• Title/Summary/Keyword: sphene

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Geochemical characteristics of Ogcheon granite in Ogcheon area (옥천화강암의 지구화학적 특성)

  • 윤현수;김대업;박석환
    • The Journal of the Petrological Society of Korea
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    • v.8 no.2
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    • pp.81-91
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    • 1999
  • The area of the study is located in Ogcheon district, middle part of Ogcheon Fold Belt. The area is covered by metasedimentary rocks of Ogcheon Supergroup at northern, eastern and southern part. Jurassic Ogcheon granite which intruded into Ogcheon Supergroup at central part, was intruded by Cretaceous quartz porphyry at western part. The granite consists of quartz, plagioclase, alkali feldspar, biotite, sphene, apatite, epidote, opaque and so on. It is generally characterized by grey to light grey, medium-grained, mafic enclave and partly weak foliation. In terms of geochmical compositions, the granite is felsic, peraluminous, subalkaline and calc-alkaline, and it was differentiated from single granitic magma. It shows parallel LREE enrichment and HREE depletion patterns with 0.84 Eu negative anomaly, which has REE variation trend and anomaly value similar to Jurassic granites in Korea. From charactristics of petrology, mineralogy and geochmistry, it may be interpreted that the Ogcheon granite body was derived from melting of I-type crustal material related to syn-collisional tectonic setting and emplaced more or less rapidly into the Ogcheon Supergroup.

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Thermal and uplift histories of Mesozoic granites in Southeast Korea: new fission track evidences

  • Shin, Seong-Cheon;Susumu Nishimura
    • The Journal of the Petrological Society of Korea
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    • v.2 no.2
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    • pp.104-121
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    • 1993
  • Fission track (FT) thermochronological analyses on Mesozoic granites provide new information about cooling and uplift histories in Southeast Korea. Twenty-nine new FT sphene, zircon and apatite ages and seven track length measurements are presented for eleven granite samples. Measured mineral ages against assumed closure temperatures yield cooling rates for each sample. Relatively rapid (7-$15^{\circ}C$/Ma) and simple cooling patterns from the middle Cretaceouss (ca. 90-100 Ma) granites are caused mainly by a high thermal contrast between the intruding magma and country rocks at shallow crustal levels (ca. 1-2.5 km-depths). On the contrary, a slow overall cooling (1-$4^{\circ}C$/Ma) of the Triassic to Jurassic granites (ca. 250-200 Ma), emplaced at deep depths (>>9 km), may mainly depend upon very slow denudation of the overlying crust. The uplift history of the Triassic Yeongdeog Pluton in the Yeongyang Subbasin, west of the Yangsan Fault, is characterized by a relatively rapid uplift (~0.4 mm/a) before the total unroofing of the pluton in the earliest Cretaceous (~140 Ma) followed by a subsidence (~0.2mm/a) during the Hayang Group sedimentation. Stability of original FT zircon ages (156 Ma) and complete erasure of apatite ages suggest a range of 3 to 5.5 km for the basin subsidence. Since 120 Ma up to present, the Yeongyang Subbasin has been slowly uplifted (~0.04 mm/a). The FT age patterns of Jurassic granites both from the northeastern wing of the Ryeongnam Massif and from the northern edge of the Pohang-Kampo Block indicate that the two geologic units have been slowly uplifted with a same mean rate (~0.04 mm/a) since early Cretaceous. Estimates of Cenozoic total uplifts since 100 Ma are different: Ryeongnam Massif (~6 km)=Pohang-Kampo Block (~6 km)>Yeongyang Subbasin(~4 km).

