• Title/Summary/Keyword: spectral bands

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Thermal denaturation analysis of protein

  • Miyazawa, Mitsuhiro
    • Proceedings of the Korean Society of Near Infrared Spectroscopy Conference
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    • 2001.06a
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    • pp.1628-1628
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    • 2001
  • Near infrared (NIR) spectroscopy is a powerful technique for non-destructive analysis that can be obtained in a wide range of environments. Recently, NIR measurements have been utilized as probe for quantitative analysis in agricultural, industrial, and medical sciences. In addition, it is also possible to make practical application on NIR for molecular structural analysis. In this work, Fourier transform near infrared (FT-NIR) measurements were carried out to utilize extensively in the relative amounts of different secondary structures were employed, such as Iysozyme, concanavalin A, silk fibroin and so on. Several broad NIR bands due to the protein absorption were observed between 4000 and $5000\;^{-1}$. In order to obtain more structural information from these featureless bands, second derivative and Fourier-self-deconvolution procedures were performed. Significant band separation was observed near the feature at $4610\;^{-1}$ ,. Particularly the peak intensity at $4525\;^{-1}$ shows a characteristic change with thermal denaturation of fibroin. The structural information can be also obtained by mid-IR and CD spectral. Correlation of NIR spectra with protein structure is discussed.

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Analysis of Interference Impacts by UWB System to WiBro Systems

  • Yoon Young-Keun;Jin Rong-Reon;Kim Kyung-Seok;Choi Ik-Guen
    • Journal of electromagnetic engineering and science
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    • v.5 no.4
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    • pp.197-203
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    • 2005
  • This paper evaluates the impacts for interference from UWB system, and determines the tolerable UWB power spectral density(PSD) to the new deploying system, which is called a portable internet service in Korea. It also proposes the interference analysis scheme that can evaluate the characteristics of the performance degradation for portable internet service according to the emission power of UWB systems at the specified frequency bands. The proposed scheme includes a multi-rate and data service environments to deal with interference to portable internet service. It is obtained from simulation results that the transmission PSD of UWB systems should be rigidly restricted by less approximately 10 ${\~}$ 20 dB than FCC provisional limit for coexistence between UWB and portable internet service already allocated at 2.3 GHz frequency bands in Korea.

Estimation of Total Precipitable Water in East Asia Using the MODIS Satellite Data

  • Park, Seon-Ki
    • Journal of Korean Society for Atmospheric Environment
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    • v.19 no.E4
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    • pp.149-155
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    • 2003
  • In this study. the amounts of the total precipitable water (TPW) in both global and regional scale are estimated from the MODIS instrument, which is on-board the EOS satellites, Terra and Aqua. The estimation is made from the five near-infrared spectral bands, using a technique employing ratios of water- vapor absorbing channels centered at 0.905, 0.936, 0.940 ${\mu}{\textrm}{m}$ with atmospheric window channels at 0.865 and 1.240 ${\mu}{\textrm}{m}$. Through analyses of monthly and eight-days mean TPW, one can monitor characteristics of seasonal variations as well as amount and distribution (i.e., water resources) of TPW at both global and local regions. Long-term monitoring of TPW is essential to understand the regional variations of water resources in East Asia.

Photoinduced Charge-Transfer Association of Tetracyanoquinodimethane with Aminobiphenyls

  • Kim, Yong-Hee;Jung, Sang-Don;Chung, Myung-Ae;Song, Ki-Dong;Cho, Dae-Won
    • Bulletin of the Korean Chemical Society
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    • v.29 no.5
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    • pp.948-952
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    • 2008
  • The molecular association of acceptors with electron donors is studied in the highly-polar solvent $CH_3CN$. Tetracyanoquinodimethane (TCNQ) forms a stable charge-transfer complex with donor molecules such as 4- aminobiphenyl (4-AB), benzidine (BD) and 2-aminobiphenyl (2-AB) with high association constants. The complexes of TCNQ with 4-AB or BD show new absorption bands at around 800 and 500 nm, which can be identified as reduced $TCNQ^{{\bullet}-}$ and $TCNQ^{2-}$ species, respectively. These bands grow quickly upon photoirradiation, implying that the charge-transfer complexes are easily formed in an excited state. Conversely, a small spectral manifestation of the charge transfer was observed in the case of 2-AB complex. It is demonstrated that the structural orientation between the geminate ion pairs could play an important role in building a stable complex.

