• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.35 no.3
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• pp.223-231
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• 2022

Spectroscopies are the most widely used for understanding the crystallographic, chemical, and physical aspects of materials; therefore, numerous commercial and non-commercial software have been introduced to help researchers better handling their spectroscopic data. However, not many researchers, especially early-stage ones, have a proper background knowledge on the choice of fitting functions and a technique for actual fitting, although the essence of such data analysis is peak fitting. In this regard, we present a practical guide for peak fitting for data analysis. We start with a basic-level theoretical background why and how a certain protocol for peak fitting works, followed by a step-by-step visualized demonstration how an actual fitting is performed. We expect that this contribution is sure to help many active researchers in the discipline of materials science better handle their spectroscopic data.

• Publications of The Korean Astronomical Society
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• v.30 no.2
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• pp.231-232
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• 2015

R Canis Majoris is a bright, short-period ($1^d$.1359) Algol-type eclipsing binary. For a long time, it was considered to be a low-mass binary star with $M_1=1.1M_{\odot}$ and $M_2=0.17M_{\odot}$ primary and secondary components, respectively (Tomkin, 1985). Glazunova, Yushchenko & Mkrtichian (2009) found new masses for the primary and secondary components of $M_1=1.81M_{\odot}$ and $M_2=0.23M_{\odot}$, respectively and resolved a long-standing problem with the low masses of components for this binary. Budding and Butland (2011) confirmed the results of Glazunova, Yushchenko & Mkrtichian and obtained improved orbits and masses. New spectroscopic observations of R CMa were done during 8 nights on December 2012 with the 2.4-meter telescope of the Thai National Observatory (TNO) and fibre-fed medium resolution echelle spectrograph. We obtained new, accurate orbital radial velocities of the two components of this binary system. Results of these investigations and the new orbital parameters are presented.

• Korean Journal of Optics and Photonics
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• v.10 no.3
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• pp.208-213
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• 1999

We proposed a new technique to precisely calibrate the angle of incidence in spectroscopic ellipsometer. The proposed technique can be useful to the thickness measurement of semiconductor thin films and optical thin films. The usefulness has been confirmed experimentally. We cut a block of optical glass into two pieces and made a prism as well as a slab using each piece. The apex angle and the angle of the minimum deviation of prism were measured. From these angles, the refractive index of glass material was calculated. From the analysis of the spectro-ellipsometric data collected near Brewster's angle, we could not only determine the error in the angle of incidence in the spectroscopic ellipsometer, but also calibrated the angle of incidence to the accuracy of 0.01 degree.

• Korean Journal of Optics and Photonics
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• v.1 no.1
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• pp.73-86
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• 1990

The technique of Spectroscopic Ellipsometry (SE) has been examined with emphasis on its inherent sensitivity to the existence of thin films or surface equivalents. A brief review of related theories like the Fresnel reflection coefficients, the effect of a multilayer upon reflectivities, together with the validity of the effective medium theory and the modelling procedure, is followed by a short description of the experimental setup of a rotating polarizer type SE as well as the necessful expressions which lead to tan and cos. Out of its numerous, successful applications, a few are exampled to convince a reader that SE can be applied to a variety of research fields related to surface, interface and thin films. Specifically, those are adsorption and/or desorption on metals or semiconductors, oxidation process, formation of passivation layers on an electrode, thickness determination, interface between semiconductor and its oxide, semiconductor heterojunctions, surface microroughness, void distribution of dielectric, optical thin films, depth profile of multilayered samples, in-situ or in-vitro characterization of a solid surface immersed in electrolyte during electrochemical, chemical, or biological treatments, and so on. It is expected that the potential capability of SE will be widely utilized in a very near future, taking advantage of its sensitivity to thin films or surface equivalents, and its nondestructive, nonperturbing characteristics.

• Journal of the Semiconductor & Display Technology
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• v.17 no.3
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• pp.70-74
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• 2018

In typical spectroscopic ellipsometry, the optical and geometrical properties of thin film and nano pattern can be obtained by measuring the polarization state of light reflected/transmitted from the object by rotating a analyzer or a compensator. We proposed a snapshot spectroscopic ellipsometric system based on a modified Michelson interferometer to overcome the time-consuring measurement principle due to rotating part. The proposed system provides spectral ellipsometric parameters (psi, delta) in real time by using a single spectral interference signal generated in the interferometric polarization module. However, it has a long-term stability problem resulting in delta(k) drift. In this paper, it is experimentally proved that the drift problem is caused by anisotropic refractive index change of the beam intersection layer in beam splitter of interferometer.

