• 제목/요약/키워드: solution phase reduction

검색결과 191건 처리시간 0.023초

3.5% NaCl 수용액의 pH변화가 복합조직강의 부식피로파괴에 미치는 영향 (Influence of pH in 3.5% NaCl aqueous solution on corrosion fatigue-fracture of dual phase steel)

  • 오세욱;안호민;도영문
    • 한국해양공학회지
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    • 제1권2호
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    • pp.123-129
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    • 1987
  • Corrosion fatigue fracture of dual phase steel(SS41) and raw material steel(SS41) were investigated in 3.5% NaCl aqueous solution at PH 4,6,9 and 11. The fatigue limit of dual phase steel is increased approximately 1.8 times larger than that of raw material in air. The corrosion fatigue life of dual phase steel is about 5-10 times larger than that of raw material in 3.5% NaCl aqueous solution. The reduction of fatigue life is larger for the acidsalt solution than for the alkali salt solution. The reduction of stress level on the reduction ratio of corrosion fatigue life is large as pH 6-11. The reduction ratio of corrosion fatigue life of dual phase steel and raw material is nearly coincided at pH 2. While at pH4-2 the reduction ratio of corrosion fatigue life only depends on the corrosion effect. It has been found that the corrosion resistance effect of dual phase steel is smaller than that of raw material in corrosion fatigue crack propagation rate. As pH below 6 is changed, it can be clearly observed from raw material that the brittle intergranular fracture is characterized, and from the above result, the influence of corrosion of dual phase steel is small.

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Influence of Ni Addition on Mechanical and Magnetic Properties of Yttria-Stabilized Tetragonal Zirconia

  • Kondo, H.;Sekino, T.;Choa, Y.H.;Kusunose, T.;Nakayama, T.;Niihara, K.
    • 한국결정성장학회:학술대회논문집
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    • 한국결정성장학회 2000년도 Proceedings of 2000 International Nano Crystals/Ceramics Forum and International Symposium on Intermaterials
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    • pp.243-248
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    • 2000
  • Effect of NiO addition on microstructure, stability of tetragonal phase and mechanical properties was investigated. (Y, Ni)-TZP solid solution was obtained by pressureless sintering. The fracture toughness was increased by solid solution of NiO. Neither reaction phase nor glassy phase was observed at the grain boundaries. From these results, it was determined that solid solution of NiO was destabilized tetragonal phase of Y-TZP. Y-TZP/Ni nanocomposite that contained nano-sized Ni particles was also fabricated by internal reduction method. Some evaluations and discussions were carried out for both (Y, Ni)-TZP solid solution and Y-TZP/Ni nanocomposite.

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수평 2상유동에서 마찰저항감소에 관한 연구 (A study on the drag reduction in a horizontal two phase flow)

  • 차경옥;김재근
    • 대한기계학회논문집B
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    • 제20권4호
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    • pp.1472-1480
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    • 1996
  • The phenomena of drag reduction using small quantities of a linear macromolecules has attracted the attention of experimental investigations. It is well known that drag reduction in single phase liquid flow is affected by polymer materials, molecular weight, polymer concentration, pipe diameter and flow velocity. But the research on drag reduction in two phase flow has not intensively investigated. Drag reduction can be applied to phase change system such as chemical reactor, pool and boiling flow, and to flow with cavitation which occurs pump impellers. The purpose of the present work is to evaluate the drag reduction by measuring pressure drop, mean liquid velocity, and turbulent intensity and determine the effects of polymer additives on drag reduction in horizontal two phase flow. Experimental results show higher drag reduction using co-polymer comparing with using polyacrylamide. Mean liquid velocities increase as adding more polymer, and turbulent intensities decrease as the distance for the wall in inversed.

합성 고분자물질 A611P를 첨가한 기액 2상 수직상향의 유동특성에 관한 실험적 연구 (Experimental study on the flow characteristic by the co-polymer A6l1P additive in gas-liquid two-phase vertical up flow)

  • 차경옥;김재근;양회준
    • 설비공학논문집
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    • 제10권4호
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    • pp.398-410
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    • 1998
  • Two-phase flow phenomena are observed in many industrial facilities and make much importance of optimum design for nuclear power plant and the liquid transportation system. The particular flow pattern depends on the conditions of pressure, flow velocity, and channel geometry. However, the research on drag reduction in two-phase flow is not intensively investigated. Therefore, experimental investigations have been carried out to analyze the drag reduction and void fraction by polymer addition in the two-phase flow system. We find that the polymer solution changes the characteristic of two-phase flow. The peak position of local void friction moves from tile wall of the pipe to the center of the pipe when polymer concentration increase. And then we predict that it is closely related with the frau reduction.

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수직관내 리튬브로마이드 수용액막의 흡수과정에 대한 비흡수가스의 영향 (Effects of Non-Absorbable Gases on the Absorption Process of Aqueous LiBr Solution Film in a Vertical Tube (II))

  • 김병주;이찬우
    • 대한기계학회논문집B
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    • 제22권4호
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    • pp.499-509
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    • 1998
  • In the absorption process of water vapor in a liquid film, the composition of the gas phase, in which a non-absorbable gas is combined with the absorbate influences the transport characteristics remarkably. In the present study, the absorption processes of water vapor into aqueous solution of lithium bromide in the presence of non-absorbable gases were investigated analytically. The continuity, momentum, energy and diffusion equations for the solution film and gas phase were formulated in integral forms and solved numerically. It was found that the mass transfer resistance in gas phase increased with the concentration of non-absorbable gas. However the primary resistance to mass transfer was in the liquid phase. As the concentration of non-absorbable gas in the absorbate increased, the liquid-vapor interfacial temperature and concentration of absorbate in solution decreased, which resulted in the reduction of absorption rate. The reduction of mass transfer rate was found to be significant for the addition of a small amount of non-absorbable gas to the pure vapor, especially at the outlet of an absorber where non-absorbable gases accumulated. At higher non-absorbable gas concentration, the decrease of absorption flux was almost linear to the volumetric concentration of non-absorbable gas.

