• Title/Summary/Keyword: species transport model

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Modeling Fate and Transport of Organic and Nitrogen Species in Soil Aquifer Treatment-(II) Simulations Based on the Field Conditions (토양/대수층 처리(Soil Aquifer Treatment)에서 유기물과 질소화합물 제거와 이송 모델링-(II) 현장조건의 변화에 따른 모델 결과)

  • Kim Jung-Woo;Kim Jeong-Kon;Lee Young-Joon;Choi Hee-Chul
    • Journal of Soil and Groundwater Environment
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    • v.10 no.4
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    • pp.13-17
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    • 2005
  • For the SAT modeling system considering the reaction module which consists of nitrification, denitrification and organic oxidation, an imaginary cross-sectional 2-dimensional model simulation was carried out to analyze the sensitivity of the model. Four parameters, such as hydraulic conductivity, source water loading rate, ground surface pavement and operation schedule, were considered for the sensitivity analysis. Most factors considered in model development step were well reflected in the simulation results.

The Ion Transport Phenomena through the Liquid Membrane with Macrocyclic Compound (I). Mechanism of Potassium Ion Transport through $H_2O-CHl_3-H_2O$ System with Dibenzo-18-Crown-6 (마크로고리 화합물을 운반체로 하는 액체막을 통한 이온의 운반에 관한 연구 (제1보). Dibenzo-18-Crown-6-(DBC)/$H_2O-CHCl_3-H_2O$계에서 칼륨이온의 운반 메카니즘)

  • Yoon, Chang-Ju;Lee, Shim-Sung;Koo, Chang-Hyun;Kim, Si-Joong
    • Journal of the Korean Chemical Society
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    • v.28 no.3
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    • pp.163-169
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    • 1984
  • The transport rates of $K^+$ion through CHCl$_3$ liquid membrane containing dibenzo-18-crown-6(DBC) as a carrier molecule have been determined at $25^{\circ}C$. The transport rates depend highly on the ion concentration and on the nature of anion. It is concluded that $K^+$ions are transported in the form of ion-pair. In the case of potassium picrate, however, it is found that the transport proceeds with the formation of the incomplete ion-pair in the concentration less than 1.0 ${\times}10^{-3}$M of picrate, while with the complete formation of ion-pair in the concentration more than 1.0 ${\times}10^{-3}$M of picrate. Seven steps of the transport process are suggested and they can be illustrated in terms of energy barrier model as a function of the position of ionic species in the membrane.

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Electrochemical model for the simulation of solid oxide fuel cells (고체산화물연료전지의 시뮬레이션을 위한 전기화학모델)

  • Park, Joon-Guen;Lee, Shin-Ku;Bae, Joong-Myeon
    • 한국신재생에너지학회:학술대회논문집
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    • 2008.10a
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    • pp.63-66
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    • 2008
  • This study presents 0-dimensional model for solid oxide fuel cells(SOFCs). The physics of the cell and the simplifying assumptions are presented, and only hydrogen participates in the electrochemical reaction. The electrical potential is predicted using this model. The Butler-Volmer equation is used to describe the activation polarization and the exchange current density is changed according to the partial pressure of reactants and the temperature. The electrical conductivities of electrodes and an electrolyte are calculated for the ohmic polarization. Material characteristics and temperature affect those factors. Analysis of concentration polarization based on transport of gaseous species through porous electrodes is incorporated in this model. Both binary diffusion and Knudsen diffusion are considered as the diffusion mechanism. For validation, simulation results at this work are compared with our experimental results and numerical results by other researchers.

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Effects of slip velocity on air gap membrane distillation process

  • Loussif, Nizar;Orfi, Jamel
    • Membrane and Water Treatment
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    • v.5 no.1
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    • pp.57-71
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    • 2014
  • In this study, a theoretical model for the transport phenomena in an Air Gap Membrane Distillation used for desalination was developed. The model is based on the conservation equations for the mass, momentum, energy and species within the feed water solution as well as on the mass and energy balances on the membrane sides. The rarefaction impacts are taken into consideration showing their effects on process parameters particularly permeate flow and thermal efficiency. The theoretical model was validated with available data and was found in good agreement especially when the slip condition is introduced. The rarefaction impact was found considerable inducing an increase in the permeate flux and the thermal efficiency.

Effect of Operating Conditions on Characteristics of Combustion in the Pulverized Coal Combustor (미분탄 연소로의 운전조건이 연소특성에 미치는 영향)

  • Kang, Ihl-Man;Kim, Ho-Young
    • 한국연소학회:학술대회논문집
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    • 1999.10a
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    • pp.139-148
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    • 1999
  • In oder to analyze the effect of operating conditions on pulverized coal combustion, a numerical study is conducted at the pulverized coal combustor. Eulerian approach is used for the gas phase, whereas Lagrangian approach is used for the particle phase. Turbulence is modeled using standard ${\kappa}-{\varepsilon}$ model. The description of species transport and combustion chemistry is based on the mixture fraction/probability density function(PDF) approach. Radiation is modeled using P-l model. The turbulent dispersion of particles is modeled using discrete random walk model. Swirl number of secondary air affects the flame front, particle residence time and carbon conversion. Primary/Secondary air mass ratio also affects the flame front but little affects the carbon conversion and particle residence time. Air-fuel ratio only affects the flame front due to lack of oxygen. Radiation strongly affects the flame front and gas temperature distribution because pulverized coal flame of high temperature is considered.