Radio Variability and Random Walk Noise Properties of Four blazars

  • Park, Jong-Ho;Trippe, Sascha
    • The Bulletin of The Korean Astronomical Society
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    • v.39 no.1
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    • pp.45.1-45.1
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    • 2014
  • We present the results of a time series analysis of the long-term radio lightcurves of four blazars: 3C 279, 3C 345, 3C 446, and BL Lacertae. We exploit the data base of the University of Michigan Radio Astronomy Observatory (UMRAO) monitoring program which provides densely sampled lightcurves spanning 32 years in time in three frequency bands located at 4.8, 8, and 14.5,GHz. Our sources show mostly flat or inverted (spectral indices -0.5 < alpha < 0) spectra, in agreement with optically thick emission. All lightcurves show strong variability on all time scales. Analyzing the time lags between the lightcurves from different frequency bands, we find that we can distinguish high-peaking flares and low-peaking flares in accord with the classification of Valtaoja et al. (1992). The periodograms (temporal power spectra) of the observed lightcurves are consistent with random-walk powerlaw noise without any indication of (quasi-)periodic variability. The fact that all four sources studied are in agreement with being random-walk noise emitters at radio wavelengths suggests that such behavior is a general property of blazars.

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Enhanced Raman Spectrum of Juglone on Ag Surface: Is It a Simile to That of Lawsone?

  • Cheong, Byeong-Seo;Cho, Han-Gook
    • Bulletin of the Korean Chemical Society
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    • v.34 no.1
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    • pp.68-74
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    • 2013
  • The surface enhanced Raman spectrum of juglone, a traditional natural dye, has been observed by a custom-built micro-Raman setup. The spectral features of juglone significantly differ from those of lawsone, a structural isomer of juglone; only small red shifts of the double bond stretching bands are observed, and strong SERS bands are observed in the lower frequency regions as well. The DFT computations reveal that juglone coordinated to an $Ag^+$ adatom with $H^+$ release best correlates with the observed vibrational characteristics in the SERS spectrum among the plausible configurations of juglone coordinated to an adatom on the Ag surface, in line with the previously studied lawsone case. The differences in the SERS spectra of juglone and lawsone are attributed to the different locations of the hydroxyl group in the two isomers.

A Study for the Adaptive wavelet-based Image Merging method

  • Kim, Kwang-Yong;Yoon, Chang-Rak;Kim, Kyung-Ok
    • Journal of Korean Society for Geospatial Information Science
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    • v.10 no.5 s.23
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    • pp.45-51
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    • 2002
  • The goal of image merging techniques are to enhance the resolution of low-resolution images using the detail information of the high-resolution images. Among the several image merging methods, wavelet-based image merging techniques have the advantages of efficient decorrelation of image bands and time-scale analysis. However, they have no regard for spatial information between the bands. In other words, multiresolution data merging methods merge the same information-the detail information of panchromatic image-with other band images, without considering specific characteristics. Therefore, a merged image contains much unnecessary information. In this paper, we discussed this 'mixing' effect and, proposed a method to classify the detail information of the panchromatic image according to the spatial and spectral characteristics, and to minimize distortion of the merged image.

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Solvent Dependence of Absorption and Fluorescence Spectra of Piroxicam. A Possible Intramolecular Proton Transfer in the Excited State

  • Yoon, Min-Joong;Choi, Hyong-Nae;Kwon, Hwang-Won;Park, Koon-Ha
    • Bulletin of the Korean Chemical Society
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    • v.9 no.3
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    • pp.171-175
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    • 1988
  • The spectral properties of piroxicam in different solvents are similar to those of its skeletal precursor, HMBDC. The maximum absorption and emission wavelengths strongly depend on the hydrogen bonding ability of the solvent, and it is shown that intramolecular hydrogen bonding between the -OH and the ortho carbonyl group of the parent benzothiazine ring plays an important role in the solvent-dependence of their spectroscopic properties. The fluorescence spectra in aprotic nonpolar solvent exhibit abnormally large Stokes-shifted (${\sim}9,000cm^{-1}$) emission bands in contrast to the spectra in water. In ethanol, dual emission bands with two different fractional components of lifetimes have been observed. These results suggest that the abnormally red-shifted emission is attributed to the proton transferred form of an intramolecularly hydrogen-bonded closed conformer.

