• Title/Summary/Keyword: spectrum and point spectrum

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Analysis of the composition of trail pheromone secreted from live Camponotus japonicus by HS-SPME GC/MS (HeadSpace-Solid Phase MicroExtraction Gas Chromatography/Mass Spectrometry) (HS-SPME GC/MS법을 이용한 일본왕개미의 trail pheromone 성분 분석)

  • Park, Kyung-Eun;Lee, Dong-Kyu;Kwon, Sung Won;Lee, Mi-Young
    • Analytical Science and Technology
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    • v.25 no.5
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    • pp.292-299
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    • 2012
  • GC/MS has been utilized for many applications due to great resolution and reproducibility, which made it possible to build up the database of mass spectrum, while HS-SPME has the advantage of solventfree extraction of volatile compounds. The combination of these two methods, HS-SPME GC/MS, enabled many scientific applications with various possibilities. In this study, the analysis of trail pheromone excreted from live Camponotus japonicus with the feature of solvent-free extraction was carried out and the optimization for this analysis was performed. The major compounds detected were n-decane, n-undecane, and n-tridecane. Optimization for the best detection of these hydrocarbons was processed in the point of SPME parameter (selection of fiber, extraction temperature, extraction time, etc.). The advantage of the analysis of live sample is to analyze phenomenon right after it is excreted by ants. But the experimental process has restriction of extraction temperature and time because of the analysis of live ants. Establishing the process of HS-SPME GC/MS applied to live samples shown in this study can be a breakthrough for the ecofriendly and ethical research of live things.

Analysis of Aroma Patterns in Muskmelon at Different Storage Temperatures Using a Mass Spectrometry-based Electronic Nose (질량분석기 기반 전자코를 이용한 저장 온도별 머스크멜론의 향기 패턴 분석)

  • Youn, Aye-Ree;Noh, Bong-Soo;Kim, Byeong-Sam;Kwon, Ki-Hyun;Kim, Jong-Hoon;Kim, Sang-Hee;Choi, Duck-Joo;Cha, Hwan-Soo
    • Korean Journal of Food Science and Technology
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    • v.43 no.4
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    • pp.419-425
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    • 2011
  • Changes in the flavor of muskmelons stored at different temperatures were examined to judge aroma patterns during storage. A mass-spectrometry based electric nose was used to distinguish the subtle differences in the muskmelon's volatile compounds. The data were used for a discriminant function analysis (DFA), and then the partial least square algorithm was used for a quantitative analysis. Volatile components in the muskmelons increased with storage, and the first discriminant function score (DF1: $r^2$=99.88%, F=3072.5) moved from a positive position to a negative position as the storage period increased. The proper point of maturity was anticipated as the $28^{th}$ day at 0$^{\circ}C$, $21^{st}C$ day at 4 and 7$^{\circ}C$, and $14^{th}$ day at 10$^{\circ}C$. Also, using the DF1 score we could predict the general tendency (vitamin C, stem moisture, acidity) of the muskmelons. The electronic nose revealed that the major volatile compounds that changed during storage of the melons were ethyl ethyl acetate, butyl acetate, nonanol, dodecanoic acid, hexadecanoic acid and tricosane. The amount of volatile compounds detected increased during storage.

Seismic Data Processing For Gas Hydrate using Geobit (Geobit을 이용한 가스 하이드레이트 탐사자료 처리)

  • Jang Seong-Hyung;Suh Sang-Yong;Chung Bu-Heung;Ryu Byung-Jae
    • Geophysics and Geophysical Exploration
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    • v.2 no.4
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    • pp.184-190
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    • 1999
  • A study of gas hydrate is a worldwide popular interesting subject as a potential energy source. A seismic survey for gas hydrate have performed over the East sea by the KIGAM since 1997. General indicators of natural submarine gas hydrates in seismic data is commonly inferred from the BSR (Bottom Simulating Reflection) that occurred parallel to the see floor, amplitude decrease at the top of the BSR, amplitude Blanking at the bottom of the BSR, decrease of the interval velocity, and the reflection phase reversal at the BSR. So the seismic data processing for detecting gas hydrates indicators is required the true amplitude recovery processing, a accurate velocity analysis and the AVO (Amplitude Variation with Offset) analysis. In this paper, we had processed the field data to detect the gas hydrate indicators, which had been acquired over the East sea in 1998. Applied processing modules are spherical divergence, band pass filtering, CDP sorting and accurate velocity analysis. The AVO analysis was excluded, since this field data had too short offset to apply the AVO analysis. The accurate velocity analysis was performed by XVA (X-window based Velocity Analysis). This is the method which calculate the velocity spectrum by iterative and interactive. With XVA, we could determine accurate stacking velocity. Geobit 2.9.5 developed by the KIGAM was used for processing data. Processing results say that the BSR occurred parallel to the sea floor were shown at $367\~477m$ depths (two way travel time about 1800 ms) from the sea floor through shot point 1650-1900, the interval velocity decrease around BSR and the reflection phase reversal corresponding to the reflection at the sea floor.

