• Title/Summary/Keyword: specific heat

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Control of Microstructure on TiO2 Nanofibers for Photocatalytic Application (광촉매 응용을 위한 TiO2 나노 섬유의 미세구조 제어)

  • Lee, Chang-Gyu;Kim, Wan-Tae;Na, Kyeong-Han;Park, Dong-Cheol;Yang, Wan-Hee;Choi, Won-Youl
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.31 no.6
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    • pp.417-421
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    • 2018
  • $TiO_2$ has excellent photocatalytic properties and several studies have reported the increase in its specific surface area. The structure of $TiO_2$ nanofibers indicates promising improved photocatalytic properties and these nanofibers can thus potentially be applied in air pollution sensors and pollutant removal filters. In this study, a $TiO_2$ nanofiber was fabricated by the electrospinning method. The fabrication processing factors such as the applied voltage, the distance between nozzle and collector, and the inflow rate of solution were controlled. The precursor was titanium (IV) isopropoxide and as-spun $TiO_2$ nanofibers were heated at $450^{\circ}C$ for 2 h to obtain an anatase crystalline structure. The microstructure was analyzed using field emission scanning electron microscope (FE-SEM) and X-ray diffraction analysis (XRD). The anatase phase was observed in the $TiO_2$ nanofibers after heat treatment. The diameter of $TiO_2$ nanofibers increased with the flow rate, but decreased with decreasing applied voltage and nozzle to collector distance. The diameter of $TiO_2$ nanofibers was controlled in the range of 364 nm to 660 nm. These nanofibers are expected to be very useful in photocatalytic applications.

Prediction of Exposure to 1763MHz Radiofrequency Radiation Using Support Vector Machine Algorithm in Jurkat Cell Model System

  • Huang Tai-Qin;Lee Min-Su;Bae Young-Joo;Park Hyun-Seok;Park Woong-Yang;Seo Jeong-Sun
    • Genomics & Informatics
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    • v.4 no.2
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    • pp.71-76
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    • 2006
  • We have investigated biological responses to radiofrequency (RF) radiation in in vitro and in vivo models. By measuring the levels of heat shock proteins as well as the activation of mitogen activated protein kinases (MAPKs), we could not detect any differences upon RF exposure. In this study, we used more sensitive method to find the molecular responses to RF radiation. Jurkat, human T-Iymphocyte cells were exposed to 1763 MHz RF radiation at an average specific absorption rate (SAR) of 10 W/kg for one hour and harvested immediately (R0) or after five hours (R5). From the profiles of 30,000 genes, we selected 68 differentially expressed genes among sham (S), R0 and R5 groups using a random-variance F-test. Especially 45 annotated genes were related to metabolism, apoptosis or transcription regulation. Based on support vector machine (SVM) algorithm, we designed prediction model using 68 genes to discriminate three groups. Our prediction model could predict the target class of 19 among 20 examples exactly (95% accuracy). From these data, we could select the 68 biomarkers to predict the RF radiation exposure with high accuracy, which might need to be validated in in vivo models.

Economic Benefit Analysis of Urban Meteorological Information Service Using Contingent Valuation Method (조건부가치측정법을 이용한 도시기상정보서비스의 경제적 편익 분석)

  • Cho, Youngsang;Koo, Yoonmo;Lee, Jongsu;Lee, Joong-Woo
    • Environmental and Resource Economics Review
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    • v.20 no.4
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    • pp.643-662
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    • 2011
  • As the concentration of people in urban area become severe and abnormal meteorological disasters such as regional torrential rains, heavy snows, sweltering heat, and so on have been increasing, the interest on the urban meteorological information service, which considers the specific characteristics of metropolitan areas in weather forecasting, are also increasing. The urban meteorological information service is one of up-to-date technologies which observes urban weather in a more microscale perspective compared to the present weather forecasting system and provides useful meteorological information which is specialized for metropolises in real time. Therefore, urban meteorological information service is expected to contribute to the increase in quality of life for citizens and to the development of industry in urban areas. In this study, we estimate the economic benefit of the urban meteorological information service using contingent valuation method with survey data of the citizens who are expected to be the direct customers of this new information service. As a result, we conclude that the household is willing to pay 5,963 Korean won per year on average, during a period of five years, for receiving this meteorological information service, and this willingness-to-pay is varied by the socio-economic characteristics of head of the household.

