• Title/Summary/Keyword: spectral methods

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Current Status of GM Crop Discrimination Technology Using Spectroscopy (분광분석법을 이용한 형질전환 작물 판별 기술 현황)

  • Sohn, Soo-In;Oh, Young-Ju;Cho, Woo-Suk;Cho, Yoonsung;Shin, Eun-Kyoung;Kang, Hyeon-jung
    • Korean Journal of Environmental Agriculture
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    • v.39 no.3
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    • pp.263-272
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    • 2020
  • BACKGROUND: This paper describes the successful discrimination of GM crops from the respective wild type (WT) controls using spectroscopy and chemometric analysis. Despite the many benefits that GM crops, their development has raised concerns, particularly about their potential negative effects on food production and the environment. From this point of view, the introduction of GM crops into the market requires the development of rapid and accurate identification technologies to ensure consumer safety. METHODS AND RESULTS: The development of a GM crop discrimination model using spectroscopy involved the pre-processing of the collected spectral information, the selection of a discriminant model, and the verification of errors. Examples of GM versus WT discrimination using spectroscopy are available for soybeans, tomatoes, corn, sugarcane, soybean oil, canola oil, rice, and wheat. Here, we found that not only discrimination but also cultivar grouping was possible. CONCLUSION: Since for the determination of GM crop there is no pre-defined pre-processing method or calibration model, it is extremely important to select the appropriate ones to increase the accuracy in a case-by-case basis.

Remote Estimation Models for Deriving Chlorophyll-a Concentration using Optical Properties in Turbid Inland Waters : Application and Valuation (분광특성을 이용한 담수역 클로로필-a 원격 추정 모형의 적용과 평가)

  • Lee, Hyuk;Kang, Taegu;Nam, Gibeom;Ha, Rim;Cho, Kyunghwa
    • Journal of Korean Society on Water Environment
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    • v.31 no.3
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    • pp.272-285
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    • 2015
  • Accurate assessment of chlorophyll-a (Chl-a) concentrations in inland waters using remote sensing is challenging due to the optical complexity of case 2 waters. and the inherent optical properties (IOPs) of natural waters are the most significant factors affecting light propagation within water columns, and thus play indispensable roles on estimation of Chl-a concentrations. Despite its importance, no IOPs retrieval model was specifically developed for inland water bodies, although significant efforts were made on oceanic inversion models. So we have applied and validated a recently developed Red-NIR three-band model and an IOPs Inversion Model for estimating Chl-a concentration and deriving inland water IOPs in Lake Uiam. Three band and IOPs based Chl-a estimation model accuracy was assessed with samples collected in different seasons. The results indicate that this models can be used to accurately retrieve Chl-a concentration and absorption coefficients. For all datasets the determination coefficients of the 3-band models versus Chl-a concentration ranged 0.65 and 0.88 and IOPs based model versus Chl-a concentration varied from 0.73 to 0.83 respectively. and Comparison between 3-band and IOPs based models showed significant performance with decrease of root mean square error from 18% to 33.6%. The results of this study provides the potential of effective methods for remote monitoring and water quality management in turbid inland water bodies using hyper-spectral remote sensing.

Study on the $N_2$ Plasma Treatment of Nanostructured $TiO_2$ Film to Improve the Performance of Dye-sensitized Solar Cell

