• Journal of Industrial Technology
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• v.23 no.A
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• pp.199-206
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• 2003

The charcoal-encapsulated methyl silica microcapsules were prepared by a O/W microemulsion sol-gel method, and the adsorption properties on aquatic humic acid were investigated. The capsules prepared were spherical, $100{\sim}1000{\mu}m$ in size. The size distribution was controllable by adjusting the size of charcoal powder, charcoal/methyl silica ratio, and agitating speed in O/W sol-gel process. Adsorption efficiency of charcoal for aquatic humic acid was decreased after encapsulation by methyl silica shell. The decreased adsorption efficiency can be dependent on the decrease of the BET surface area and pore volume after encapsulation. Diffusion properties of humic acid through the capsule shell also played an important role on adsorption efficiency. Therefore, the reasonable target pollutants for the capsules can be VOC or odor molecules which can overcome diffusion barrier through shell of capsules in air condition. Functionalization methods for the charcoal-encapsulated $CH_3(SiO)_n$ microcapsules by incorporation of $TiO_3$ as a phtocatalytic function and by incorporation of inorganic pigment as a color function were also investigated. $TiO_2$ coating properties were controllable by adjusting pH, temperature, and the concentration of $TiOSO_4$. In XRD measurement, the crystal form of the coated $TiO_2$ was anatase. For the colorization of the capsules, inorganic pigments were more efficient than organic dyes, and various color was introduced to the capsules using inorganic pigments.

• Transactions of the Korean hydrogen and new energy society
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• v.29 no.5
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• pp.450-457
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• 2018

To design the practical core-shell electrocatalysts, combination of core and shell materials is important to meet catalytic activity and durability target. In general, Pd is considered as a good core material due to its best activity caused by strain/ligand effect. Preparing Pd nanoparticles can be a starting point in fabricating core-shell type electrocatalysts, much simplified Pd preparing process is suggested by using carbon monoxide (CO) as a reducing agent and/or capping agent. The solvent composition and reaction temperature can control to nanosheet, tetrahedron, and sphere without using additional stabilizer. Among them, Pd nanosheet which has mainly (111) plane showed about 3 times higher electrocatalytic activity for oxygen reduction reaction (ORR) to the spherical Pd nanoparticles. The enhanced ORR activity of Pd nanosheets can be attributed to the exposure of Pd (111) surface and the high electrochemical surface area. Therefore, we demonstrated that the shape of Pd nanomaterials is easily controlled via a facile reduction method using CO, and (111) plane-oriented Pd nanosheets can be a promising ORR catalysts and core material for polymer electrolyte fuel cells (PEFCs).

• Journal of the Computational Structural Engineering Institute of Korea
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• v.15 no.3
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• pp.399-407
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• 2002

A three-dimensional method of analysis is presented for determining the free vibration frequencies and mode shapes of hollow bodies of revolution (i.e., thick shells), not limited to straight line generators or constant thickness. The middle surface of the shell may have arbitrary curvatures, and the wall thickness may vary arbitrarily. Displacement components$U_\Phi, U_z, U_\theta$ in the meridional, normal and circumferential directions, respectively, are taken to be sinusoidal in time, periodic in$\theta$, and algebraic polynomials in the$\Phi$and z directions. Potential(strain) and kinetic energies of the entire body are formulated, and upper bound values of the frequencies are obtained by minimizing the frequencies. As the degrees of the polynomials are increased, frequencies converge to the exact values. Novel numerical results are presented for two types of thick conical shells and thick spherical shell segments having linear thickness variations. Convergence to four digit exactitude is demonstrated for the first five frequencies of both types of shells. The method is applicable to thin shells, as well as thick and very thick ones.

• Korean Chemical Engineering Research
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• v.53 no.5
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• pp.627-631
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• 2015

Various solid structures were prepared by electrospray technique. In this process, liquid flows out from a capillary nozzle under a high electrical potential and is subjected to an electric field, which causes elongation of the meniscus to form a jet. In our study, by controlling the amount of polyvinyl pyrrolydone in precursor solution, the jet either disrupted into droplets for the formation of spherical particles or was stretched in the electric field for the formation of fibers. During the electrospray process, the ethanol solvent was evaporated and induced the solidification of precursors, forming solid particles. The evaporation of ethanol solvent also enhanced the mass transport of solutes from the inner core to the solid shell, which facilitated fabrication of porous and hollow structure. The network structures were also prepared by heating the collector.