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Wallrock Alteration and Primary Dispersion of Elements in the Vicinity of the Mugeug Gold-bearing Quartz Veins (무극 함금석영맥광상 주변모암에서의 모암변질과 원소들의 일차분산)

  • Hwang, In Ho;Chon, Hyo Taek
    • Economic and Environmental Geology
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    • v.27 no.4
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    • pp.387-396
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    • 1994
  • Mineralogical and geochemical studies on gold-bearing quartz veins and wallrock from the Mugeug mine were carried out in order to investigate the variation of mineralogical composition and the geochemical behavior of elements with distance from the gold-bearing quartz veins. Gold-bearing quartz veins occur in early Cretaceous medium- to coarse-grained biotite granite. The unaltered wallrock is composed mainly of quartz, plagioclase, orthoclase, microcline, biotite and hornblende with accessory minerals of sphene and apatite. Mineralogical changes in altered wallrock around the gold-bearing quartz veins were observed as follows; 1) biotite and hornblende altered into chlorite, and next to sericite, 2) plagioclase, orthoclase and microcline altered into sericite, and 3) calcite and quartz introduced into wallrock. Contents of $K_2O$, Rb, Cs, Au, As and Sb in altered wallrock increase, whereas those of $Na_2O$, CaO, Ba, and Sr decrease with proximity to the gold-bearing quartz veins. The loss on ignition also increases with the increase of alteration mineral. The width of primary dispersion increases in order $Au=SiO_2<As=Cs=Rb<K_2O=Sb$ and $MnO<Na_2O=CaO=Ba<Sr$. The sericitization index, $K_2O/(K_2O+Na_2O)$, is an important indicator to interpret the degree of alteration at the Mugeug mine, which is more than 0.8 in strongly and moderately altered granite, 0.5~0.8 in wea altered granite, and less than 0.5 in unaltered granite. Alteration indices for major and trace elements, and the ratio of Rb/Sr are also useful to discriminate alteration zones.

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A Study o the Geological Occurrence, the Mineralogical and Physico-chemical Properties of the Sericite Ore from the Yangbuk Area, Kyungsangbuk-do (경북 양북지역산 견운모광석의 물성 및 부존산상)

  • 이동진;고상모
    • Journal of the Mineralogical Society of Korea
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    • v.11 no.2
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    • pp.85-96
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    • 1998
  • The sericite ore is formed by the hydrothermal alteration of rhyodacitic welded tuff. The alteration zone of the host rock can be classified into four types based on the mineral assemblages ; sericite, quartz-sericite, silicified and propylite zone. The sericite ore mainly occurs as vein types and fault clay along the fault plane in the quartz-sericite zone. Mineral components of the sericite ore are mainly sericite with minor diaspore, corundum and pyrite. The sericitic porcelaineous ore is mainly composed of quartz and sericite. Accessory minerals are muscovite, diaspore, sphene, corundum, pyrite, iron-oxides and etc. The chemical compositions of K2O, Al2O3, and ignition loss in the sericite ore increase largely than that of the host rock, while the compositions of SiO2, Na2O and Fe2O3 decrease. XRD patterns of the heat-treated sericite ores show the formation of mullite at $1,200^{\circ}C$. and the diaspore-bearing sericite ore forms mullite and corundum at $1,200^{\circ}C$. The differential thermal analysis of the sericite ores show small endothermic peak at 645~668$^{\circ}C$. and the diaspore-bearing sericite ore shows a strong endothermic peak at $517^{\circ}C$. It indicates that the decomposition of diaspore appear at lower temperature than that of sericite. The thermal expansivity of the sericite ores show the similar pattern. The sericite ores show the thermal expansivity of 3.3~4.7% at 900$^{\circ}C$ and 0.39~0.75% at 1,20$0^{\circ}C$, respectively. DTA-TG curves of the sericite ores show closely relations with the thermal expansivity.