  • Jo, Seul-Ki;Roh, Ji-Hyung;Lee, Kyung-Joo;Song, Sang-Woo;Park, Jae-Ho;Shin, Ju-Hong;Yer, In-Hyung;Park, On-Jeon;Moon, Byung-Moo
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.02a
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    • pp.337-337
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    • 2012
  • Dye sensitized solar cell (DSSC) having high efficiency with low cost was first reported by Gr$\ddot{a}$tzel et al. Many DSSC research groups attempt to enhance energy conversion efficiency by modifying the dye, electrolyte, Pt-coated electrode, and $TiO_2$ films. However, there are still some problems against realization of high-sensitivity DSSC such as the recombination of injected electrons in conduction band and the limited adsorption of dye on $TiO_2$ surface. The surface of $TiO_2$ is very important for improving hydrophilic property and dye adsorption on its surface. In this paper, we report a very efficient method to improve the efficiency and stability of DSSC with nano-structured $TiO_2$. Atmospheric plasma system was utilized for nitrogen plasma treatment on nano-structured $TiO_2$ film. We confirmed that the efficiency of DSSC was significantly dependent on plasma power. Relative in the $TiO_2$ surface change and characteristics after plasma was investigated by various analysis methods. The structure of $TiO_2$ films was examined by X-ray diffraction (XRD). The morphology of $TiO_2$ films was observed using a field emission scanning electron microscope (FE-SEM). The surface elemental composition was determined using X-ray photoelectron spectroscopy (XPS). Each of plasma power differently affected conversion efficiency of DSSC with plasma-treated $TiO_2$ compared to untreated DSSC under AM 1.5 G spectral illumination of $100mWcm^{-2}$.

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Prediction of Soluble Solids Content of Chestnut using VIS/NIR Spectroscopy

  • Park, Soo Hyun;Lim, Ki Taek;Lee, Hoyoung;Lee, Soo Hee;Noh, Sang Ha
    • Journal of Biosystems Engineering
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    • v.38 no.3
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    • pp.185-191
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    • 2013
  • Purpose: The present study focused on the estimation of soluble solids content (SSC) of chestnut using reflectance and transmittance spectra in range of VIS/NIR. Methods: Four species intact/peeled chestnuts were used for acquisition of spectral data. Transmittance and reflectance spectra were used to develop the best PLS model to estimate SSC of chestnut. Results: The model developed with the transmitted energy spectra of peeled chestnuts rather than intact chestnuts and with range of NIR rather than VIS performed better. The best $R^2$ and RMSEP of cross validation were represented as 0.54 and $1.85^{\circ}Brix$. The results presented that the reflectance spectra of peeled chestnuts by species showed the best performance to predict SSC of chestnut. $R^2$ and RMSEP were 0.55 and $1.67^{\circ}Brix$. Conclusions: All developed models showed RMSEP around $1.44{\sim}2.54^{\circ}Brix$, which is considered not enough to estimate SSC accurately. It was noted that $R^2$ of cross validation that we found were not high. For all that, grading of the fruits in two or three classes of SSC during postharvest handling seems possible with an inexpensive spectrophotometer. Furthermore, the development of estimation of SSC by each chestnut species could be considered in that SSC distribution is clustering in different range by species.

Rapid and Nondestructive Discrimination of Fusarium Asiaticum and Fusarium Graminearum in Hulled Barley (Hordeum vulgare L.) Using Near-Infrared Spectroscopy

  • Lim, Jong Guk;Kim, Gi Young;Mo, Chang Yeun;Oh, Kyoung Min;Kim, Geon Seob;Yoo, Hyeon Chae;Ham, Hyeon Heui;Kim, Young Tae;Kim, Seong Min;Kim, Moon S.
    • Journal of Biosystems Engineering
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    • v.42 no.4
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    • pp.301-313
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    • 2017
  • Purpose: This study was conducted to discriminate between normal hulled barley and Fusarium (Fusarium asiaticum and Fusarium graminearum) infected hulled barley by using the near-infrared spectroscopy (NIRS) technique. Methods: Fusarium asiaticum and Fusarium graminearum were artificially inoculated in hulled barley and the reflectance spectrum of the barley spike was obtained by using a near-infrared spectral sensor with wavelength band in the range 1,175-2,170 nm. After obtaining the spectrum of the specimen, the hulled barley was cultivated in a greenhouse and visually inspected for infections. Results: From a partial least squares discriminant analysis (PLS-DA) prediction model developed from the raw spectrum data of the hulled barley, the discrimination accuracy for the normal and infected hulled barley was 99.82% (563/564) and 100% (672/672), respectively. Conclusions: NIRS is effective as a quick and nondestructive method to detect whether hulled barley has been infected with Fusarium. Further, it expected that NIRS will be able to detect Fusarium infections in other grains as well.

