• Title/Summary/Keyword: specific surface

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Effect of pore structure on electrochemical performance of EDLC (EDLC의 전기화학적 성능에 대한 메조기공 구조의 효과)

  • Lee, Myung-Suk;Shin, Yun-Sung;Lee, Jong-Dae
    • Journal of the Korean Applied Science and Technology
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    • v.27 no.3
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    • pp.310-317
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    • 2010
  • The electrochemical properties of electric double layer capacitor(EDLC) was studied by controlling pore size distribution and specific surface area of the activated carbon fiber(ACF). The mesoporous ACF, which was prepared by the iron exchange method, showed the tendency of increasing average pore size and decreasing total surface area. The mesoporous ACF (surface area = 2225 $m^2$/g, pore size=1.93 nm) showed increased mesopore(pore size=1~3nm) volume from 0.055 cc/g to 0.408 cc/g compared to its raw ACF. The charging capacity of the EDLC which uses the prepared mesoporous ACF also increased from 0.39 F/$cm^2$ to 0.55 F/$cm^2$. From these results, it can be known that the electrochemical properties of EDLC are mainly dependent on the specific surface area, but above the surface area 2200 $m^2$/g, it is the mesopore volume that affects the performance of the capacitor considerably. Because the increased mesopore volume results in a decreased ion mobility resistance, the charge capacitance is enhanced.

Monoclonal Antibody Production against Piglet Diarrhea Agent (Enterotoxigenic E. coli) by Cell Fusion-Hybridoma Cell Technique (세포융합(細胞融合) 및 Hybridoma 세포작성(細胞作成)에 의한 항자돈백리(抗仔豚白痢) Monoclone항체(抗體)의 생산(生産))

  • Kim, Uh-ho;An, Soo-hwan;Yoon, Young-dhuk
    • Korean Journal of Veterinary Research
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    • v.27 no.2
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    • pp.259-267
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    • 1987
  • Enterotoxigenic E. coli (ETEC) cause an acute diarrhea (white scour) in both animals and humans. The disease process initially involves the adherence and colonization of the mucosal surface of the small intestine, followed by the elaboration of a heat-labile enterotoxin (LT) and/or heat-stable enterotoxin (ST). Intestinal adherence or colonization by ETEC is generally mediated by a specific surface-associated pilus (fimbrial) antigen that endows the bacteria with the capacity to adhere to epitherial cell surface. Fourteen monoclonal antibodies (MAbs) directed against pili antigens of ETEC were obtained by cell fusion/hybridoma technique. They were characterized by indirect immunofluorescence assay (IFA), and divided into four groups: specific to K99 antigen (group 1), cross-reactive with K99 and F41 antigens (group 2), specific to K88 antigen (group 3) and specific to 987P and K88 antigens (group 4), respectively. These MAbs demonstrated the distinct pili (K) antigens on the surface of ETEC by IFA, and could be utilized as diagnostic reagent for the identification of ETEC. When eighty-seven field isolates of E. coli from piglet with diarrhea were tested by group 3 MAb, fourty-two strains (48.3%) has K88 pilus antigen suggesting that this is one of the major pilus antigen of ETEC present in fifeld.

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Experimental Investigation to Establish Correlation between Specific Film Thickness and Sound Signals in a Spur Gear System (스퍼 기어 시스템의 음향 신호와 비 유막 두께(Specific Film Thickness)의 상관관계에 관한 실험적 연구)

  • Kim, Jongsik;Amarnath, M.;Lee, Sangkwon
    • Transactions of the Korean Society for Noise and Vibration Engineering
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    • v.24 no.8
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    • pp.643-650
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    • 2014
  • Gear transmission system is widely applied in engineering. As the problem of contact fatigue, wear, lubrication failure etc, the condition of gear teeth contacts will be worse. The vibration and sound signals in the gear system will be affected by the some failures like scuffing, abrasive wear and spalling due to the deterioration of gear teeth surface. By studying the estimation of specific film thickness, measurement of reduction in tooth thickness, visual examination of wear mechanisms on the gear teeth and their effects on the statistical parameters of vibration and sound signals, the research obtained the satisfactory results on accessing the surface fatigue wear in a spur gear system. The paper utilizes the relationship between statistical parameters obtained from sound signals and Stribeck curve to confirm the hypothesis of dependency of surface fatigue wear, specific film thickness.

