoparticles. Furthermore, the carbon and silica hollow capsules were also fabricated via a serial replication process.

• International Journal of Naval Architecture and Ocean Engineering
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• v.8 no.6
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• pp.530-536
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• 2016

The number of fabrication shop for spherical type LNG tank is proportional to that of the tank radius to be constructed. Due to limitation of facility investment including building sites, it is practically difficult to fabricate various size tanks with perfectly spherical shape in the yards. The efficient method to be capable of increasing cargo tank volume is to extend vertically the conventional spherical type LNG tank by inserting a cylindrical shell structure. The main purpose of this study is to derive related equations on forces generated on spherical type LNG tank with central cylindrical part under various static loadings in order to establish the simplified analysis method for the initial estimate. In this study, equations on circumferential and meridional force have been derived and verified by relations with the reaction forces per unit length of equator.

• Computational Structural Engineering
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• v.10 no.3
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• pp.167-174
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• 1997

Engineers must be aware of possible sources of chaotic behavior. They may render conventional design predictions untrustworthy and potentially unsafe because of the sensitivity to initial conditions. Dynamic responses of a spherical shell subjected to impulsive loading which act on the center are analyzed using the finite element method. The chaotic responses are identified by the standard methods, such as displacement-time histories, Poincare maps, and phase diagrams. The responses are chaotic, but, not so sensitive to the initial conditions, and the characteristics of responses are not changed with time, in contrast to the case of the responses of beam. The Poincare points scattered in the limited area represent that the responses are chaotic, but do not show the geometric structures. The snap-through phenomena of the shell to the side of the direction of the load or of the opposite direction, is analysed by using the energy diagram.