• The Bulletin of The Korean Astronomical Society
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• v.44 no.1
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• pp.56.3-56.3
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• 2019

We are currently living in the era of the wide field cosmological surveys, either spectroscopic such as Dark Energy Spectrograph Instrument or photometric such as the Dark Energy Survey or the Large Synoptic Survey Telescope. By analyzing the distribution of matter clustering, we can use the growth of structure, in combination with measurements of the expansion of the Universe, to understand dark energy or to test different models of gravity. But we also live in the era of multi-tracer or multi-messenger astrophysics. In particular, during the next decades radio surveys will map the matter distribution at higher redshifts. Like in optical surveys, there are radio imaging surveys such as continuum radio surveys such as the ongoing EMU or spectroscopic by measuring the hydrogen 21cm line. However, we can also use intensity mapping as a low resolution spectroscopic technique in which we use the intensity given by the emission from neutral hydrogen from patches of the sky, at different redshifts. By cross-correlating this maps with galaxy catalogues we can improve our constraints on cosmological parameters and to understand better how neutral hydrogen populates different types of galaxies and haloes. Creating realistic mock intensity mapping catalogues is necessary to optimize the future analysis of data. I will present the mock neutral hydrogen catalogues that we are developing, using the Horizon run 4 simulations, to cross-correlate with mock galaxy catalogues from low redshift surveys and I will show the preliminary results from the first mock catalogues.

• Near Infrared Analysis
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• v.1 no.2
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• pp.41-44
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• 2000

The objectives of this study are to discriminate the geographical origin and cultivation years of ginseng based on the near-infrared(NIR) reflectance spectroscopic analysis. Korea and China ginseng samples were prepared for discrimination of geographical origin. 4, 5 and 6 years-old ginseng samples from Korea were prepared for discrimination of cultivation years. Used spectrometer were InfraAlyzer 500, InfraAlyzer 400 and Fiber optic. Sample type of ginseng was 3, whole ginseng radix, slide section and powder type. The accuracy was affected by sample types and instruments. The accuracy for discrimination geographical origin was 97% in calibration model using IA 500 and ginseng powder. For discrimination of cultivation years, the model with slide selection using IA500 were relative accurate. The accuracy was 96.7% for 4-year, 91.3% for 5-year and 89.3% for 6-year old ginseng. The study shows that NIR spectroscopic analysis can be used to discriminate the geographical origin and cultivation years of ginseng with acceptable accuracy.

• Journal of Biosystems Engineering
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• v.40 no.2
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• pp.124-136
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• 2015

Purpose: Grain quality is a general concept that covers many characteristics, ranging from physical to biochemical and physiochemical properties. Rice aging during storage is currently a challenge in the rice industry, and is a complicated process involving changes in all of the above properties. Spectroscopic techniques can be used to obtain information on the quality of rice samples in a non-destructive manner. Methods: The objective of this review was to highlight the factors that contribute to rice quality and aging, and to describe various spectroscopic modalities, particularly vibrational and hyperspectral imaging, for the assessment of rice quality. Results: Starch and protein are the main components of the rice endosperm, and are therefore key factors contributing to eating and cooking quality. While the overall starch, protein, and lipid content in the rice grain remains essentially unchanged during storage, structural changes do occur. These changes affect pasting and gel properties, and ultimately the flavor of cooked rice. In addition, grain quality is significantly affected by growing and environmental conditions, such as water availability, temperature, fertilizer application, and salinity stress. These properties can be evaluated using spectroscopic techniques, and rice samples can be discriminated by using multivariate statistical analysis methods. Conclusion: Hyperspectral imaging and vibrational spectroscopy techniques have good potential for determining rice quality properties in a non-invasive manner, i.e., not requiring the introduction of instruments into the rice grain.

• Bulletin of the Korean Chemical Society
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• v.34 no.3
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• pp.823-826
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• 2013

A low-${\varepsilon}$ solid-state NMR(Nuclear Magnetic Resonance) probe was developed for the spectroscopic analysis of two-dimensional $^{15}N-^1H$ heteronuclear dipolar coupling in dilute membrane proteins oriented in hydrated and dielectrically lossy lipid environments. The system employed a 800 MHz narrow-bore magnet. A solenoid coil strip shield was used to reduce deleterious RF sample heating by minimizing the conservative electric fields generated by the double-tuned resonator at high magnetic fields. The probe's design, construction, and performance in solid-state NMR experiments at high magnetic fields are described here. Such high-resolution solid-state NMR spectroscopic analysis of static oriented samples in hydrated phospholipid bilayers or bicelles could aid the structural analysis of dilute biological membrane proteins.

• Biotechnology and Bioprocess Engineering:BBE
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• v.3 no.2
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• pp.61-66
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• 1998

Glycolipids produced by Pseudomonas aeruginosa YPJ-80 were characterized by chromatographic and spectorscopic techniques as a mixture of two rhamnolipids. For recovery of glycolipids from the culture broth, various isolation methods including ultrafiltration, adsorption and solvent extraction were compared. Ultrafiltration showed the best results in terms of glycolipids recovery. Further purification for spectroscopic analysis was carried out by adsorption chromatography and preparative thin layer chromatography. From the spectroscopic analysis, such as IR spectroscopy. FAB-MS, 1H-NMR and 13C-NMR and hydrolysis analysis, the glycolipids were identified as L-${\alpha}$-rhamnopyranosyl-${\beta}$-hydroxydecanoly-${\beta}$-hydroxydecanoate and 2-O-${\alpha}$-L-rhamnopyranosyl-${\alpha}$-L-rhamnopyranosyl-${\beta}$-hydroxydecanoyl-${\beta}$-hydroxydecanoate. Monorhamnolipid and dirhamnolipid lowered the surface tension of water to 28.1 mN/M and 29.3 mN/m, respectively.