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Petrographic and Magnetic Fabric Investigation of the Tadaout-Tizi n'Rsas Dyke Swarms in the Eastern Anti-Atlas, Morocco

  • Daoud, Mustapha Ait;Essalhi, Mourad;Essalhi, Abdelhafid;Toummite, Abdeslam
    • Economic and Environmental Geology
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    • v.54 no.6
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    • pp.629-647
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    • 2021
  • Located in the eastern part of the Anti-Atlas, the Tafilalet region shows numerous dykes and sills that crosscut the Paleozoic terrains. The magmatic structures (dykes and sills) of the Tadaout-Tizi n'Rsas (TTR) anticline is studied here, it located neighboring the main branch of the Anti-Atlas Major Fault (AAMF), known in this location as the Oumejrane-Taouz Fault (OJTF). The N20° to N60° trending dykes crosscut the Paleozoic formations (Ordovician to Devonian), whereas sills are injected into the Silurian and Devonian ones. The dyke swarms of TTR have been studied using the Anisotropy of Magnetic Susceptibility (AMS), petrographic study and structural analyses. The petrographic study of the TTR doleritic dykes shows a dominance of plagioclase feldspars, alkali feldspars, amphiboles, pyroxenes and biotite. The dykes contain also mesotype (natrolite), sphene (titanite), apatite, actinolite and pegmatitic enclaves of biotite, orthoclase feldspars and pelites. Concerning field works, they show the deformation of TTR dykes by the Variscan tectonics events, it is marked by the presence of displacements (strike-slip faults) and cleavages. The Magnetic Susceptibility (MS) measured on magmatic specimens show the dominance of ferromagnetic and paramagnetic minerals. The high values of MS in the dykes are due to the presence of hematite, amphibole, pyroxene and biotite. In addition their magnetic fabric, determined by our AMS study, allows us to reconstitute the tectonic event which affected the magmatic bodies. This one is characterized by a magnetic foliation and a NNW-trending lineation that reflect the Variscan shortening orientation.

Petrology of Host Body of Feldspar Deposits in Jechon Ganites (장석광상 모암인 제천반상화강암의 암석학적 특성)

  • Lee, Han-Yeang;Kim, Dai-Oap;Park, Joong-Kwon
    • Journal of the Korean earth science society
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    • v.22 no.5
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    • pp.405-414
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    • 2001
  • Jecheon granite can be divided into two types; porphyritic granite (K-feldspar megacryst bearing) and medium-grained biotite granite. Porphyritic granite, host body of feldspar deposits, is 8${\sim}$11 km in diameter and about 80 $km^{2}$ in area. It mainly contains K-feldspar, plagioclase, biotite and quartz, and magnetite, zircon, sphene and apatite are accessary minerals. Enclosed minerals in K-feldspar megacryst with 3${\sim}$10 cm in diameter are hornblende, plagioclase, quartz, magnetite, apatite, sphene and zircon. Mafic enclaves mainly consisting of hornblende, plagioclase and quartz are frequently observed in porphrytic granite. Medium-grained biotite granite consists of K-feldspar, plagioclase, biotite and hornblende as main, and hematite, muscovite, apatite and zircon as accessary minerals. Core and rim An contents of plagioclase from porphyritic granite, medium biotite granite, K-feldspar megacryst, and mafic enclave are 36 and 21, 40 and 32, 37 and 32, and 43 and 36, respectively. $X_{Fe}$ values of hornblende are 0.57 at biotite granite, 0.51 at K-feldspar mehacryst and 0.45 at mafic enclave. $X_{Fe}$ values of biotite and hornblende are homogeneous without chemical zonation. K-feldspar megacryst shows end member of pure composition with exsolved thin lamellar pure albites. Characteristics of mineral compositions and petrography indicate porphyritic granite is igneous origin and medium-grained biotite granite comes from the same source of magma; biotite granite is initiated to solidly and from residual melt porphyritic granite can be formed. Possibly K-feldspar megacrysts are formde under H$_{2}$O undersaturation condition and near K-feldspar solidus curve temperature; growth rate is faster than nucleation rate. Mafic enclaves are thought to be mingled mafic magma in felsic magma, which is formed from compositional stratigraphy. Estimated equilibrium temperature and pressure for medium-grained biotite granite are about $800^{\circ}C$ and 4.83${\sim}$5.27 Kb, respectively.

