• Title/Summary/Keyword: solution structure

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Effect of the Coating Structure on the Corrosion Resistance of Al-Mg Coated Steel (Al-Mg 코팅층의 구조가 강판 내식성에 미치는 영향)

  • Jung, Jae-Hun;Yang, Ji-Hoon;Kim, Sung-Hwan;Byeon, In-Seop;Jeong, Jae-In;Lee, Myeong-Hoon
    • Journal of the Korean institute of surface engineering
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    • v.49 no.5
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    • pp.454-460
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    • 2016
  • Double-layered Al-Mg films have been deposited by using an e-beam deposition method on a cold-rolled steel sheet(CR), which the structure of the film was Al/Mg/CR. The micro-structure, alloy phase, and corrosion resistance of the Al-Mg coated CR were investigated before and after heat treatment at $400^{\circ}C$ for 2, 3, and 10 min in a nitrogen atmosphere. Total thickness of Al-Mg films was fixed at $3{\mu}m$ and the thickness ratio of Al and Mg layers(Al:Mg) has been changed from 5:1 to 1:5. The cross-sectional morphology of the films, which had the thickness ratio of 2:1(Al:Mg), 1:1, and 1:2, was changed after heat treatment from columnar to featureless structure. The x-ray diffraction data for as-deposited films showed only pure Al and Mg peaks. Al-Mg alloy peaks such as $Al_3Mg_2$ and $Al_{12}Mg_{17}$ phase appeared after the heat treatment. The Al-Mg coating with the thickness ratio of 1:1(Al:Mg) showed the best corrosion resistance of up to 500 hours by salt spray test.

Solution Structure of LXXLL-related Cofactor Peptide of Orphan Nuclear Receptor FTZ-F1

  • Yun, Ji-Hye;Lee, Chul-Jin;Jung, Jin-Won;Lee, Weon-Tae
    • Bulletin of the Korean Chemical Society
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    • v.33 no.2
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    • pp.583-588
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    • 2012
  • Functional interaction between Drosophila orphan receptor FTZ-F1 (NR5A3) and a segmentation gene product fushi tarazu (FTZ) is crucial for regulating genes related to define the identities of alternate segmental regions in the Drosophila embryo. FTZ binding to the ligand-binding domain (LBD) of FTZ-F1 is of essence in activating its transcription process. We determined solution structures of the cofactor peptide ($FTZ^{PEP}$) derived from FTZ by NMR spectroscopy. The cofactor peptide showed a nascent helical conformation in aqueous solution, however, the helicity was increased in the presence of TFE. Furthermore, $FTZ^{PEP}$ formed ${\alpha}$-helical conformation upon FTZ-F1 binding, which provides a receptor bound structure of $FTZ^{PEP}$. The solution structure of $FTZ^{PEP}$ in the presence of FTZ-F1 displays a long stretch of the ${\alpha}$-helix with a bend in the middle of helix.

Analysis of Symmetric and Periodic Open Boundary Problem by Coupling of FEM and Fourier Series

  • Kim, Young Sun
    • Journal of Magnetics
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    • v.18 no.2
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    • pp.130-134
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    • 2013
  • Most electrical machines like motor, generator and transformer are symmetric in terms of magnetic field distribution and mechanical structure. In order to analyze these problems effectively, many coupling techniques have been introduced. This paper deals with a coupling scheme for open boundary problem of symmetric and periodic structure. It couples an analytical solution of Fourier series expansion with the standard finite element method. The analytical solution is derived for the magnetic field in the outside of the boundary, and the finite element method is for the magnetic field in the inside with source current and magnetic materials. The main advantage of the proposed method is that it retains sparsity and symmetry of system matrix like the standard FEM and it can also be easily applied to symmetric and periodic problems. Also, unknowns of finite elements at the boundary are coupled with Fourier series coefficients. The boundary conditions are used to derive a coupled system equation expressed in matrix form. The proposed algorithm is validated using a test model of a bush bar for the power supply. And the each result is compared with analytical solution respectively.

Formation and Structure of Self-Assembled Monolayers of Octylthioacetates on Au(111) in Catalytic Tetrabutylammonium Cyanide Solution

  • Park, Tae-Sung;Kang, Hun-Gu;Choi, In-Chang;Chung, Hoe-Il;Ito, Eisuke;Hara, Masahiko;Noh, Jae-Geun
    • Bulletin of the Korean Chemical Society
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    • v.30 no.2
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    • pp.441-444
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    • 2009
  • The formation and structure of self-assembled monolayers (SAMs) by the adsorption of acetyl-protected octylthioacetate (OTA) on Au(111) in a catalytic tetrabutylammonium cyanide (TBACN) solution were examined by means of scanning tunneling microscopy (STM), X-ray photoelectron spectroscopy (XPS), and cyclic voltammetry (CV). Molecular-scale STM imaging revealed that OTA molecules on Au(111) in a pure solvent form disordered SAMs, whereas they form well-ordered SAMs showing a c(4 × 2) structure in a catalytic TBACN solution. XPS and CV measurements also revealed that OTA SAMs on Au(111) formed in a TBACN solution have a stronger chemisorbed peak in the S 2p region at 162 eV and a higher blocking effect compared to OTA SAMs formed in a pure solvent. In this study, we clearly demonstrate that TBACN can be used as an effective deprotecting reagent for obtaining well-ordered SAMs of thioacetyl-protected molecules on gold.

