• Title/Summary/Keyword: solution casting

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Effect of Physical Properties of Polymer Solution on the Thickness of Ultrathin Membrane Prepared by Water Casting Method (고분자용액의 물성이 수면전개 박막의 두께에 미치는 영향)

  • Nam, Suk-Tae;Han, Myeong-Jin;Choi, Ho-Sang;Park, Young Tae
    • Applied Chemistry for Engineering
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    • v.9 no.2
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    • pp.200-206
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    • 1998
  • The effect of surface tension and viscosity of polymer solution on the thickness of water casting membranes was studied. Spreading of polymer solutions on water surface was governed by the surface tension and viscosity of the polymer solution. The thickness of water casting membrane was affected by these two factors. The properties, mentioned above, were proportional to the polymer concentration. The order of magnitude in surface tension was PVC>PS>CA and that of viscosity was CA>PS>PVC. The difference of surface tension between water and polymer solution acts as driving force for spreading of polymer solution, but the viscosity as resistance. The thickness of polymeric membrane prepared by water casting was PS>CA>PVC. The order of membrane thickness was not as same as that of surface tension. This phenomena were due to the viscosity which acts as more effective spreading resistance than the surface tension.

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Scheduling of a Casting Sequence Under Just-In-Time (JIT) Production (적시 생산 방식에서의 주조공정 스케줄링)

  • Park, Yong-Kuk;Yang, Jung-Min
    • Journal of Korean Society of Industrial and Systems Engineering
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    • v.32 no.3
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    • pp.40-48
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    • 2009
  • In this article, scheduling of a casting sequence is studied in a casting foundry which must deliver products according to the Just-in-time(JIT) production policy of a customer. When a foundry manufactures a variety of casts with an identical alloy simultaneously, it frequently faces the task of production scheduling. An optimal casting schedule should be emphasized in order to maximize the production rate and raw material efficiency under the constraints of limited resources; melting furnaces and operation time for a casting machine. To solve this practical problem-fulfilling the objectives of casting the assigned mixed orders for the highest raw material efficiency in a way specified by the customer's JIT schedule, we implement simple integer programming. A simulation to solve a real production problem in a typical casting plant proves that the proposed method provides a feasible solution with a high accuracy for a complex, multi-variable and multi-constraint optimization problem. Employing this simple methodology, a casting foundry having an automated casting machine can produce a mixed order of casts with a maximum furnace utilization within the due date, and provide them according to their customer's JIT inventory policy.

Preparation of Polycarbonate/Polyaniline Conducting Composite and Their Electrical Properties (Polycarbonate/Polyaniline 전도성 복합체의 제조 및 전기적 성질)

  • Lee, Wan-Jin;Kim, Yong-Ju
    • Applied Chemistry for Engineering
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    • v.10 no.2
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    • pp.287-292
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    • 1999
  • The conducting composites were prepared by solution blending of polyaniline (PANI) as a conducting polymer and polycarbonate (PC) as a matrix in chloroform. Also the composites film was prepared by solution casting method. The PANI was protonated with alkylbenzenesulfonic acids, such as camphorsulfonic acid (CSA) or dodecylbenzenesulfonic acid (DBSA). The electrical conductivity of composites prepared by solution casting was enhanced compared with that of compression molding. The electrical conductivity, tensile strength and morphology were observed as a function of the amount of protonating agent as well as PANI complex content. In general, as the PANI complex content was increased, the electrical conductivity increased. In the case of the composite film containing 25 wt % of PANI complex doped with DBSA, the electrical conductivity exhibited 3.18 S/cm.

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A Development of Casting Design Automation Framework (주조방안 자동설계 프레임워크 구축)

  • Cho, Won-Chul;Kim, Sung-Min;Nyamsuren, Purevdorj;Sohn, Jung-Woo;Lee, Soo-Hong
    • Korean Journal of Computational Design and Engineering
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    • v.17 no.2
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    • pp.91-96
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    • 2012
  • Use of casting simulation software, analyzing the reason for defect became easy. However, to create a practical solution, experienced casting expert's knowledge is always indispensable. In this study, we develop casting design automation system and the algorithm based on casting expert's knowledge, so that faster and more accurate design is enabled. Especially, to generate runner which can be shaped in numerous ways, we suggest the 'nexus' method to shape runner system.

Preparation of Forward Osmosis Membranes with Low Internal Concentration Polarization (농도 분극이 저감된 정삼투 분리막 제조)

  • Kim, Nowon;Jung, Boram
    • Membrane Journal
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    • v.24 no.6
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    • pp.453-462
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    • 2014
  • Thin film composite (TFC) polyamide (PA) membranes were prepared on polyester (PET) nonwoven reinforced polysulfone supports for forward osmosis (FO) processes. PSF (polysulfone) supports were prepared via the phase inversion process from PSF casting solutions in dimethyl formamide (DMF) solvents (19 wt%) by using a PET nonwoven (thickness of $100{\mu}m$) as a mechanical reinforcing material for reverse osmosis (RO) membrane. The PSF support from 19 wt% of DMF/PSF casting solution showed sponge-like morphology and asymmetric internal structure. To reduce the internal concentration polarization in FO operation, thin ($20{\mu}m$ of thickness) nonwoven-supported PSF supports were prepared by using PSF/DMF casting solution (9~19 wt%). A desirable support structure with a highly porous sponge-like morphology were achieved from the thin nonwoven-supported PSF layer prepared with 9~12 wt% casting solution. A crosslinked aromatic polyamide layer was fabricated on top of each support to form a TFC PA membrane. The tested sample from 12 wt% of DMF/PSF casting solution presented outstanding FO performance, almost 5.5 times higher water flux (24.3 LMH) with low reverse salt flux (RDF, 1.5 GMH) compared to a thick nonwoven rainforced membrane (4.5 LMH of flux and 3.47 GMH of RSF). By reducing the thickness of the nonwoven and optimizing PSF concentration of casting solution, the morphology of the prepared membranes were changed from a dense structure to a porous sponge structure in the boundary area between nonwoven and PET support layer.