The Development of Water Quality Monitoring System and its Application Using Satellite Image Data

  • Jang, Dong-Ho;Jo, Gi-Ho
    • Proceedings of the KSRS Conference
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    • 1998.09a
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    • pp.376-381
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    • 1998
  • In this study, we was measured the radiance reflectance by using multi-spectral image of low resolution camera(LRC) which will be loaded in the multi-purpose satellite(KOMPSAT) to use the data in analyzing water pollution. Also we investigated the possibility of extraction of water quality factors in rivers and water body by using high resolution remote sensing data such as Airborne MSS. Especially, we tried to extract the environmental factors related with eutrophication, and also tried to develop the process technique and the radiance feature of reflectance related with eutrophication. The results were summarized as follows: First, the spectrum of sun's rays which reaches the surface of the earth was consistent with visible rays bands of 0.4${\mu}{\textrm}{m}$~0.7${\mu}{\textrm}{m}$ and about 50% of total quantity of radiation were there. And at around 0.5${\mu}{\textrm}{m}$ of green spectral band in visible rays bands, the spectrum was highest. Second, as a result of the radiance reflectance Chlorophyll-a represented high spectral reflectance mainly around 0.52${\mu}{\textrm}{m}$ of green spectral band, and suspended sediments and turbidity represented high spectral reflectance at 0.8${\mu}{\textrm}{m}$ and at 0.57${\mu}{\textrm}{m}$ each. Third, as a result of the water quality analysis by using Airborne MSS, Chlorophyll-a could have a distribution chart when carried out ratio of B3 and BS to B7. And Band 7 was useful for making the distribution chart of suspended sediments. And when we carried out PCA, suspended sediments and turbidity had distributions at PC 1 , PC 4 each similarly to ground truth data. Above results can be changed according to the change of season and time. Therefore, in order to analyze more exactly the environmental factors of water quality by using LRC data, we need to investigate constantly the ground truth data and the radiance feature of reflectance of water body. Afterward in this study, we will constantly analyze the radiance feature of the surface of water in water body by measuring the on-the-spot radiance reflectance and using low resolution satellite image(SeaWiFs). Besides, we will gather the data of water quality analysis in water body and analyze the pattern of water pollution.

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Study on Plastics Detection Technique using Terra/ASTER Data

  • Syoji, Mizuhiko;Ohkawa, Kazumichi
    • Proceedings of the KSRS Conference
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    • 2003.11a
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    • pp.1460-1463
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    • 2003
  • In this study, plastic detection technique was developed, applying remote sensing technology as a method to extract plastic wastes, which is one of the big causes of concern contributing to environmental destruction. It is possible to extract areas where plastic (including polypropylene and polyethylene) wastes are prominent, using ASTER data by taking advantage of its absorptive characteristics of ASTER/SWIR bands. The algorithm is applicable to define large industrial wastes disposal sites and areas where plastic greenhouses are concentrated. However, the detection technique with ASTER/SWIR data has some research tasks to be tackled, which includes a partial secretion of reference spectral, depending on some conditions of plastic wastes and a detection error in a region mixed with vegetations and waters. Following results were obtained after making comparisons between several detection methods and plastic wastes in different conditions; (a)'spectral extraction method' was suitable for areas where plastic wastes exist separated from other objects, such as coastal areas where plastic wastes drifted ashore. (single plastic spectral was used as a reference for the 'spectral extraction method') (b)On the other hand, the 'spectral extraction method' was not suitable for sites where plastic wastes are mixed with vegetation and soil. After making comparison of the processing results of a mixed area, it was found that applying both 'separation method' using un-mixing and ‘spectral extraction method’ with NDVI masked is the most appropriate method to extract plastic wastes. Also, we have investigated the possibility of reducing the influence of vegetation and water, using ASTER/TIR, and successfully extracted some places with plastics. As a conclusion, we have summarized the relationship between detection techniques and conditions of plastic wastes and propose the practical application of remote sensing technology to the extraction of plastic wastes.

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