Localization and a Distributed Local Optimal Solution Algorithm for a Class of Multi-Agent Markov Decision Processes

  • Chang, Hyeong-Soo
    • International Journal of Control, Automation, and Systems
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    • v.1 no.3
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    • pp.358-367
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    • 2003
  • We consider discrete-time factorial Markov Decision Processes (MDPs) in multiple decision-makers environment for infinite horizon average reward criterion with a general joint reward structure but a factorial joint state transition structure. We introduce the "localization" concept that a global MDP is localized for each agent such that each agent needs to consider a local MDP defined only with its own state and action spaces. Based on that, we present a gradient-ascent like iterative distributed algorithm that converges to a local optimal solution of the global MDP. The solution is an autonomous joint policy in that each agent's decision is based on only its local state.cal state.

Exact Solution for Resistance Capacity utilizing Bingham Model of MR Dampers under Collapse Load (붕괴하중을 받는 MR 댐퍼의 Bingham 모델을 이용한 저항성능 정해)

  • Seong, Ji-Young;Min, Kyung-Won;Kim, Jin-Koo
    • Transactions of the Korean Society for Noise and Vibration Engineering
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    • v.21 no.3
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    • pp.234-240
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    • 2011
  • This study deals with progressive collapse of a structure retrofitted with MR dampers. In order to assess their effect of mitigation which prevents progressive collapse, control force ratio is defined by friction force of MR dampers divided by external force. First, simple model of a structure with MR dampers is suggested. Using the model, exact solution with the control force ratio is obtained. When and where the system is stopped is predicted by the derived solution. Through the dissipated energy by MR dampers during collapse event, equivalent damping ratio is derived. Finally, comparison of exact and equivalent solutions is presented.

A Far Field Solution of the Slowly Varying Drift Force on the Offshore Structure in Bichromatic Waves-Three Dimensional Problems

  • Lee, Sang-Moo
    • Journal of Ocean Engineering and Technology
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    • v.24 no.6
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    • pp.1-6
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    • 2010
  • A far field approximate solution of the slowly varying force on a 3 dimensional offshore structure in gravity ocean waves is presented. The first order potential, or at least the far field form of the Kochin function, of each frequency wave is assumed to be known. The momentum flux of the fluid domain is formulated to find the time variant force acting on the floating body in bichromatic waves. The second order difference frequency force is identified and extracted from the time variant force. The final solution is expressed as the circular integration of the product of Kochin functions. The limiting form of the slowly varying force is identical to the mean drift force. It shows that the slowly varying force components caused by the body disturbance potential can be evaluated at the far field.

CIGS Thin Film Fabrication Using Spray Deposition Technique (스프레이 분무법을 이용한 CIGS 태양전지 박막의 합성)

  • Cho, Jung-Min;Bae, Eun-Jin;Suh, Jeong-Dae;Song, Ki-Bong
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2010.06a
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    • pp.250-250
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    • 2010
  • We have prepared CIGS thin film absorber layers with simple solution spray deposition technique and thin film were synthesized with different atomic ratio. CIGS thin films were synthesized using non-vacuum solution deposition method on pre-heated sodalime glass substrates and Mo-coated soadlime glass substrate. In precursor solution were Cu : In : Ga: S ratio 4 : 3 : 2 : 8 and the crystal type of sprayed thin film were CIGS chalcopyrite structures. This structure was identified as typical chalcopyrite tetragonal structure with XRD analysis. This result showed that CIGS solution deposition technique has potential for the one step synthesis and low cost fabrication process for CIS or CIGS thin film absorber layer.

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Mass perturbation influence method for dynamic analysis of offshore structures

  • Cho, Kyu Nam
    • Structural Engineering and Mechanics
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    • v.13 no.4
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    • pp.429-436
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    • 2002
  • The current work presents an analysis algorithm for the modal analysis for the dynamic behaviors of offshore structures with concepts of mass perturbation influence term. The mass perturbation concept by using the term, presented in this paper offers an efficient solution procedure for dynamical response problems of offshore structures. The basis of the proposed method is the mass perturbation influence concepts associated with natural frequencies and mode shapes and mass properties of the given structure. The mathematical formulation of the mass perturbation influence method is described. New solution procedures for dynamics analysis are developed, followed by illustrative example problems, which deal with the effectiveness of the new solution procedures for the dynamic analysis of offshore structures. The solution procedures presented herein is compact and computationally simple.

Synthesis of a new class of carbon nanomaterials by solution plasma processing for use as air cathodes in Li-Air batteries

  • Kang, Jun
    • Journal of Advanced Marine Engineering and Technology
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    • v.39 no.8
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    • pp.833-837
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    • 2015
  • Li-air batteries have a promising future for because of their high energy density, which could theoretically be equal to that of gasoline. However, substantial Li-air cell performance limitations exist, which are related to the air cathode. The cell discharge products are deposited on the surfaces of the porous carbon materials in the air electrode, which blocks oxygen from diffusing to the reaction sites. Hence, the real capacity of a Li-air battery is determined by the carbon air electrode, especially by the pore volume available for the deposition of the discharged products. In this study, a simple and fast method is reported for the large-scale synthesis of carbon nanoballs (CNBs) consisting of a highly mesoporous structure for Li-air battery cathodes. The CNBs were synthesized by the solution plasma process from benzene solution, without the need for a graphite electrode for carbon growth. The CNBs so formed were then annealed to improve their electrical conductivity. Structural characterization revealed that the CNBs exhibited both an pore structure and high conductivity.