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Experimental Study for the Resonance Effect of the Power Buoy Amplitude (공진형 전력부이의 상하변위증폭 효과에 관한 실험적 연구)

  • Kweon, Hyuck-Min;Koh, Hyeok-Jun;Kim, Jung-Rok;Choi, Young-Hwan
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.33 no.2
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    • pp.585-594
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    • 2013
  • In this study, laboratory experiments and numerical simulations were conducted to test the performance of resonance power buoy system proposed by Kweon et al.(2010). The system is composed of a linear generator and a mooring buoy. The mover of the linear generator mainly has heave motion driven by vertical oscillation of the buoy. In this system, the velocity discrepancy between the mover and the buoy makes electricity. However, ocean wave energy as a natural resource around Korean peninsula is comparatively small and the driving force for producing electricity is not enough for commercialization. Therefore, it is necessary that the buoy motion be amplified by using resonance characteristics. In order to verify the resonance effects on the test power buoy, the experimental investigations were conducted in the large wave flume (length of 110 m, width of 8 m, maximum depth of 6 m) equipped with regular and random plunger wave generator. The resonance draft of test power buoy is designed for the corresponding period of incident wave, 1.96 sec. Regular wave test results show that the heave response amplitude operator(RAO) by a test buoy has the amplification of 5.66 times higher compared to the wave amplitude at the resonance period. Test results of random waves show that the buoy has the largest spectrum area of 20.73 times higher at the point of not the resonance period but the shorter one of 1.85 sec. Therefore this study suggests the resonance power buoy for wave power generation for commercial application in the case of the coastal and oceanic area with smaller wave energy.

Neutron Dose Measurements Using TLDs in a 252Cf Neutron Field (252Cf 중성자장에서 열형광선량계(TLD)를 이용한 중성자 방사선량 측정)

  • Chang, Insu;Kim, Sang In;Lee, Jung Il;Kim, Jang Lyurl;Kim, Bong Hwan
    • Journal of Radiation Protection and Research
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    • v.38 no.1
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    • pp.37-43
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    • 2013
  • In case of neutron dose measurement using TLDs (thermo-luminescence dosimeters), because the neutron energy dependence of the TLD is very high, the calibration of the energy response according to the characteristics of the neutron spectrum of workplace is required. In the present study, the ambient dose equivalent rates inside and around the Long-Counter (neutron detector) with narrow and complex inside in the neutron field of $^{252}Cf$ were evaluated. The calibration factors to account for the neutron energy dependence of TLDs were established for both the bare and $D_2O$ modulated $^{252}Cf$ neutron beams, respectively. The values of the TLD's measurement were compared with the computational results of the MCNPX (Monte Carlo N-Particles transport code). When using the two calibration factors of the TLD than a single calibration factor, the measured and the calculated values at the point of verification outside and inside the Long-Counter were in more good agreement. This results show that TLD should be calibrated in the reference neutron field similar to workplace situation.

Inelastic Dynamic Analysis of Structure Subjected to Across-Wind Load (풍직각방향 풍하중이 작용하는 구조물의 비탄성 동적 해석)

  • Ju-Won Kim
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.36 no.3
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    • pp.185-192
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    • 2023
  • In this study, fluctuating wind velocity for time history analysis is simulated by a single variate, single-dimensional random process using the KBC2022 spectrum about across-wind direction. This study analyzed and obtained the inelastic dynamic response for structures modeled as a single-degree-of-freedom system. It is assumed that the wind response is excellent in the primary mode, the change in vibration owing to plasticization is minor, along-wind vibration and across-wind vibration are independent, and the effect of torsional vibration is small. The numerical results, obtained by the Newmark-𝛽 method, shows the time-history responses and trends of maximum displacements. As a result of analyzing the inelastic dynamic response of the structure with the second stiffness ratio(𝛼) and yield displacement ratio (𝛽) as variables, it is identified that as the yield displacement ratio (𝛽) increases when the second stiffness ratio is constant, the maximum displacement ratio decreases, then reaches a minimum value, and then increases. When the stiffness ratio is greater than 0.5, there is a yield point ratio at which the maximum displacement ratio is less than 1, indicating that the maximum deformation is reduced compared to the elastically designed building even if the inelastic behavior is permitted in the inelastic wind design.

Application of the JMA instrumental intensity in Korea (일본 기상청 계측진도의 국내 활용)

