• Title/Summary/Keyword: specific discharge

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Effects of Cathode Composition for $LiV_3O_8$/Li Secondary Battery ($LiV_3O_8$/Li 이차전지의 복합양극의 조성에 따른 영향)

  • 박수길;김종진;이홍기;엄재석;전세호
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1998.11a
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    • pp.29-32
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    • 1998
  • A new treatment of LiV$_3$O$_{8}$ has beer proposed for improving its electrochemical behavior as a cathode material secondary lithium batteries. Early in its development, the preparation method of LiV$_3$O$_{8}$ strongly influenced its electrochemical properties, such as discharge capacity, rate capability and cycling efficiency. In the present experiment, a new synthesis route has been applied to obtain LiV$_3$O$_{8}$ . Instead of the conventional high temperature technique leading to the crystalline form, a solution technique producing the amorphous form has been used. This material, after dehydration, shows an electrochemical performance exceeding that of the crystalline one. These measurements showed that the ultrasonic treatment process of crystalline LiV$_3$O$_{8}$ causes a decrease in crystallinity and considerable increases in specific surface area and interlayer spacing. So the ultrasonic method provides a convenient means for improving the electrochemical behavior of LiV$_3$O$_{8}$ as a cathode material for secondary lithium batteries.batteries.

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Fundamental study on volume reduction of heavy metal-contaminated soil by magnetic separation

  • Konishi, Yusuke;Akiyama, Yoko;Manabe, Yuichiro;Sato, Fuminobu
    • Progress in Superconductivity and Cryogenics
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    • v.22 no.2
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    • pp.1-6
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    • 2020
  • Large-scale civil engineering works discharge a large amount of soil suspension contaminated with natural heavy metals. Most of the heavy metal ions due to industrial activities and minings are accumulated in the soils and the sediments of lakes and inner bays through the rivers. It is necessary to remove heavy metals from the soils and the sediments, because some of these heavy metals, such as arsenic and cadmium, have significant biological effects even in small amounts. This study proposes a new volume reduction method of the contaminated soils and sediments by superconducting magnetic separation. Our process can remove the specific minute minerals selectively, which adsorbs heavy metals depending on pH. As a fundamental study, the adsorption behaviors of arsenic and cadmium on minute minerals as a function of pH were investigated, and the adsorption mechanism was discussed based on the crystal structure and pH dependence of surface potential in each minute minerals.

Synthesis and Performance of Li2MnSiO4 as an Electrode Material for Hybrid Supercapacitor Applications

  • Karthikeyan, K.;Amaresh, S.;Son, J.N.;Lee, Y.S.
    • Journal of Electrochemical Science and Technology
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    • v.3 no.2
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    • pp.72-79
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    • 2012
  • $Li_2MnSiO_4$ was synthesized using the solid-state method under an Ar atmosphere at three different calcination temperatures (900, 950, and $1000^{\circ}C$). The optimization of the carbon coating was also carried out using various molar concentrations of adipic acid as the carbon source. The XRD pattern confirmed that the resulting $Li_2MnSiO_4$ particles exhibited an orthorhombic structure with a $Pmn2_1$ space group. Cyclic voltammetry was utilized to investigate the capacitive behavior of $Li_2MnSiO_4$ along with activated carbon (AC) in a hybrid supercapacitor with a two-electrode cell configuration. The $Li_2MnSiO_4$/AC cell exhibited a high discharge capacitance and energy density of $43.2Fg^{-1}$ and $54Whkg^{-1}$, respectively, at $1.0mAcm^{-2}$. The $Li_2MnSiO_4$/AC hybrid supercapacitor exhibited an excellent cycling stability over 1000 measured cycles with coulombic efficiency over > 99 %. Electrochemical impedance spectroscopy was conducted to corroborate the results that were obtained and described.