Hyperspectral Imaging and Partial Least Square Discriminant Analysis for Geographical Origin Discrimination of White Rice

  • Mo, Changyeun;Lim, Jongguk;Kwon, Sung Won;Lim, Dong Kyu;Kim, Moon S.;Kim, Giyoung;Kang, Jungsook;Kwon, Kyung-Do;Cho, Byoung-Kwan
    • Journal of Biosystems Engineering
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    • v.42 no.4
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    • pp.293-300
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    • 2017
  • Purpose: This study aims to propose a method for fast geographical origin discrimination between domestic and imported rice using a visible/near-infrared (VNIR) hyperspectral imaging technique. Methods: Hyperspectral reflectance images of South Korean and Chinese rice samples were obtained in the range of 400 nm to 1000 nm. Partial least square discriminant analysis (PLS-DA) models were developed and applied to the acquired images to determine the geographical origin of the rice samples. Results: The optimal pixel dimensions and spectral pretreatment conditions for the hyperspectral images were identified to improve the discrimination accuracy. The results revealed that the highest accuracy was achieved when the hyperspectral image's pixel dimension was $3.0mm{\times}3.0mm$. Furthermore, the geographical origin discrimination models achieved a discrimination accuracy of over 99.99% upon application of a first-order derivative, second-order derivative, maximum normalization, or baseline pretreatment. Conclusions: The results demonstrated that the VNIR hyperspectral imaging technique can be used to discriminate geographical origins of rice.

The Effect of Electroacupuncture at the PC6(Naegwan) and TE5 (Oegwan) on the EEG (내관, 외관 전침 자극이 뇌파변화에 미치는 영향)

  • Yim, Jin-Teck;Kim, Su-Hyun;Lee, Sang-Ryong
    • Journal of Pharmacopuncture
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    • v.6 no.3
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    • pp.91-106
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    • 2003
  • Objectives : The aim of this study was to examine the effects of electroacupuncture(EA) at the PC6(Naegwan) and the TE5 (Oegwan) on nounal humans using power spectral analysis. Methods : EEG power spectrum exhibit site-specific and state-related differences in specific frequency bands. In this study, power spectrum was used as a measure of complexity. 30 channel EEG study was carried out in 30 subjects(30 males ; age=23.7 years). Results : In ${\alpha}$(alpha) band, the power values at F7 channels(p<0.05) during the PC6-acupoint treatment were significantly were decreased. In ${\beta}$(beta) band, the power values at Fp1, Fz, TT1, T5, P3, P4, Po1, P02, O1, Oz, O2 channels(p<0.05) during the non-acupoint treatment and at Fp1, F4, F8 channels(p<0.05) during the TE5-acupoint treatment significantly were increased. In ${\theta}$(theta) band, the power values at Fp1 channels(p<0.05) during the non-acupoint treatment and at Oz channels(p<0.05) the TE5-acupoint treatment significantly were increased. but, the power values at F7 channels(p<0.05) during the non-acupoint treatment were significantly were decreased. In ${\delta}$(delta) band, the power values at TCP1, TCP2, CP1, T5 channels(p<0.05) during PC6-acupoint treatment were increased and the power values at F7, TT2 channels(p<0.05) during non-acupoint treatment were increased. but, the power values at the TE5-acupoint treatment significantly was decreased than the before-acupuncture treatment.

