• Bulletin of the Korean Chemical Society
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• v.19 no.6
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• pp.654-660
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• 1998

$[Fe^{II}Fe^{III}BPLMP(OAc)_2](BPh_4)_2$ (1), a new model for the reduced form of the purple acid phosphatases, has been synthesized by using a dinucleating ligand, 2,6-bis[((2-pyridylmethyl)(6-methyl-2-pyridylmethyl)amino) methyl]-4-methylphenol (HBPLMP). Complex I has been characterized by X-ray diffraction method as having (μ-phenoxo)bis(acetato)diiron core. Complex 1 was crystallized in the monoclinic space group C2/c with the following cell parameters: a=41.620(6) Å, b=14.020(3) Å, c=27.007(4) Å, β=90.60(2)°, and Z=8. The iron centers in the complex 1 are ordered as indicated by the difference in the Fe-O bond lengths which match well with typical $Fe^{III}-O\; and\; Fe^{II}-O$ bond lengths. Complex 1 has been studied by electronic spectral, NMR, EPR, SQUID, and electochemical methods. Complex 1 exhibits strong bands at 592 nm, 1380 nm in $CH_3CN$ (ε = 1.0 × 103 , 3.0 × 102). These are assigned to $phenolate-to-Fe^{III}$ and intervalence charge-transfer transitions, respectively. Its NMR spectrum exhibits sharp isotropically shifted resonances, which number half of those expected for a valence-trapped species, indicating that electron transfer between $Fe^{II}\;and\;Fe^{III}$ centers is faster than NMR time scale. This complex undergoes quasireversible one-electron redox processes. The $Fe^{III}_2/Fe^{II}Fe^{III}\;and\;Fe^{II}Fe^{III}/Fe^{II}_2$ redox couples are at 0.655 and -0.085 V vs SCE, respectively. It has $K_{comp}=3.3{\times}10^{12}$ representing that BPLMP/bis(acetate) ligand combination stabilizes a mixed-valence $Fe^{II}Fe^{III}$ complex in the air. Complex 1 exhibits a broad EPR signal centered near g=1.55 which is a characteristic feature of the antiferromagnetically coupled high-spin $Fe^{II}Fe^{III}$ system $(S_{total}=1/2)$. This is consistent with the magnetic susceptibility study showing the weak antiferromagnetic coupling $(J= - 4.6\;cm^{-1},\; H= - 2JS_1{\cdot}S2)$ between $Fe^{II}\; and \;Fe^{III}$center.

• Journal of the Optical Society of Korea
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• v.12 no.4
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• pp.262-268
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• 2008

A compact imaging spectrometer (COMIS) for use in the STSAT3 microsatellite is currently under development. It is scheduled to be launched into a low Sun-synchronous Earth orbit (${\sim}700km$) by the end of 2010. COMIS was inspired by the success of CHRIS, which is a small hyperspectral imager developed for the ESA microsatellite PROBA. COMIS is designed to achieve nearly equivalent imaging capabilities of CHRIS in a smaller (65 mm diameter and 4.3 kg mass) and mechanically superior (in terms of alignment and robustness) package. Its main operational goal will be the imaging of Earth's surface and atmosphere with ground sampling distances of ${\sim}30m$ at the $18{\sim}62$ spectral bands ($4.0{\sim}1.05{\mu}m$). This imaging will be used for environmental monitoring, such as the in-land water quality monitoring of Paldang Lake, which is located next to Seoul, South Korea. The optics of COMIS consists of two parts: imaging telescope and dispersing relay optics. The imaging telescope, which operates at an f-ratio of 4.6, forms an image (of Earth's surface or atmosphere) onto an intermediate image plane. The dispersion relay optics disperses the image and relay it onto a CCD plane. All COMIS lenses and mirrors are spherical and are made from used silica exclusively. In addition, the optics is designed such that the optical axis of the dispersed image is parallel to the optical axis of the telescope. Previous efforts focused on manufacturing ease, alignment, assembly, testing, and improved robustness in space environments.

• Journal of the Korean Society of Surveying, Geodesy, Photogrammetry and Cartography
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• v.36 no.6
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• pp.555-563
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• 2018

Thermal infrared images have the characteristic of being able to detect objects that can not be seen with the naked eye and have the advantage of easily obtaining information of inaccessible areas. However, TIR (Thermal InfraRed) images have a relatively low spatial resolution. In this study, the applicability of the pansharpening algorithm used for satellite imagery on images acquired by the UAV (Unmanned Aerial Vehicle) was tested. RGB image have higher spatial resolution than TIR images. In this study, pansharpening algorithm was applied to TIR image to create the images which have similar spatial resolution as RGB images and have temperature information in it. Experimental results show that the pansharpening algorithm using the PC1 band and the average of RGB band shows better results for the quantitative evaluation than the other bands, and it has been confirmed that pansharpening results by ATWT (${\grave{A}}$ Trous Wavelet Transform) exhibit superior spectral resolution and spatial resolution than those by HPF (High-Pass Filter) and SFIM (Smoothing Filter-based Intensity Modulation) pansharpening algorithm.