The Electrochemical Performance of Li3V2(PO4)3/Graphene Nano-powder Composites as Cathode Material for Li-ion Batteries

  • Choi, Mansoo;Kim, Hyun-Soo;Lee, Young Moo;Jin, Bong-Soo
    • Journal of Electrochemical Science and Technology
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    • v.5 no.4
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    • pp.109-114
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    • 2014
  • The $Li_3V_2(PO_4)_3$/graphene nano-particles composite was successfully synthesized by a facile sol-gel method. The addition of a graphene in $Li_3V_2(PO_4)_3(LVP)$(LVP) showed the high crystallinity and influenced the morphology of the $Li_3V_2(PO_4)_3$ particles observed in X-ray diffraction (XRD) and scanning electron microscopy (SEM). The LVP/graphene samples were well connected, resulting in fast charge transfer. The effect of the addition graphene nano-particles on electrochemical performance of the materials was investigated. Compared with the pristine LVP, the LVP/graphene composite delivered a higher discharge capacity of $122mAh\;g^{-1}$ at 0.1 C-rate, better rate capability and cyclability in the potential range of 3.0-4.3 V. The electrochemical impedance spectra (EIS) measurement showed the improved electronic conductivity for the LVP/graphene composite, which can ensure the high specific capacity and rate capability.

Probability Distribution of BOD EMC from Paddy Fields (논 유출수 BOD의 유량가중평균농도(EMC) 확률분포)

  • Jin, So-Hyun;Jung, Jae-Woon;Yoon, Kwang-Sik;Choi, Woo-Jung;Choi, Dong-Ho;Kim, Sang-Don;Kang, Jae-Hong;Choi, Yu-Jin
    • Journal of Environmental Science International
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    • v.19 no.9
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    • pp.1153-1159
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    • 2010
  • Identification of probability distribution for water quality constituents from specific land use is important to achieve successful implementation of TMDL program. In this 3-year study, distribution of discharge and BOD(Biological Oxygen Demand) concentration from paddy rice fields were monitored. Four probability distributions, normal, log-normal, Gamma and Weibull were fitted and the goodness-of-fit was assessed using probability plots and Kolmogorov-Smirnov test. $EMC_s$ of BOD in runoff from paddy field ranged 0.37 to $7.99\;mgL^{-1}$, and all four probability distributions were acceptable. But the normal distribution would be preferred for BOD from paddy fields considering nature of straight forward application.

Design of partial emission type liquid nitrogen pump

  • Lee, Jinwoo;Kwon, Yonghyun;Lee, Changhyeong;Choi, Jungdong;Kim, Seokho
    • Progress in Superconductivity and Cryogenics
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    • v.18 no.1
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    • pp.64-68
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    • 2016
  • High Temperature Superconductor power cable systems are being developed actively to solve the problem of increasing power demand. With increases in the unit length of the High Temperature Superconductor power cable, it is necessary to develop highly efficient and reliable cryogenic pumps to transport the coolant over long distances. Generally, to obtain a high degree of efficiency, the cryogenic pump requires a high pressure rise with a low flow rate, and a partial emission type pump is appropriate considering its low specific speed, which is different from the conventional centrifugal type, full emission type. This paper describes the design of a partial emission pump to circulate subcooled liquid nitrogen. It consists of an impeller, a circular case and a diffuser. The conventional pump and the partial emission pump have different features in the impeller and the discharge flow passage. The partial emission pump uses an impeller with straight radial blades. The emission of working fluid does not occur continuously from all of the impeller channels, and the diffuser allows the flow only from a part of the impeller channels. As the area of the diffuser increases gradually, it converts the dynamic pressure into static pressure while minimizing the loss of total pressure. We used the known numerical method for the optimum design process and made a CFD analysis to verify the theoretical performance.

The Basic Insulation Characteristics of Solid-Nitrogen for Cryocooling of HTS Systems (고온초전도 시스템 냉각용 고화질소의 기초 절연 특성)

  • Choi, Jae-Hyeong;Choi, Jin-Wook;Lee, Hai-Gun;Song, Jung-Bin;Kim, Hae-Jong;Seong, Ki-Chul;Kim, Sang-Hyun
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.58 no.1
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    • pp.132-136
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    • 2009
  • Recently, for improvement of the magnetic field of high temperature superconductor (HTS) apparatus, many studies investigating on operating in the range of $20{\sim}65\;K$ with liquid helium or the conducting method using cryocooler are actively reviewed. Also, the cooling method using solid nitrogen as cryogen is being suggested. Since the nitrogen has very large specific heat in solid state, it is expected that it can be operated for a long time without a continuous supply of cooling energy. However, there are still insufficient data on the characteristics of solid nitrogen such as thermodynamic properties and liquid-solid phase change. Especially, there was almost no study done on the electrical insulation properties of solid nitrogen so far. In this study, solid nitrogen to find the electrical characteristics was made by using cryocooler and cryostat, and investigated the flashover discharge and breakdown. The results of this study will be useful as a basic data for electrical insulation design of the HTS system using solid nitrogen as cryogen.