고분자물질 첨가에 의한 유동특성에 관한 연구 (A Study on the Characteristics of Flow with Polymer Additives)

  • 차경옥;김재근
    • 한국자동차공학회논문집
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    • 제4권3호
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    • pp.176-186
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    • 1996
  • The phenomena of drag reduction using small quantities of a liner macromolecules has attracted the attention of many experimental investigations. On the other hand drag reduction in two phase flow can be applied to the transport of crude oil, phase change system such as chemical reactor, pool and boiling flow, and to flow with cavitation which occurs pump impellers. But the research on dragreduction in two phase flow is not sufficient. The purpose of the present work is to evaluate the drag reduction by measuring pressure drop, void fraction, mean liquid velocity and turbulent intensity whether polymer additives a horizontal single and two phase system or not. Flow pattern of air-water two phase flow was classified by electrical conductivity probe signal. Velocities and turbulent intensities of signal were measured simultaneously with a Hot-film anemometer.

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기-액(氣-液) 2상유동(二相流動)시 항력(抗力)에 관(關)한 연구(硏究) (The Study on the Drag Reduction for Gas/Liquid Two Phase Flow)

  • 차경옥;오율권;김재근
    • 한국분무공학회지
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    • 제1권3호
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    • pp.20-28
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    • 1996
  • It is well known that drag reduction in single phase liquid flow is affected by polymer material, molecular weight, polymer concentration, pipe diameter, and flow velocity. Drag reduction in two phase flow can be applied to the transport of crude oil, phase change system such as chemical reactor, pool and boiling flow, and to present cavitation which occurs in pump impellers. But the research of drag reduction in two phase flow is not sufficient. The purpose of the present work is to evaluate the drag reduction by measuring pressure drop, void fraction whether polymer is added in the horizontal two phase system or not. Experiment has been conducted in a test section with 24 m of the inner diameter and 1,500 mm of the length. The used polymer materials are two kinds of polyacrylamide[PAAM] and co-polymer[A611P]. The polymer concentration was varied with 50, 100 and 200 ppm under the same experimental conditions. Experimental results were shown that the drag is higher reduced by co-polymer rather than polyanylamide.

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액상환원법에 의한 저온 열처리용 Ag 나노분말의 합성 (Synthesis of Ag Nanopowder for Low Temperature Heat Treatment Prepared by Liquid Phase Reduction Method)

  • 이종국;최남규;송대성;양권승;서동석
    • 열처리공학회지
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    • 제18권4호
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    • pp.242-246
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    • 2005
  • Silver nanoparticles were synthesized by liquid phase reduction method from aqueous silver nitrate solution and borohybride as a reduction agent. The morphology, particle size and shape were influenced by the reaction conditions such as the concentration of $AgNO_3$, a reduction agent and addition of surfactant. The particle size decreased with decreasing the concentration of silver nitrate and using a borohydride. The obtained Ag particles showed the spherical shape with the range of 10-20 nm.

Two Phase Reduction of Carbonyl Compounds with Sodium Borohydride

  • Jin Soon Chong;Nung Min Yoon
    • 대한화학회지
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    • 제15권3호
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    • pp.117-120
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    • 1971
  • Possibility of two phase reduction of carbonyl compounds to the corresponding alcohols was studied. Thus the 0.5 M ether solutions of the representative carbonyl compounds were treated with alkaline stabilized sodium borohydride aqueous solution at room temperature. Butyraldehyde was reduced rapidly within one hr., whereas other aldehydes tested; heptaldehyde, benzaldehyde, and 1-naphthaldehyde were reduced in 6-12 hr. 2-Heptanone was reduced much slowly; 87% in 48 hr., however, acetophenone was reduced moderately; 92% in 12 hr. and cycloalkanones were reduced rapidly (cyclohexanone in 0.5 hr., and cyclopentanone in 3-6 hr.).

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수직 상향유동 배관에서 비뉴톤유체에 의한 2상류의 유동특성 (The Characteristics of Two Phase Flow by Non-Newtonian Fluid for Vertical Up-ward in a Tube)

  • 차경옥;김재근;최경석
    • 한국가스학회지
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    • 제2권4호
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    • pp.53-59
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    • 1998
  • 기-액 2상유동장에서 유동양식은 압력강하, 보이드율분포, 유동장의 기하학적 형상과 밀접한 관계가 있다. 한편 원유수송, 비등이 발생하는 유동, 펌프에서 발생하는 케비테션 현상, 그리고 화학 반응로와 같은 상변화 장치 등의 2상유동에서 고분자물질에 의한 저항감소 현상의 적용이 가능할 것으로 예상된다. 그러나 2상유동장에서 고분자물질에 의한 저항감소에 관한 연구는 매우 미비하다. 그래서 본 연구는 2상유동장에 합성고분자물질(A611p)에 의한 저항감 소율을 실험을 통하여 계측 및 분석하였다. 본 연구에서는 고분자물질의 농도를 증가시킬수록 국부보이드율의 최고치가 관의 중심에서 관의 벽쪽으로 이동하며 2상유동의 유동양식이 변화됨을 규명하였다. 그래서 저항감소율과 유동양식과 밀접한 관계가 있음을 예측할 수 있었다.

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