• The Journal of the Korea institute of electronic communication sciences
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• v.16 no.5
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• pp.991-1000
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• 2021

Among non-invasive blood glucose detection technologies, the optical technique is a method that uses light reflection, absorption, and scattering characteristics when passing through a biological medium. It reduces pain or discomfort in measurement and has no risk of infection. So it is becoming a major flow of blood glucose detection research. Among them, near-infrared spectroscopy has a disadvantage in that the complexity increases when analyzing signals detected due to interferences between proteins and acids that share a similar absorption function with blood glucose molecules. In this study, a non-invasive sensor system with multiple near-infrared bands was designed and manufactured to alleviate the deterioration of blood glucose detection function that may occur due to skin absorption of near-infrared rays. A blood survey was conducted to verify the system, and the degree of blood glucose response in the blood was collected as spectral data, and the results of this study were quantitatively verified in terms of correlation between the data and blood glucose.

• International Journal of Computer Science & Network Security
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• v.22 no.4
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• pp.193-202
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• 2022

The classification of hyperspectral imagery (HSI) is essential in the surface of earth observation. Due to the continuous large number of bands, HSI data provide rich information about the object of study; however, it suffers from the curse of dimensionality. Dimensionality reduction is an essential aspect of Machine learning classification. The algorithms based on feature extraction can overcome the data dimensionality issue, thereby allowing the classifiers to utilize comprehensive models to reduce computational costs. This paper assesses and compares two HSI classification techniques. The first is based on the Joint Spatial-Spectral Stacked Autoencoder (JSSSA) method, the second is based on a shallow Artificial Neural Network (SNN), and the third is used the SVM model. The performance of the JSSSA technique is better than the SNN classification technique based on the overall accuracy and Kappa coefficient values. We observed that the JSSSA based method surpasses the SNN technique with an overall accuracy of 96.13% and Kappa coefficient value of 0.95. SNN also achieved a good accuracy of 92.40% and a Kappa coefficient value of 0.90, and SVM achieved an accuracy of 82.87%. The current study suggests that both JSSSA and SNN based techniques prove to be efficient methods for hyperspectral classification of snow features. This work classified the labeled/ground-truth datasets of snow in multiple classes. The labeled/ground-truth data can be valuable for applying deep neural networks such as CNN, hybrid CNN, RNN for glaciology, and snow-related hazard applications.

• Korean Journal of Remote Sensing
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• v.40 no.1
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• pp.93-101
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• 2024

Accurate field crop classification is essential for various agricultural applications, yet existing methods face challenges due to diverse crop types and complex field conditions. This study aimed to address these issues by combining support vector machine (SVM) models with multi-seasonal unmanned aerial vehicle (UAV) images, texture information extracted from Gray Level Co-occurrence Matrix (GLCM), and RGB spectral data. Twelve high-resolution UAV image captures spanned March-October 2021, while field surveys on three dates provided ground truth data. We focused on data from August (-A), September (-S), and October (-O) images and trained four support vector classifier (SVC) models (SVC-A, SVC-S, SVC-O, SVC-AS) using visual bands and eight GLCM features. Farm maps provided by the Ministry of Agriculture, Food and Rural Affairs proved efficient for open-field crop identification and served as a reference for accuracy comparison. Our analysis showcased the significant impact of hyperparameter tuning (C and gamma) on SVM model performance, requiring careful optimization for each scenario. Importantly, we identified models exhibiting distinct high-accuracy zones, with SVC-O trained on October data achieving the highest overall and individual crop classification accuracy. This success likely stems from its ability to capture distinct texture information from mature crops.Incorporating GLCM features proved highly effective for all models,significantly boosting classification accuracy.Among these features, homogeneity, entropy, and correlation consistently demonstrated the most impactful contribution. However, balancing accuracy with computational efficiency and feature selection remains crucial for practical application. Performance analysis revealed that SVC-O achieved exceptional results in overall and individual crop classification, while soybeans and rice were consistently classified well by all models. Challenges were encountered with cabbage due to its early growth stage and low field cover density. The study demonstrates the potential of utilizing farm maps and GLCM features in conjunction with SVM models for accurate field crop classification. Careful parameter tuning and model selection based on specific scenarios are key for optimizing performance in real-world applications.

• The Journal of the Acoustical Society of Korea
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• v.25 no.2
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• pp.78-87
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• 2006

In this paper. we propose an effective mask estimation scheme for missing-feature reconstruction in order to achieve robust speech recognition under unknown noise environments. In the previous work. colored noise is used for training the mask classifer, which is generated from the entire frequency Partitioned signals. However it gives a limited performance under the restricted number of training database. To reflect the spectral events of more various background noise and improve the performance simultaneously. a new Bayesian classifier for mask estimation is proposed, which works independent of other frequency bands. In the proposed method, we employ the colored noise which is obtained by combining colored noises generated from each frequency band in order to reflect more various noise environments and mitigate the 'sparse' database problem. Combined with the cluster-based missing-feature reconstruction. the performance of the proposed method is evaluated on a task of noisy speech recognition. The results show that the proposed method has improved performance compared to the Previous method under white noise. car noise and background music conditions.