Operation Algorithm for a Parallel Hybrid Electric Vehicle with a Relatively Small Electric Motor

  • Kyoungcheol Oh;Kim, Donghyeon;Kim, Talchol;Kim, Chulsoo;Kim, Hyunsoo
    • Journal of Mechanical Science and Technology
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    • v.18 no.1
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    • pp.30-36
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    • 2004
  • In this paper, operation algorithms for a parallel HEV equipped with a relatively small motor are investigated. For the HEV, the power assist and the equivalent fuel algorithms are proposed. In the power assist algorithm, an electric motor is used to assist the engine which provides the primary power source. Tn the equivalent fuel algorithm, the electric energy stored in the battery is considered to be an equivalent fuel, and an equivalent brake specific fuel consumption for the electric energy is proposed. From the equivalent fuel algorithm, distribution of the engine power and the motor power is determined to minimize the fuel consumption for a given battery state of charge (SOC) and a required vehicle power. It is found from the simulation results that the fuel economy and the final battery SOC depend on the motor discharge energy and it is the best way to charge the battery only by the regenerative braking, not by the engine to improve the overall fuel efficiency of the HEV with the relatively small motor.

Patient Satisfaction as an Outcome Indicator (결과지표로서의 환자 만족도에 관한 연구)

  • Hwang, Jeein;Park, Hyeoun-Ae
    • Korean Journal of Adult Nursing
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    • v.13 no.1
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    • pp.29-39
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    • 2001
  • The purpose of this study was to identify factors influencing patient satisfaction and to evaluate the utility of patient satisfaction as an outcome indicator. The study was conducted by mailed questionnaire. The subjects were 900 patients discharged from adult nursing units in a tertiary teaching hospital. On the discharge date, questionnaires were distributed by two trained research assistants. The questionnaire developed by the researchers was based on Larson(1996)'s study, and consisted of 71 items with the following components: overall satisfaction, domain-specific satisfaction(administration process, hospital facility and environment, nurses, and doctors), patients' loyalty(intention to use the health care service of the hospital in the future), recommendation to others, health benefits, and demographic characteristics. Each item was rated using a five point Likert scale ranging from '1=strongly disagree' to '5= strongly agree'. The response rate was 43%(387/900). The satisfaction level with the health care service was generally high. Perceived health status was the only significant factor influencing satisfaction level. Satisfaction with doctors contributed the most to explaining overall satisfaction. Overall satisfaction was significantly correlated with patient loyalty, recommendation, to other and perceived health benefit. It was found that the score of satisfaction was positively correlated with the score of loyalty, recommendation, and health benefit. Therefore, patient satisfaction seems to be a good outcome indicator.

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Periventricular Germinoma - Case Report - (뇌실주위 배아종 - 증례보고 -)

  • Kwon, Young-Yi;Park, Bong-Jin;Sung, Jung-Nam;Kim, Young-Joon;Cho, Maeng Ki
    • Journal of Korean Neurosurgical Society
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    • v.30 no.10
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    • pp.1245-1249
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    • 2001
  • Germinomas of the central nervous system are rare embryonal tumors(accounting for less than 1% of intracranial neoplasms) that may be located in the pineal region, in the floor of the third ventricle, or in the suprasellar area. We report a case of germinoma developed in periventricular deep white matter without pineal region tumors or suprasellar masses. The 19-year-old male patient presented with slowly progressing headache, dizziness, photophobia, and dysarthria. Initial brain MRI revealed a irregular and dense enhancement from lateral ventricles to 4th ventricle. The stereotactic biopsy of tumor and histologic examination revealed the germinoma. Craniospinal axis radiation therapy was performed. After radiation therapy patient was improved and no neurologic sequelae was seen at discharge. Periventricular germinomas without pineal or suprasellar lesion are very rare. The radiation therapy, as in our case, is beneficial as with other intracranial germinomas. Stereotactic biopsy of periventricular germinoma provides precise pathologic diagnosis and thus allows more specific management.

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