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Low Temperature Thermal Conductivity of Sheath Alloys for High $T_{c}$ Superconductor Tape

  • Park, Hyung-Sang;Oh, Seung-Jin;Jinho Joo;Jaimoo Yoo
    • Transactions on Electrical and Electronic Materials
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    • v.1 no.2
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    • pp.32-37
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    • 2000
  • Effect of alloying element additions to Ag on thermal conductivity and electrical conductivity of sheath materials for Bi-Pb-Sr-Ca-Cu-O(BSCCO) tapes has been characterized. The thermal conductivity at low temperature range (10~300K) of Ag and Ag alloys were evaluated by both direct and indirect measurement techniqueas and compared with each other, It was observed that the thermal conductivity decreases with increasing the content of alloying element such as Au, Pd and Mg. Thermal conductivity of pure Ag at 3 0K was measured to be 994.0 W(m.K) on the other hand, the corresponding values of $Ag_{0.9995}Mg_{0.0005}$, $Ag_{0.974}$, $Au_{0.025}$, $Mg_{0.001}$, $Ab_{0.973}$, $Au_{0.025}$, $Mg_{0.002}$ and $Ag_{0.92}$, $Pb_{0.06}$, $Mg_{0.02}$ were 342.6, 62.1, 59.2 and 28.9 W(m.K), respectively, indicating 3 to 30 times lower than that of pure Ag. In addition, the thermal conductivity of pure Ag measured by direct and indirect measurement techniques was 303.2 and 363.8 W(m.K) The difference in this study is considered to be within an acceptable error range compared to the reference data.

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A Comparative Study of Pulse-echo Method and TOFD Method for the Defect in the Welding Joint of the STS304 Stainless Steel (STS304 스테인리스강 용접부 결함평가에 대한 Pulse-echo법과 TOFD법의 비교연구)

  • Kil, Doo-Song;Choi, Won-Doo
    • Journal of Power System Engineering
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    • v.6 no.4
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    • pp.68-72
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    • 2002
  • For the evaluation of a flaw in a welded stainless steel by the Time of Flight Diffraction(TOFD) Method, we have made the reference specimen for experimentation. As a result, we could analyze a specific character and the inner state of the structure in a welded stainless steel and we came to the conclusion as followed. (1) For analyze the structure state of a section in a welded stainless steel through the optical microscope, we could have analyzed the generated shape and the location of a flaw and the inner parts of the structure state through the microscope of eighty magnification and two hundred magnification about the soundness, the heat affected zone(HAZ) and the welded part. (2) Through the comparison with the shape and the size of a flaw in the welded part about the conventional ultrasonic test and the TOFD Method, we could make an observation the special character of the TOFD Method and principles. (3) We analyzed and collected the merit of the TOFD Method on the basis of the experimental result by the shape and the size of a flaw in the inner welded parts. So, we made up a base that we could use as a basic data for a similar flaw like that. Through the study as mentioned above, we could make an observation the flaw detective method and principles used in the TOFD Method.

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Analysis of stress and distortion that develop during accelerated cooling of plate (가속냉각시 강판에 발생하는 응력 및 변형에 대한 연구)

  • 김호영;김창영;주웅용;장래웅
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.12 no.5
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    • pp.952-958
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    • 1988
  • To analyze the nonflatness and residual stress in accelerated cooled plate, a numerical analysis model has been developed. Two factors, i.e. temperature and phase transformation, are considered in calculating the stress distribution that develops during cooling. The plastic strain and plate-buckling, which are often shown in accelerated cooled plate, were determined from this stress. Mean temperature in through thickness direction and temperature difference in width direction are considered in the model to simplify the calculation. The temperature and stress distribution changes caused by phase transformation are involved in terms of the effective specific heat and the effective thermal expansion coefficient. With the model, accelerated cooling of 10mm(t) $^{*}$3000mm(w) plate was simulated. The condition of accelerated cooling was .deg. C/sec from just after hot rolling to 500.deg. C. The initial temperature-difference ratio, .DELTA.Tr, in width direction is an important factor in evaluating the stress distribution. When .DELTA.Tr is 0.08, buckling occurs during cooling and 7kgf/m $m^{2}$ of residual stress develops at the edge of plate. To secure the flatness, .DELTA.Tr should be less than 0.07. Small scaled cooling test was conducted to verify the exactness of the model and the results proved the usefulness of this numerical analysis model.l.