• Korean Journal of Remote Sensing
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• v.28 no.4
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• pp.393-407
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• 2012

This study focuses on the correction of topographic effects caused by a combination of solar elevation and azimuth, and topographic relief in single optical remote sensing imagery, and by a combination of changes in position of the sun and topographic relief in comparative analysis of multi-temporal imageries. For the Jeju Island, Republic of Korea, where Mt. Halla and various cinder cones are located, a Landsat 7 ETM+ imagery and ASTER GDEM data were used to normalize the topographic effects on the imagery, using two topographic normalization methods: cosine correction assuming a Lambertian condition and assuming a non-Lambertian c-correction, with kernel sizes of $3{\times}3$, $5{\times}5$, $7{\times}7$, and $9{\times}9$ pixels. The effects of each correction method and kernel size were then evaluated. The c-correction with a kernel size of $7{\times}7$ produced the best result in the case of a land area with various land-cover types. For a land-cover type of forest extracted from an unsupervised classification result using the ISODATA method, the c-correction with a kernel size of $9{\times}9$ produced the best result, and this topographic normalization for a single land cover type yielded better compensation for topographic effects than in the case of an area with various land-cover types. In applying the relative radiometric normalization to topographically normalized three multi-temporal imageries, more invariant spectral reflectance was obtained for infrared bands and the spectral reflectance patterns were preserved in visible bands, compared with un-normalized imageries. The results show that c-correction considering the remaining reflectance energy from adjacent topography or imperfect atmospheric correction yielded superior normalization results than cosine correction. The normalization results were also improved by increasing the kernel size to compensate for vertical and horizontal errors, and for displacement between satellite imagery and ASTER GDEM.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.26 no.5D
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• pp.885-894
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• 2006

The purpose of this study is focused on the development of the effective classification technique using ultra multiband of hyperspectral image. This study suggests the classification technique using canonical correlation analysis, one of multivariate statistical analysis in hyperspectral image classification. High accuracy of classification result is expected for this classification technique as the number of bands increase. This technique is compared with Maximum Likelihood Classification(MLC). The hyperspectral image is the EO1-hyperion image acquired on September 2, 2001, and the number of bands for the experiment were chosen at 30, considering the band scope except the thermal band of Landsat TM. We chose the comparing base map as Ground Truth Data. We evaluate the accuracy by comparing this base map with the classification result image and performing overlay analysis visually. The result showed us that in MLC's case, it can't classify except water, and in case of water, it only classifies big lakes. But Canonical Correlation Classification (CCC) classifies the golf lawn exactly, and it classifies the highway line in the urban area well. In case of water, the ponds that are in golf ground area, the ponds in university, and pools are also classified well. As a result, although the training areas are selected without any trial and error, it was possible to get the exact classification result. Also, the ability to distinguish golf lawn from other vegetations in classification classes, and the ability to classify water was better than MLC technique. Conclusively, this CCC technique for hyperspectral image will be very useful for estimating harvest and detecting surface water. In advance, it will do an important role in the construction of GIS database using the spectral high resolution image, hyperspectral data.

• Korean Journal of Remote Sensing
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• v.30 no.4
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• pp.481-491
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• 2014

Blue-ice area is a glacial ice field in ice sheet, ice shelf and glaciers where snow ablation and sublimation is larger than snowfall. As the blue-ice area has large influences on the meteorite concentration mechanism and ice mass balance, it is required to quantify the concentration of blue-ice. We analyzed spectral reflectance characteristics of blue-ice, snow and cloud by using MODIS images obtained over blue-ice areas in McMurdo Dry Valleys, East Antarctica, from 2007 to 2012. We then developed Normalized Difference Blue-ice Index (NDBI) algorithm which quantifies the concentration of blue-ice. Snow and cloud have a high reflectance in visible and near-infrared (NIR) bands. Reflectance of blue-ice is high in blue band, while that lowers in the NIR band. NDBI is calculated by dividing the difference of reflectance in the blue and NIR bands by the sum of reflectances in the two bands so that NDBI = (Blue-NIR)/(Blue + NIR). NDBI calculated from the MODIS images showed that the blue-ice areas have values ranging from 0.2 to 0.5, depending on the exposure and concentration of blue-ice. It is obviously different from that of snow and cloud that has values less than 0.2 or rocks with negative values. The change of NDBI values in the blue-ice area has higher correlation with snow depth ($R^2=0.699$) than wind speed ($R^2=0.012$) or air temperature ($R^2=0.278$), all measured at a meteorological station installed in McMurdo Dry Valleys. As the snow depth increased, the NDBI value decreased, which suggests that snow depth can be estimated from NDBI values over blue-ice areas. The NDBI algorithm developed in this study will be useful for various polar research fields such as meteorite exploration, analysis of ice mass balance as well as the snow depth estimation.