Using Hyperspectral Fluorescence Spectra of Deli Commodities to Select Wavelengths for Surveying Deli Food Contact Surfaces

  • Lefcourt, Alan M.;Beck, Elizabeth A.;Lo, Y. Martin;Kim, Moon S.
    • Journal of Biosystems Engineering
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    • v.40 no.2
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    • pp.145-152
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    • 2015
  • Purpose: The inability to adequately judge the efficacy of cleaning and sanitation procedures in deli departments is a recognized food safety concern. In a prior study, our research group demonstrated that visual inspection of cleaned produce processing surfaces could be enhanced through the use of a portable fluorescence imaging device that detected residual produce residues. Methods: To explore the feasibility of using fluorescence imaging to similarly detect residual deli residues, spectra of American, Cheddar, Provolone, and Swiss cheeses and of processed chicken, ham, roast beef, and turkey were acquired using a laboratory hyperspectral imaging system. Circular punches of these commodities were placed onto stainless steel and high density polyethylene coupons for imaging. The coupon materials were selected to represent common surfaces found in deli departments. Results: Analysis of hyperspectral fluorescence images showed that cheeses exhibited peaks in the blue-green region and at around 675 nm. Meats exhibited peaks in the blue-green region with one of four ham and one of four chicken brands exhibiting peaks at around 675 nm, presumably due to use of plant-derived additives. When commodities were intermittently imaged over two weeks, locations of spectral peaks were preserved while intensity of peaks at shorter wavelengths increased with time. Conclusion: These results demonstrate that fluorescence imaging techniques have the potential to enhance surface hygiene inspection in deli departments and, given the immediate availability of imaging results, to help optimize routine cleaning procedures.

Dynamic Amplification Characteristics of Major Domestic Seismic Observation Sites using Ground Motions from Domestic Macro Earthquakes (국내 중규모지진의 자료를 이용한 주요 관측소 지반의 동적 증폭특성에 관한 연구)

  • Kim, Jun Kyoung
    • The Journal of Engineering Geology
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    • v.22 no.4
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    • pp.399-408
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    • 2012
  • To estimate seismic source and soil-structure interaction more reliably, site amplification characteristics should be considered. Among the various estimation methods, we used Nakamura's method (1989) to estimate site amplification. This method was originally applied to background noise; however, it has recently been successfully applied to S-wave and Coda-wave energy, and is applied to S-waves in the present study. We used more than 180 observed ground motions from 23 macro-earthquakes and then analyzed site amplification characteristics at eight seismic stations. Each station showed characteristics of site amplification properties in the low-, high- and resonance-frequency ranges. Comparison of the present results with those of other studies provide successful information regarding the dynamic amplification of domestic site characteristics and site classification.

The Effect of Hwangryunhaedoktang Herbal Acupuncture at the $PC_6$(Naegwan) on the EEG (내관$(PC_6)$의 황련해독탕 약침이 EEG 변화에 미치는 효과)

  • Kim, Dong-Seok;Lee, Sang-Ryong
    • Korean Journal of Acupuncture
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    • v.21 no.3
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    • pp.39-58
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    • 2004
  • Objectives : The aim of this study was to examine the effects of Hwangryunhaedoktang Herbal acupuncture at the PC6(Naegwan) on the EEC of normal human being by using power spectral analysis. Methods : EEC power spectrum exhibit site-specific and state-related differences in specific frequency bands. In this study, power spectrum was used as a measure of complexity. 32 channel EEC study was carried out in 11 subjects (11 males; age=27.8 years). Results : In ${\alpha}(alpha)$ band, the power values at T3, TT1, CP1, T5, Po2, O1, Oz channels(p<0.05) during the PC6-acupoint treatment were increased significantly. In ${\beta}(beta)$ band, the power values at TT1, CP1, T5, P3, Po2, O1, Oz channels(p<0.05) during the PC6-acupoint treatment were increased significantly. In ${\theta}(theta)$ band, the power values at T3, TT1, CP1, Po2, O1, Oz channels(p<0.05) during the PC6-acupoint treatment were increased significantly. In ${\delta}(delta)$ band, the power values at F4, T3, CP1, O1, Oz, O2 channels(p<0.05) during the PC6-acupoint treatment were increased significantly. Conclusions : This results suggest that Hwangryunhaedoktang Herbalacupuncture at the PC6 is significantly in ${\alpha}(alpha)$ band.

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