Tailoring of the Chemical Resistance of Chrome Yellow Particles by Silica Coating (안료의 내약품성 향상을 위한 황연입자의 실리카 피복에 관한 연구)

  • Lee, Seewoo;Kim, Seongsoo;Kim, Dong-Uk;Wang, Lin;Choi, Heekyu
    • Applied Chemistry for Engineering
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    • v.19 no.3
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    • pp.310-315
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    • 2008
  • Herein, we synthesized silica-coated chrome yellow particles having improved chemical resistance. The intermediate with a good dispersion stability was prepared and the chemical resistance of the final product was investigated. The effects of pH and temperature, as the main parameters influencing the formation of particles, the reduced particle size by homogenizer on the silica coating were investigated. The change in the particle morphology by temperature and pH was also studied. As the results, small and monodisperse particles were achieved at low pH and high temperature. Good silica coating was obtained when used reduced size of the particles by homogenizer. Furthermore, the sufficient silica coating by microencapsulation was obtained at 9~10 pH and the temperature above $90^{\circ}C$.

Review of Hazard Test of Combustion Gas and Exhaust Temperature of Acrylic Fire Protection Paint (아크릴계 내화도료 연소가스의 유해성 평가와 배기온도에 대한 고찰)

  • Jeon, Soo-Min;Kim, Jae-Jun
    • Fire Science and Engineering
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    • v.31 no.4
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    • pp.1-6
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    • 2017
  • A fire resistance certification needs to be obtained before fire protection paint can be used in Korea. In the case of paint, the tests for certification are fire, gas hazard and bond strength. According to the hazard test standard of combustion gas, 16 mice are sacrificed every test. Therefore, there are ethical problems for the experimenter and legal problems for the laboratory. Accordingly, many alternatives are being assessed, such as combustion gas analysis, but they have not replaced animal testing yet. With gas hazard testing, the exhaust gas temperature can be measured. The property of the initial reaction of a specific fire paint can be characterized by this temperature. The purpose of this study was to consider the improvement point for a gas hazard test through comparative analysis of the exhaust temperature and the time of death of the mice.

Manufacture of Dismantling Apparatus for Waste CPU Chip and Performance Evaluation (폐 CPU 칩의 해체장치 제작 및 성능 평가)

  • Joe, Aram;Park, Seungsoo;Kim, Boram;Park, Jaikoo
    • Resources Recycling
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    • v.25 no.6
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    • pp.3-12
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    • 2016
  • In this study, Au distribution in F-PGA chip and W-BGA chip were examined to recover Au effectively from CPU chips. The result showed that 80.8% and 89.8% of Au exist in terminal of F-PGA chip and bare die of W-BGA chip, respectively. Based on the fact that Au exists in specific parts of the chips, an CPU chip dismantling apparatus was developed. The experimental variables were roller rotating speed, heat temperature of IR heater and heating time. Terminals of F-PGA chips were completely recovered under the temperature of $300^{\circ}C$ and the residence time of 90 s. Bare dies of W-BGA chips were completely recovered as well under the temperature of $300^{\circ}C$, the roller rotating rate of 90 rpm and the residence time of 90 s.

Purification and Some Properties of the polyphenol Oxidase form Ascidian, Halocynthia roretzi

  • Jeon, Byeong-Jun;Lee, Kang-Ho;Ryu, Hong-Soo;You, Byeong-Jin
    • Preventive Nutrition and Food Science
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    • v.1 no.1
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    • pp.111-116
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    • 1996
  • Polyphenol oxidase(PPO) isolated from the crude extract of ascidian, Halocynthia roretzi, showed higher affinity for catechol than tyrosine or DL-DOPA. Successful enzyme assay could be performed at $25^{\circ}C$, 10min. by mixing 0.2ml of crude enzyme extract with 2.8ml of 0.13M catechol in 0.1M sodium phosphate buffer(pH 6.4). The specific activity of PPO which had been purified with a combination of ammonium sulfate treatment, ion exchange chromatography on DEAE-cellulose, and gel filtration on Sepharose 6B was 13-fold disc gel electrophoresis. The activity of PPO was stable from pH 5.0 to 8.0 and showed the peak activity at pH 6.4 .The optimum reaction temperature for PPO oxidation on catechol was 35$^{\circ}C$ and those enzyme were heat stable up to 4$0^{\circ}C$. Molecular weigth of the enzyme was estimated about 170kDa. One molecule was found to be composed of gour subunits. Two of them had molecular weigh of 55kDa and the others 30kDa. The {TEX}$K_{m}${/TEX} values, {TEX}$V_{max}${/TEX} and catalytic efficiency({TEX}$V_{max}${/TEX}/{TEX}$K_{m}${/TEX}) for catechol were 0.12mM, 2.5mM/liter/min. and {TEX}$0.18min^{-1}${/TEX} respectively. The substrate affinity and electrophorectic pattern suggested that the enzyme of ascidian was considered to be not tyosine but catechol oxidase.

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