• 한국세라믹학회지
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• 제54권3호
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• pp.222-227
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• 2017

Flake-type micro hollow silica was synthesized by precipitation method using an $Mg(OH)_2$ inorganic template and sodium silicate and ammonium sulfate as the silica precursors. We investigated the effects of the silica precursor concentration on the shape, shell thickness, and surface of the hollow silica. When the concentration of the silica precursor was 0.5 M, the hollow silica had a smooth and translucent thin shell, but the shell was broken. On the other hand, the shell thickness of the hollow silica changed in the range of 12 nm to 18 nm with the increase of the precursor concentration from 0.7 M to 1.1 M. Simultaneously, unintended spherical silica satellites were created on the shell surface. The number of satellites and the size rose according to the increased concentration of silica precursor. The reason for the formation of spherical silica satellites is that the $NH_4OH$ nucleus generated in the synthesis of hollow silica acted as another silica reaction site.

• Journal of Electrochemical Science and Technology
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• 제12권1호
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• pp.74-81
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• 2021

Silicon (Si) is recognized as a promising anode material for high-energy-density lithium-ion batteries. However, under a condition of electrode comparable to commercial graphite anodes with low binder content and a high electrode density, the practical use of Si is limited due to the huge volume change associated with Si-Li alloying/de-alloying. Here, we report a novel core-shell composite, having a reversible capacity of ~ 500 mAh g-1, by forming a shell composed of a mixture of nano-Si, graphite nanosheets and a pitch carbon on a spherical natural graphite particle. The electrochemical measurements are performed using electrodes with 2 wt % styrene butadiene rubber (SBR) and 2 wt.% carboxymethyl cellulose (CMC) binder in an electrode density of ~ 1.6 g cm-3. The core-shell composites having the reversible capacity of 478 mAh g-1 shows the outstanding capacity retention of 99% after 100 cycles with the initial coulombic efficiency of 90%. The heterostructure of core-shell composites appears to be very effective in buffering the volume change of Si during cycling.

• 한국재료학회:학술대회논문집
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• 한국재료학회 2011년도 추계학술발표대회
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• pp.31.2-31.2
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• 2011

We studied a method of manufacturing an anode to restrict contraction in reducing NiO/YSZ by uniformly mixing. In order to mix Ni and YSZ, a sub-micron Ni core surface was coated at high-speed by a mixture of nano-sized YSZ and a spherical core-shell was subsequently formed. The micron-sized core-shell anode powder was then heat treated at $400{\sim}1,450^{\circ}C$ in an air atmosphere and Ni was extruded and synthesized in nano-size. Subsequently, when the nano-sized mixture of the anode was heat treated and maintained at a temperature of $1,450^{\circ}C$, the anode was manufactured, where Ni and YSZ were uniformly distributed with the nano-structure. According to the nano-sized anode powder synthesis process, Ni particles were oxidized at $400{\sim}500^{\circ}C$ and became spherical by surface tension. In the case of the spherical core Ni powder, the heat treatment temperature rose to $1,250^{\circ}C$ and then a gap between the internal and external pressures occurred due to thermal and tensile stresses. A crack subsequently appeared on the surface, and the heat treatment temperature was increased continuously to increase the pressure gap and then the core Ni extruded as a nano-sized powder, Ni and YSZ uniformly distributed. It was found that the anode of 50~200 nm with a consistent structure obtained in this study has electric conductivity that is approximately 3 times larger than that of a commercial anode.

• 한국음향학회지
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• 제38권5호
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• pp.549-557
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• 2019

표적의 음향 산란 특성은 표적의 재료 특성과 구조적 특성에 영향을 받으며, 이는 음향을 이용하여 수중에서 표적을 탐지, 식별하고자 할 때 매우 중요한 정보가 된다. 특히, 얇은 탄성체의 경우 램파(Lamb wave)에 의해 표적 주변 유체에 산란파가 생성된다. 본 논문에서는 계단 주파수 스윕 사인 파형을 이용하여 수조에서 알루미늄 구의 산란 신호를 측정한 결과를 제시한다. 특히 알루미늄 구의 내부에 물이 채워져 있는 경우와 공기가 채워져 있는 경우에 대하여 산란 신호의 차이를 측정하고 이론 모델과 비교하였다. 또, 내부 물질에 따른 표적 산란 신호 차이를 유사 위그널-빌 분포를 이용하여 분석하고, 유도파의 평균 주파수, 주파수 분포, 에너지의 차이를 비교하였다. 분석 결과, 구의 내부에 물이 채워진 경우가 공기가 채워진 경우에 비해 유도파의 평균 주파수, 주파수 분포, 에너지가 증가하는 것을 확인하였으며 이는 이론적인 예상과 부합한다.