  • Kim, Hye-Lim;Kim, Sung-Kyun;Choi, Kang-Ryong
    • Journal of the Earthquake Engineering Society of Korea
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    • v.14 no.2
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    • pp.49-56
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    • 2010
  • In general, the seismic intensity deduced from instrumental data has been evaluated from the empirical relation between the intensity and the PGA. From the point of view that the degree of earthquake damage is more closely associated with the seismic intensity than with the observed PGA, JMA developed the instrumental seismic intensity (JMA instrumental intensity) meter that estimate the real-time seismic intensity from the observed strong motion data to obtain a more correct estimate of earthquake damage. The purpose of the present study is to propose a practical application of the JMA instrumental intensity in Korea. Since the occurrence of strong earthquakes is scarce in the Korean Peninsula, there is an insufficiency of strong motion data. As a result, strong motion data were synthesized by a stochastic procedure to satisfy the characteristics of a seismic source and crustal attenuation of the Peninsula. Six engineering ground motion parameters, including the JMA instrumental intensity, were determined from the synthesized strong motion data. The empirical relations between the ground motion parameters were then analyzed. Cluster analysis to classify the parameters into groups was also performed. The result showed that the JMA acceleration ($a_0$) could be classified into similar group with the spectrum intensity and the relatively distant group with the CAV (Cumulative Absolute Velocity). It is thought that the $a_0$ or JMA intensity can be used as an alternative criterion in the evaluation of seismic damage. On the other hand, attenuation relation equations for PGA and $a_0$ to be used in the prediction of seismic hazard were derived as functions of the moment magnitude and hypocentral distance.

Non-contact Stress Measurement in Steel Member of PSC Box Bridge Using Raman Spectroscopy (라만 형광 분광법을 이용한 PSC 박스교 인장케이블 응력측정방법 연구)

  • Kim, Jongwoo;Kim, Namgyu
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.23 no.2
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    • pp.130-134
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    • 2019
  • In this paper, a laser-based non-contact load cell is newly developed for measuring forces in prestressed concrete tendons. First, alumina particles have been sprayed onto an empty load cell which has no strain gauges on it, and the layer has been used as a passive stress sensor. Then, the spectral shifts in fluorescence spectroscopy have been measured using a laser-based spectroscopic system under various force levels, and it has been found that the relation of applied force and spectral shift is linear in a lab-scale test. To validate the field applicability of the customized load cell, a full-scale prestressed concrete specimen has been constructed in a yard. During the field test, it was, however, found that the coating surface has irregular stress distribution. Therefore, the location of a probe has to be fixed onto the customized load cell for using the coating layer as a passive stress sensor. So, a prototype customized load cell has been manufactured, which consists of a probe mount on its casing. Then, by performing lab-scale uniaxial compression tests with the prototype load cell, a linear relation between compression stress and spectrum shift at a specific point where laser light had been illuminated has been detected. Thus, it has a high possibility to use the prototype load cell as a force sensor of prestressed concrete tendons.

A CELP Coder using the Band-Divided Long Term Prediction (대역 분할 장구간 예측을 이용한 CELP 부호화기)

  • Choi, Young-Soo;Kang, Hong-Goo;Lim, Myoung-Seob;Ahn, Dong-Soon;Youn, Dae-Hee
    • The Journal of the Acoustical Society of Korea
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    • v.14 no.4
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    • pp.38-45
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    • 1995
  • In this paper a way to improve the performance of the long term prediction is proposed, which adopts the Multi-band Excitation (MBE) method in addition to the Code-Excited Linear Prediction (CELP) method at low bit rates below 4.8 kbps. In the proposed method, the multiband long term prediction is performed on the periodic components which still remain after the long term prediction of the conventional CELP method. At this point, the whole frequency region is divided into subbands whose size is equal to the spacing between the harmonics of the fundamental frequency, and the periodic multiband excitation signals. are represented as the sum of sine waves approximately as large as the spectrum of the excitation signals, so that the actual characteristics of the excitation signals can be better taken into account. To evaluate the performance of the proposed method, computer simulation is performed at 4.8 kbps. The 4.8 kbps DoD CELP and the 4.4 kbps IMBE were chosen as the reference vocoders for the speech quality measure. The result of the perceptual speech quality measure showed that the performance of the proposed method is better than that of the 4.8 kbps DoD CELP vocoder, and similar to that of the 4.4 kbps IMBE vocoder.

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Experimental Analysis on Vibration of Composite Plate by Using FBG Sensor System (브래그 격자 센서 시스템을 이용한 복합재 평판 진동의 실험적 해석)

  • Kim, Dae-Hyun
    • Journal of the Korean Society for Nondestructive Testing
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    • v.29 no.5
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    • pp.436-441
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    • 2009
  • A fiber optic sensor is prospective to be applied to structural health monitoring. Especially, a fiber Bragg grating(FBG) sensor is one of the most popular sensors for the structural health monitoring. The FBG sensor has several demodulation systems for tracking the shift of the Bragg wavelength. The dynamic bandwidth is dependent on the demodulation system. In this paper, the sensing mechanism is that the slope of the optical spectrum of FBG could be used as its sensitivity when the tunable laser shot the monochromatic laser wavelength at the highest slope point. In this technique, the high sensitivity is guaranteed even though the sensing range is limited. In an example of the application, the composite plate embedding a FBG sensor was manufactured by using an autoclave method and the above sensing mechanism was applied to the composite plate. Firstly, the natural frequencies of the plate were successfully measured by the FBG sensor during the impact hammer test. Secondly, a high-power speaker was used to force the plate to be vibrated at the specific frequency that was one of the natural frequencies. During the shaking, the FBG sensor measures the dynamic characteristics and ESPI was also used to measure the mode shape. From the two dynamic tests, the availability of the FBG sensor system and the ESPI was proven as a technique for measuring the dynamic characteristics of composite structure.