Variation of Filamentous Periphyton Chlorophyll-a in accordance with Water Velocity and Specific Surface Area of Media in Small Urban Stream (도시 소하천에서 유속, 비표면적에 따른 사상형 부착조류의 Chlorophyll-a 변화)

  • Ahn, Chang Hyuk;Joo, Jin Chul;Lee, Saeromi;Oh, Ju Hyun;Ahn, Hosang;Song, Ho Myeon
    • Journal of Korean Society on Water Environment
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    • v.29 no.4
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    • pp.551-558
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    • 2013
  • The feasibility of water supply as in-stream flow for Mangwall stream was analyzed in terms of water quality and cultivation periphyton using two different types of water resources (e.g., surface water and bank filtration from Han River basin) and three different types of media (e.g., tile, concrete and pebble). The concentrations of organic and inorganic contaminants from the bank filtration were lower than those from surface water by 17.5 - 55.0%. Using water samples collected from Mangwall stream, surface water, and bank filtration, chlorophyll-a, phaeopigment, and growth rate of periphyton were investigated. During 30 day incubation for each water sample, it was observed that filamentous cyanobacteria, Oscillatoriaceae, accounted for 98%, and water velocity of 5 cm/s was optimum for the in situ filamentous cyanobacteria growth. Also, it was deducted for water velocity and chl-a to have an inverse correlation. Meanwhile, the greater the specific surface area of media, the higher the concentration of chl-a. From these results, both water velocity and specific surface area of media should be considered as an combined parameter to deter the growth of filamentous cyanobacteria.

Effect of Intermediate Layer Coated Diamond Particles on Performance of Diamond Tool (다이아몬드 입자에 형성된 중간층이 다이아몬드 공구 성능에 미치는 영향)

  • Son, Kyung-Sik;Lee, Jung-Hoon;Choi, Yong-Je;Jung, Uoo-Chang;Chung, Won-Sub
    • Journal of the Korean institute of surface engineering
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    • v.46 no.5
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    • pp.216-222
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    • 2013
  • In order to improve the performance of electrodeposited diamond-nickel composite, surface modification of diamond particles was carried out using powder immersion reaction assisted coating (PIRAC). Titanium and chromium were selected as coating elements, which are known as carbide former. With respect to the powder elements, various phases were formed on diamond; metallic Ti and TiC for Ti powder, $Cr_3C_2$ for Cr powder, and TiC and $Cr_3C_2$ for Ti-Cr mixed powder. Surface modified diamond particle showed higher specific surface area, especially Ti coating induced considerable increase of specific surface area. The increase of specific surface area suggests increase of surface roughness, and that was confirmed by surface observation using FE-SEM. In addition, wear properties of diamond-nickel composite including surface modified diamonds were improved, and Ti coated diamond showed the highest performance. The wear property of diamond-nickel composite is dependent on adhesion strength between diamond particle and nickel layer. Therefore, surface modification of diamond particle by PIRAC increasing surface roughness is effective to improve the properties of diamond-nickel composite.

Physical Properties of Carbon Prepared from a Coconut Shell by Steam Activation and Chemical Activation and the Influence of Prepared and Activated Carbon on the Delivery of Mainstream Smoke

  • Ko, Dong-Kyun;Shin, Chang-Ho;Jang, Hang-Hyun;Lee, Young-Taeg;Rhee, Moon-Soo
    • Journal of the Korean Society of Tobacco Science
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    • v.30 no.1
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    • pp.8-13
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    • 2008
  • Several activated carbon in different specific surface area was prepared by steam and chemical activation of coconut shell. Products were characterized by BET ($N_2$) at 77K, and probed to be highly specific surface area of $1580m^2/g$ and pore volume that had increased with activating conditions. And also we have analyzed the adsorption efficiency of vapor phase components in cigarette mainstream smoke in order to evaluate the relationship between thesmoke components and the physicochemical properties of activated carbons. As a result of this study, the delivery of mainstream smoke was directly affected by the specific surface area and the pore size of activated carbon. The activated carbon prepared by steam activation exhibited better adsorption efficiency on the vapor phase components in mainstream smoke compared with activated carbon prepared by $ZnCl_2$, due to the higher micro-pore area of 66%. But the adsorption efficiency of semi-volatile matters such as phenolic components in a main stream smoke by the activated mesoporous carbon prepared by $ZnCl_2$ is more effective. From the these results, we can conclude that specific surface area by the micropore area increased the adsorption efficiency of activated carbon on vapour phase components, but semi-volatiles or particulate matter was affected by the ratio of mesopore area in total specific surface area.