• 천문학회보
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• 제39권1호
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• pp.60.2-60.2
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• 2014

The dust cloud around ${\lambda}$-Orionis is seen to be circular symmetric with the large angular extent (${\sim}8^{\circ}$). However, whether the three dimensional structure of the cloud is shell or torus ring is not yet fully resolved. We studied the structure of the dust cloud using a three-dimensional Monte-Carlo simulation code, MoCafe (Monte Carlo radiative transfer). The dust density structure of the cloud was inferred based on the star-count method. We assumed that the cloud is a spherical shell or a torus ring and calculated the radial profiles of scattered light originating from a central OB association. Comparison of the results with the S2/68 ultraviolet observations indicates that the cloud is a spherical shell. We also compared the Av map around ${\lambda}$-Orionis with the optical depth obtained based on the star-count.

• 한국군사과학기술학회지
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• 제7권3호
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• pp.157-164
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• 2004

This is a boundary integral formulation for elastic shallow shell structures subjected to both membrane and bending loads. Fundamental solutions for shell actions are determined from the plate solutions and, finally the corresponding kernel functions for shell BIEs can be constructed. It is illustrated by solving an example of uniform load of spherical cap.

• 한국정보통신학회논문지
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• 제2권1호
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• pp.37-43
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• 1998

This article describes the application of a coupled finite element-boundary element method to obtain the steady-state response of a sonar transducer. The particular structure considered is a flooded piezoelectric spherical shell. The sonar shell is simulated to be driven by electrical charges applied onto inner and outer surfaces of the shell. It is shown that at relatively low input frequency a beam pattern which is almost close to omnidirection can be obtained. The coupled FE-BE method is described in detail.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2011년도 제40회 동계학술대회 초록집
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• pp.467-467
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• 2011

Reflecting the growing importance of nanomaterials in science and technology, controlling the porosity combined with well-defined structural properties has been an ever-demanding pursuit in the related fields of frontier researches. A number of reports have focused on the synthesis of various nanoporous materials so far and, recently, the nanomaterials with multimodal porosity are getting an emerging importance due to their improved material properties compared with the mono porous materials. However, most of those materials are obtained in bulk phases while the spherical nanoparticles are one of the most practical platforms in a great number of applications. Here, we report on the synthesis of the core-shell silica nanoparticles with double mesoporous shells (DMSs). The DMS nsnoparticles are spherical and monodispersive and have two different mesoporous shells, i.e., the bimodal porosity. It is the first example of the core-shell silica nanoparticles with the different mesopores coexisting in the individual nanoparticles. Furthermore, the carbon and silica hollow capsules were also fabricated via a serial replication process.

• International Journal of Naval Architecture and Ocean Engineering
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• 제8권6호
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• pp.530-536
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• 2016

The number of fabrication shop for spherical type LNG tank is proportional to that of the tank radius to be constructed. Due to limitation of facility investment including building sites, it is practically difficult to fabricate various size tanks with perfectly spherical shape in the yards. The efficient method to be capable of increasing cargo tank volume is to extend vertically the conventional spherical type LNG tank by inserting a cylindrical shell structure. The main purpose of this study is to derive related equations on forces generated on spherical type LNG tank with central cylindrical part under various static loadings in order to establish the simplified analysis method for the initial estimate. In this study, equations on circumferential and meridional force have been derived and verified by relations with the reaction forces per unit length of equator.

• 전산구조공학
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• 제10권3호
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• pp.167-174
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• 1997

계가 혼돈거동을 나타낼 경우에는 변수들의 미소변화에 의해서도 계가 전혀 다른 거동을 나타낼 수 있기 때문에 비선형계의 설계 및 해석시에는 이를 고려해야 한다. 따라서 본 연구에서는 구형 쉘의 중앙에 충격하중이 수직방향으로 작용하는 경우, 쉘의 기하학적 비선형성과 재료적 비선형성으로부터 기인되는 혼돈거동을 해석하였다. 쉘의 탄소성거동을 유한요소법을 이용하여 구한 후 계의 거동을 변위-시간이력, 프앙카레 맵, phase diagram등의 표준적인 방법들을 이용하여 쉘의 혼돈거동을 규명하였다. 해석결과, 계는 혼돈거동을 나타내었으나 탄소성보의 경우와는 달리 초기조건의 미소변화에 대한 극도의 민감도는 나타나지 않았으며 시간에 대한 쉘의 거동특성도 크게 변하지 않았다. 프앙카레 맵은 한정된 영역에 결쳐서 점들이 분포되었기 때문에 계의 거동이 혼돈거동임을 보여 주고 있지만 혼돈계의 프앙카레 맵에서 나타나는 기하학적 구조는 나타나지 않았다. 에너지선도를 이용하여 쉘이 하중의 작용방향 또는 반대방향으로 불규칙적으로 snap-through되는 원인을 규명하였다.