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Physical Properties of Carbon Prepared from a Coconut Shell by Steam Activation and Chemical Activation and the Influence of Prepared and Activated Carbon on the Delivery of Mainstream Smoke  

Ko, Dong-Kyun (KT&G Central Research Institute)
Shin, Chang-Ho (KT&G Central Research Institute)
Jang, Hang-Hyun (KT&G Central Research Institute)
Lee, Young-Taeg (KT&G Central Research Institute)
Rhee, Moon-Soo (KT&G Central Research Institute)
Publication Information
Journal of the Korean Society of Tobacco Science / v.30, no.1, 2008 , pp. 8-13 More about this Journal
Abstract
Several activated carbon in different specific surface area was prepared by steam and chemical activation of coconut shell. Products were characterized by BET ($N_2$) at 77K, and probed to be highly specific surface area of $1580m^2/g$ and pore volume that had increased with activating conditions. And also we have analyzed the adsorption efficiency of vapor phase components in cigarette mainstream smoke in order to evaluate the relationship between thesmoke components and the physicochemical properties of activated carbons. As a result of this study, the delivery of mainstream smoke was directly affected by the specific surface area and the pore size of activated carbon. The activated carbon prepared by steam activation exhibited better adsorption efficiency on the vapor phase components in mainstream smoke compared with activated carbon prepared by $ZnCl_2$, due to the higher micro-pore area of 66%. But the adsorption efficiency of semi-volatile matters such as phenolic components in a main stream smoke by the activated mesoporous carbon prepared by $ZnCl_2$ is more effective. From the these results, we can conclude that specific surface area by the micropore area increased the adsorption efficiency of activated carbon on vapour phase components, but semi-volatiles or particulate matter was affected by the ratio of mesopore area in total specific surface area.
Keywords
carbon; coconut shell; mainstream smoke;
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1 Jankowska, H., Swiatkowski, A., and Choma, J. (1991) Active Carbon. Ellis Harwood, New York, NY
2 Morie, G. P. (1977) Proceedings of the American Chem. Soc. Sym., Recent Adv. In the Chem. Comp. of Tobacco & Tobacco Smokes. New Orleans, Louisiana, p 553
3 Baker, R. R. (1987) A review of pyrolysis studies to unravel reaction steps in burning tobacco, J. Anal. Appllied Pyrol. 11: 555-573
4 Xue, L., Thomas, Charles E., and Koller, Kent B. (2002) Mainstream smoke gas phase filtration performance of adsorption materials evaluated with a puff-by-puff multiplex GC-MS method Beitr. Tabakforsch. Int. 4: 251-256
5 Sai, PMS and Krishnaiah, K. (2005) Development of the pore-size distribution in activated carbon produced from coconut shell char in a fluidized-bed reactor. Ind. Eng. Chem. Res. 44: 51-60   DOI   ScienceOn