• 한국생물공학회:학술대회논문집
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• 2001.11a
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• pp.697-700
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• 2001

Iron is an essential nutrient for most organisms, which supplied to them in a protein-iron complex known as ferritin. Ferritins are multimeric proteins found in prokaryotes, plants and animals. They are consisted of spherical shell of 24 subunits defining a cavity of about 8nm in diameter, where an iron core is laid down. Expression of ferritin in recombinant E. coli at $37^{\circ}C$ led to the accumulation of recombinant ferritin. Insoluble form of ferritin was separated from disrupted cells, followed by various primary separation steps with two kinds of buffers. Collected samples from the primary steps were purified by DEAE-cellulose gels packed in a column. The fractions from the DEAE column were assayed to gain the amount and the purity of ferritin by using HPLC and SDS-PAGE.

• The Bulletin of The Korean Astronomical Society
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• v.40 no.2
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• pp.44.2-44.2
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• 2015

Radiative transfer programs have been developed to simulate near-IR spectra of Titan. The formalism of the radiative transfer calculations includes the absorption and emission lines of $CH_4$, $C_2H_2$, $C_2H_6$, and HCN, and continua produced by Titanian haze particles. Absorption and scattering of sunlight by haze particles are considered by employing a two-stream approximation and a spherical-shell model for the atmospheric layers of Titan. Various constraints on the radiative transfer calculations for generating synthetic spectra will be discussed and presented. Several examples of comparisons between the synthetic spectra and recent spectral observations of Titan will also be presented.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.26 no.11
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• pp.2245-2252
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• 2002

Design sensitivity analysis scheme is proposed in an elasto -plastic finite element method with explicit time integration using a direct differentiation method. The direct differentiation is concerned with large deformation, the elasto-plastic constitutive relation, shell elements with reduced integration and the contact scheme. The design sensitivities with respect to the process parameter are calculated with the direct analytical differentiation of the governing equation. The sensitivity results obtained from the present theory are compared with that obtained by the finite difference method in a class of sheet metal forming problems such as hemi-spherical stretching and cylindrical cup deep-drawing. The result shows good agreement with the finite difference method and demonstrates that the preposed sensitivity calculation scheme is a pplicable in the complicated sheet metal forming analysis and design.

• Journal of KSNVE
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• v.10 no.2
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• pp.319-324
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• 2000

This paper shows hot to model the submerged elastic structures and adequate analysis tools for modal behavior when using finite element and boundary element method. Four different cases are reviewed depending on the location of the water and air. First case is that structures are filled with air and water is located outside. Second case is opposite to case one. These cases are solved by direct approach using collocation procedure. Third case is that water is located both sides of structures. Last case is that air is located both sides. These cases are solved by indirect approach using variational procedure. As analysis tools harmonic frequency sweep analysis and eigenvalue iteration method are selected to obtain the natural frequencies of vibrating submerged structures depending on the cases. Results are compared with closed form solutions of submerged spherical shell.

• Proceedings of the KSRS Conference
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• 2003.11a
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• pp.537-539
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• 2003

We present a GPS-derived regional ionosphere model, which estimates Total Electron Content (TEC) in rectangular grids on the spherical shell over Korea. The GPS data from nine GPS stations were used. The pseudorange data were phase-leveled by a linear combination of pseudoranges and carrier phases. During a quiet day of solar activity, the regional ionosphere map indicated 30-45 Total Electron Content Unit (TECU) at the peak of the diurnal variation. In comparison with the Global Ionosphere Map of the Center for Orbit Determination in Europe, RMS differences were at the level of 4-5 TECU for five days.

• Macromolecular Research
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• v.15 no.1
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• pp.39-43
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• 2007

The amphiphilic block copolymer (PEtOz-PCL) of poly(2-ethyl-2-oxazoline) (PEtOz) and poly(${\varepsilon}$-caprolactone) (PCL) formed spherical micellar structures with an average diameter of 26 nm in aqueous phase. Au and Pd nanoparticles with an average diameter of $2{\sim}3nm$ were prepared by using the PEtOz-PCL micelle consisting of a PEtOz shell and PCL core. The Au nanoparticles of PEtOz-PCL micelles in aqueous phase could be transferred into organic phase by using n-dodecanethiol. The use of the Pd-NP/PEtOz-PCL micelle as a nanoreactor for Suzuki cross-coupling reaction was investigated.