Development of Certified Reference Materials for Specific Surface Area (비표면적 인증표준물질 개발)

  • Choi, Byung Il;Kim, Jong Chul;Kim, Taeyoung;Nham, Hyunsoo;Kwon, Su Yong
    • Analytical Science and Technology
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    • v.18 no.1
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    • pp.74-84
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    • 2005
  • Understandings of adsorption characteristic of interface are very important in several advanced materials processes, related to NT and BT technology. Volumetric gas adsorption method, suitable for absolute measurements, is regarded as the standardized measurement technique for specific surface area. In order to verify the reliability of commercial equipments, certified reference materials (called CRM) of specific surface area are developed and evaluated its uncertainty factors by standard equipment which has traceability to SI units. Specific surface areas of developed materials are $10.72{\pm}0.46m^2g^{-1}$ for silicon nitride powders and $149.50{\pm}3.44m^2g^{-1}$ for alumina. These disseminations of CRMs would result in improved reliability chains in industrial processes, and lead eventually to contribution to productivity improvement, quality management, safety evaluation, and possibly to new material development.

Adsorption Characteristics of Activated Carbon Blocks for Water Purifier Varying Binder Particle Sizes (바인더 입자크기에 따른 정수용 활성탄 블록의 흡착 특성)

  • Kang, Kwang Cheol;Ju, Jin-Hee
    • Applied Chemistry for Engineering
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    • v.24 no.6
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    • pp.668-671
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    • 2013
  • This paper describes activated carbon block filters prepared by extrusion for water purifier. The specific surface area of the activated carbon blocks affecting the properties of a polymer binder were investigated. Polyethylene (PE) particles were used as a binder polymer and the effect of particle sizes on changes in the specific surface area of activated carbon blocks in addition to the adsorption properties of chloride anion in the aqueous solution were investigated. The sizes and shapes of PE particles were measured using SEM. The specific surface area of activated carbon was $1186m^2/g$. The specific surface area of PE binder was $444m^2/g$ and $940m^2/g$ with the particle sizes of $200{\mu}m$ and $20{\mu}m$, respectively. In order to verify the performance of the filter, chlorine adsorption experiments were conducted.

Evaluation of Humidity Control Ceramic Board Using Gypsum Binder (석고계 바인더를 활용한 습도도절 세라믹 보드의 특성 평가)

  • Lee, Jong-Kyu;Kim, Tae-Yeon
    • Korean Journal of Materials Research
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    • v.28 no.1
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    • pp.62-67
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    • 2018
  • Active clay, bentonite and zeolite were used as porous materials for humidity controlling ceramic boards. The specific area and the pore volume of active clay were higher than bentonite and zeolite. The flexible strength of the gypsum board decreased with an increasing amount of porous material, and the flexible strength was lowest when active clay with a higher specific surface area than others porous materials was added. The specific surface area and total pore volume of ceramic boards containing porous material were highest at $102.25m^2/g$, $0.142cm^3/g$, respectively, when the active clay was added. In addition, as the amount of added porous materials increased, the specific surface area and total pore volume of the ceramic board increased, but the average pore diameter decreased. The addition of s porous materials with a high specific area and a large pore volume improved the moisture absorptive and desorptive performance of the ceramic board. Therefore, in this experiment, the moisture absorptive and desorptive properties were the best when active clay was added. Furthermore, as the amount of added porous materials increased, the moisture absorptive and desorptive properties improved. When 70 mass% of active clay was added to ${\alpha}$-type gypsum, the hygroscopicity was the highest, about $300g/m^2$, in this experiment.

A Characteristics of Thick and Hard Al-Cu Alloy by Overlaying Welding Process (오버레이 용접법에 의한 Al-Cu 합금 경화후막의 특성)

  • 박정식;양변모;박경재
    • Journal of Welding and Joining
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    • v.14 no.4
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    • pp.53-61
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    • 1996
  • It was attempted to improve the wear resistance of Al alloy under the load condition by making a formation of the thicker surface hardening alloy layers. The thicker surface hardening alloy layers were formed on 6061 Al alloys overlayed by MIG and TIG welding process with Cu powders feeding. The characteristics of hardening and wear resistance have been investigated in relation to the microstructures of alloyed layers, with a selection of optimum alloying conditions for formation of overlaying layer. The results obtained were summarized as follows With increasing feeding rate of Cu powders by MIG welding, the hardness and specific wear of the overlay weld alloys were increased. It is considered that these high hardness and specific wear of overlay weld alloys were due to the formation of Θ($Al_2Cu$) phases. With increasing feeding rate of Cu powders by TIG welding, the hardness and specific wear of the overlay weld alloys were increased in feeding rates 12 and 18g/min. However, the hardness and specific wear were decreased in the powder feeding rate 38g/min. It is considered that considered that decrease of hardness and specific wear in the powder feeding rate 38g/min due to formation of ${\gamma}$($Al_4Cu_9$) phases.

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