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Cooling and Thermal Histories of Cretaceous-Paleogene Granites from Different Fault-bounded Blocks, SE Korean Peninsula: Fission-track Thermochronological Evidences (한반도 동남부의 주단층대에 의해 구분된 지질블록별 백악기-고제3기 화강암의 차별적 냉각-지열 이력: 피션트랙 열연대학적 증거)

  • Shin, Seong-Cheon
    • The Journal of the Petrological Society of Korea
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    • v.21 no.3
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    • pp.335-365
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    • 2012
  • Fission-track (FT) thermochronological records from SE Korean Cretaceous-Paleogene granitic plutons in different fault-bounded blocks reveal contrasting cooling and later thermal histories. Overall cooling patterns are represented by a monotonous (J-shaped) curve in most plutons except some Cretaceous granites retaining a complicated (N-shaped) path due to post-reset re-cooling. Discriminative cooling rates over different temperature ranges can be explained for individual plutons with respect to relative pluton sizes, differences in initial heat loss depending on country rocks, and the presence and proximity of later igneous activity. Even within a single batholith, cooling times for different isotherms were roughly contemporaneous with respect to positions. Insignificant deviations in cooling ages from two different plutons in succession across the Yangsan fault may suggest their contemporaneity before major horizontal fault movement. The extent of later thermal rise recorded locally along the Yangsan and Dongnae fault zones were reached the Apatite Partial Stability Zone ($70-125^{\circ}C$), but did not exceed $200^{\circ}C$. Thermal alteration from fractured zones in the Yangsan-Ulsan fault junction may suggest a thermal reset above $290^{\circ}C$ resulting a complete reset in FT sphene age (31 Ma), caused by a tectonic subsidence in Early Oligocene. A consistency in FT zircon/apatite ages (24 Ma) may imply a sudden rapid cooling over $200-105^{\circ}C$, plausibly related to the abrupt tectonic uplift of the Pohang-Gampo Block including the fault junction in Late Oligocene. A remarkable trend of lower cooling ages for $300-200-100^{\circ}C$ isotherms (i.e., 19% for FT sphene and K-Ar biotite; 20% for FT zircon; 27% for FT apatite) from the east of the Ulsan fault (Pohang-Gampo Block) comparing to the west of the fault may be attributed to retarded cooling times from the Paleogene granites and also reflected by their partially-reduced apatite ages due to later thermal effects.

Characteristics of Heavy Minerals in the South East Yellow Sea Mud (SEYSM) and South West Cheju Island Mud (SWCIM) (황해남동니질대와 제주남서니질대 표층퇴적물의 중광물 특성 비교 연구)

  • Koo, Hyo Jin;Cho, Hyen Goo;Lee, Bu Yeong;Yi, Hi Il
    • Journal of the Mineralogical Society of Korea
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    • v.30 no.3
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    • pp.93-102
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    • 2017
  • Heavy mineral provide an important information for sediment provenance as well as a potential submarine mineral resources. We compared the heavy mineral characteristics between Southeastern Yellow Sea Mud (SEYSM) and Southwestern Cheju Island Mud (SWCIM) surface sediments. We separated heavy minerals from 28 surface sediments in each mudbelt, and then carried out stereo-microscopic, field-emission scanning electron microscopic, energy dispersive spectroscopic and electron probe microanalysis to characterize the type, abundance, mineralogical properties and distribution pattern of heavy mineral. Amphibole and epidote, which are two major heavy minerals, account for more than 70% of total heavy minerals. Zircon and sphene contents are more abundant in SEYSM, whereas apatite and rutile contents are more abundant in SWCIM. Monazite only occurs in some area of SEYSM. Sphene and monazite content decrease to the south in SEYSM. Both garnet-zircon index (GZi) and rutile-zircon index (RuZi) are low in SEYSM but high in SWCIM. Amphiboles in SEYSM primarily correspond to hornblende, however those in SWCIM represent variable composition from pargasite, tshermakite, hornblende to tremolite. Garnets in SEYSM have high Mg and low Ca, but those in SWCIM have low Mg with variable Ca. Different heavy mineral characteristics between SEYSM and SWCIM suggests that sediments in each mudbelt have different provenances. Although this study implies that SEYSM sediment may mostly come from nearby Korean western rivers such as the Keum and Han rivers, this study does not suggest any idea of the source area of SWCIM sediment. Further study is needed to interpret the provenance and transportation mechanism of mudbelt sediments through the heavy mineral research for the river sediments flowing into the Yellow Sea and much more marine sediments.