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Prediction of NOx Formation Characteristics in Turbulent Nonpremixed Hydrogen-Air Jet Flames (비예혼합 수소-공기 난류제트화염내의 NOx 생성특성 예측)

  • Kim, S.K.;Kim, Y.M.;Ahn, K.Y.;Oh, K.S.
    • 한국연소학회:학술대회논문집
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    • 1998.10a
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    • pp.165-170
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    • 1998
  • Turbulent nonpremixed $H_2$-air jet flames are numerically investigated using the joint PDF model. The reaction progress variable is derived by assuming the radicals 0, H, and OH to be in partial equilibrium and additional species $HO_2$ and $H_2O_2$ in steady state. The model is extended to npnadiabatic flame by introducing additional variable for the transport of enthalpy and radiative source term is calculated using a local, geometry independent model. In terms of flame structure and NO formation, the predicted results are favorably agreed with experimental data. The effects of nonequilibrium chemistry and radiative heat loss on the thermal NO formation are discussed in detail.

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A Study on Internal Flow of Mixing Tank by CFD (CFD를 이용한 가향 탱크 내부 유동에 관한 연구)

  • Chung, Han-Joo;Cho, Sung-Eel;Yang, Jin-Chul
    • Journal of the Korean Society of Tobacco Science
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    • v.32 no.2
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    • pp.63-69
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    • 2010
  • In the chemical, mineral and electronics, mechanically stirred tanks are widely used for complex liquid mixing processes. The paper present results from a computational fluid dynamics (CFD) model for the mixing tank in casing process. We used CFD software, FLUENT(Fluent, Inc, Lebanon, NH, version 6.2). A species transport model was used to model the problem. The flow patterns in a mixing tank, 1.6 m in diameter and 2.0 m in height, were studied using CFD. Numerical analysis results show that improved mixing tank was reduced low speed flow region and turbulent region in internal flow of mixing tank.

Computational Analysis for Effects of Cooling System on Homogeneity of Ice Thickness and Temperature on Water Surface (빙해수조 공냉 시스템 변화에 따른 결빙 균질도 비교 전산해석)

  • Lee, Sungsu;Kim, Young-Min;Lee, Chun-Ju
    • Journal of the Society of Naval Architects of Korea
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    • v.50 no.3
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    • pp.167-174
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    • 2013
  • Model ice forming process in ice tank needs several steps of seeding, freezing, tempering. In those process, one of the most important factors to affect the accuracy of experiment is the homogeneity of the ice thickness and the temperature. This paper investigated a computational and statistical method to assess the uniformity of the model ice. In addition, the different configurations of freezing systems were considered to improve the uniformity. Qualitative assessment using streamlines from the cooling units was carried out by computational fluid dynamics (CFD) and the quantitative evaluations of the homogeneity were compared using the temperature distribution on the ice surface. In addition, multi species transport analysis is introduced to understand the circulation efficiency of cold air from the cooling units. As the results, optimized configurations were determined by adjusting the angles of vane in the cooling units.

Characteristic of GaN Growth on the Periodically Patterned Substrate for Several Reactor Configurations (반응로 형상에 따른 주기적으로 배열된 패턴위의 GaN 성장 특성)

  • Kang, Sung-Ju;Kim, Jin-Taek;Pak, Bock-Choon;Lee, Cheul-Ro;Baek, Byung-Joon
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.31 no.3 s.258
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    • pp.225-233
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    • 2007
  • The growth of GaN on the patterned substances has proven favorable to achieve thick, crack-free GaN layers. In this paper, numerical modeling of transport and reaction of species is performed to estimate the growth rate of GaN from tile reaction of TMG(trimethly-gallium) and ammonia. GaN growth rate was estimated through the model analysis including the effect of species velocity, thermal convection and chemical reaction, and thermal condition for the uniform deposition was to be presented. The effect of shape and construction of microscopic pattern was also investigated using a simulator to perform surface analysis, and a review was done on the quantitative thickness and shape in making GaN layer on the pattern. Quantitative analysis was especially performed about the shape of reactor geometry, periodicity of pattern and flow conditions which decisively affect the quality of crystal growth. It was found that the conformal deposition could be obtained with the inclination of trench ${\Theta}>125^{\circ}$. The aspect ratio was sensitive to the void formation inside trench and the void located deep in trench with increased aspect ratio.

Estimation of Thermodynamic/Transport Properties of Kerosene using a 3-Species Surrogate Mixture (3-화학종 대체 혼합물을 이용한 케로신의 열역학적·전달 상태량 예측)

  • Joh, Miok;Kim, Seong-Ku;Choi, Hwan-Seok
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.41 no.11
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    • pp.874-882
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    • 2013
  • Kerosene(Jet A-1), one of the propellants for each stage's engine of the Korea Space Launch Vehicle-II(KSLV-II), functions as coolant at the same time as it flows inside the cooling jacket of the combustion chambers and is injected through the film cooling holes. A physical surrogate mixture model to reproduce the thermophysical characteristics of Jet A-1 has been selected and the thermodynamic/transport properties of the model fuel under high pressure including supercritical conditions have been estimated using SUPERTRAPP(NIST SRD4). Comparisons with the measured properties suggest that proposed database can be used to extract properties of Jet A-1 for conjugate heat transfer analysis of liquid propellant rocket engine thrust chambers. Predicted combustion/cooling performance of regeneratively cooled thrust chambers shall be validated through comparisons with upcoming firing test results.