Preliminary Study of Heavy Minerals in the Central Yellow Sea Mud (황해중앙이질대 퇴적물에 대한 중광물 예비 연구)

  • Lee, Bu Yeong;Cho, Hyen Goo;Kim, Soon-Oh;Yi, Hi Il
    • Journal of the Mineralogical Society of Korea
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    • v.29 no.1
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    • pp.1-10
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    • 2016
  • We studied the heavy minerals in 46 surface sediments collected from the Central Yellow Sea Mud (CYSM) to characterize the type, abundance, mineralogical properties and distribution pattern using the stereo-microscopy, field-Emission scanning electron microscopy (FE SEM) and chemical analysis through the energy dispersive spectrometer (EDS). Heavy mineral assemblages are primarily composed of epidote group, amphibole group, garnet group, zircon, rutile and sphene in descending order. Epidote group and amphibole group minerals account for more than 50% of total heavy minerals. The minerals in epidote group, amphibole group and garnet group in studied area are epidote, edenite and almandine, respectively. When we divided the CYSM into two regions by $124^{\circ}E$, the eastern region contain higher contents of epidote and (zircon + rutile), which are more resistant to weathering but lower of amphibole, which is less resistant to weathering than the western region. Based on this results, it is possible to estimate that the eastern region sediments are transported for a long distance while western region sediments are transported for a short distance from the source area. In the future, the additional study on the heavy minerals in river sediments flowing into the Yellow Sea and much more samples for marine sediments must be carried out to interpret exactly the provenance and sedimentation process.

Characteristics and Provenance of Heavy Minerals in the Yellow Sea and Northern East China Sea (황해 및 동중국해 북부의 중광물 특성과 기원)

  • Koo, Hyo Jin;Lee, Bu Yeong;Cho, Hyen Goo
    • Economic and Environmental Geology
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    • v.53 no.5
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    • pp.505-515
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    • 2020
  • The Yellow Sea and northern East China Sea contain a transgressive sand layer. Numerous sedimentary studies have been carried out in these sand deposits using seismic exploration and core sediment techniques, but few mineralogical studies have been reported. The major purposes of this study are to describe the distributions of heavy minerals throughout the Yellow sea and northern East China Sea and to identify the provenance of coarse sediments using the mineral chemistry. Eight heavy mineral species were identified in the study area (epidote, amphibole, garnet, zircon, sphene, rutile, apatite, and monazite). The study region was divided into six areas (areas A to F) based on heavy mineral distributions and sampling locations. In mineral chemistry, the amphiboles present are classified as edenite and hornblende in the calcic amphibole group, and the garnets are identified primarily as almandine in the pyralspite group. A combined data set of heavy mineral distributions and mineral chemistry showed clear differentiation of the characteristics of the six classified areas, enabling determination of provenance and sedimentary environment. Area A and B in the eastern Yellow Sea were originated from the Korean peninsula, and these regions showed different heavy mineral characteristics by tidal current and coastal current. In addition, monazite was only found in the area B and could be used as an indicator from the southwestern Korean peninsula. Area D and E in the western Yellow Sea showed the characteristics of sediments originating from the Huanghe, and sediment in the area E was derived from the Changjiang. Area C in the northern East China Sea appeared to have Changjiang-origin sediment, and abundant apatite indicated that area C was formed close to the Last Glacial Maximum.