Effects of the Solid Solution Treatment Conditions and Casting Methods on Mechanical Properties of Al-Si-Cu Based Alloys (Al-Si-Cu계 합금의 주조법과 용체화처리 조건이 기계적 특성변화에 미치는 영향)

  • Moon, Min-Kook;Kim, Young-Chan;Kim, Yu-Mi;Choi, Se-Weon;Kang, Chang-Seog;Hong, Sung-Kil
    • Journal of Korea Foundry Society
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    • v.38 no.6
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    • pp.111-120
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    • 2018
  • In this study, the effects of two different casting methods (gravity casting and, diecasting) and various solid-solution conditions on the mechanical properties of ASC (Al-10.5wt%Si-1.75wt%Cu) and ALDC12 (Al-10.3wt%Si-1.72wt%Cu-0.76wt%Fe-0.28wt% Mn-0.32wt%Mg-0.9wt%Zn) alloys were investigated. A thermodynamic solidification analysis program (PANDAT) was used to predict the liquidus, solidus, and phases of the used alloys. In the results of an XRD analysis, ${\beta}$-AlFeSi peaks were observed only in the ALDC12 alloy regardless of the casting method or SST (solid-solution treatment) conditions. However, according to the results of a FE-SEM observation, both ${\theta}(Al_2Cu)$ and ${\beta}$-AlFeSi were found to exist besides ${\alpha}$-Al and eutectic Si in the gravity-casted ASC alloy at $500^{\circ}C$ after a SST of 120min. The ${\alpha}$-AlFeSi and ${\beta}$-AlFeSi phases including the eutectic phases were also found to exist in the ALDC12 alloy. The results of a microstructural observation and analyses by XRD, FE-SEM and EDS were in good agreement with the PANDAT results. The gravity-casted ALDC12 and ASC specimens showed the highest Y.S. and UTS values after aging for three hours at $180^{\circ}C$ after a SST at $500^{\circ}C$ for 30min. At longer solid-solution treatment times at $500^{\circ}C$ in the gravity-casted ALDC12 and ASC specimens, the elongations of the ASC alloys increased, whereas they decreased slightly in the ALDC12 alloys.

Determination of Solid Solution Treatment Condition of Mg-6Al-xZn(x=0,1,2) Alloys Fabricated by Squeeze Casting Method (용탕단조법에 의해 제조된 Mg-6Al-xZn(x=0,1,2) 합금의 용체화처리조건 규명)

  • Kang, Min-Cheol;Yoon, Il-Sung;Kim, In-Bae
    • Journal of the Korean Society for Heat Treatment
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    • v.9 no.4
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    • pp.281-288
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    • 1996
  • This study has been investigated the influence of solid solution treatment on the microstructure of Mg-6Al-xZn(x=0,1,2) alloys fabricated by squeeze casting process. The products having clean surface and fine microstructure are fabricated by adopting the liquid metal forging method. The microstructures of as-fabricated state show ${\beta}(Mg_{17}Al_{12})$ precipitates between the dendrite boundaries. It is found that the hardness of the alloys is increased with increasing amount of zinc due to the solid solution hardening effect of zinc. In the changes of microstructure upon solid solution treatment time at $405^{\circ}C$, ${\beta}$ phases are dissolved in ${\alpha}$ matrix up to 1hr and the microstructure are coarsened rapidly after 2hrs. The microhardness are decreased rapidly until 1hr of solution treatment time and then stabilized. From the above results, it is concluded that the optimum solid solution treatment condition for Mg-6Al-xZn alloys is at $405^{\circ}C$ for 1hr. The solution treatment time is greatly reduced comparing to conventional casting(at $385{\sim}418^{\circ}C$ for 10~14hrs) due to the formation of the super-saturated solid solution by liquid metal forging.

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Preparation and Structure of the Synthetic Polymeric Membranes based on Polystyrene and Poly(sodium 4-styrene sulfonate) (Polystyrene과 Poly(sodium 4-styrene sulfonate)를 이용한 합성 고분자 분리막의 제막 및 구조)

  • 변홍식;탁태문
    • Membrane Journal
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    • v.6 no.4
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    • pp.273-283
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    • 1996
  • A cation-exchange membranes were prepared by polystyrene and poly(sodium 4-styrene sulfonate). The degree of crosslinking of polystyrene membranes was controlled by DVB. At the same time, the structure of PS membranes was changed from RO to MF by varying the concentration of PSS in the casting solution. Water flux increased with PS-PSS membranes due to the sulfonate groups, and final membrane cast from the solution containing 5% of DVB and 3% of PSS showed MF structure.

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Effect of Toluene Added to Casting Solution on Characteristic of Phase Inversion Polysulfone Membrane (상전환 공정에 의한 폴리설폰막의 제조에 있어 제막용액에 첨가된 톨루엔의 영향)

  • Choi, Seung-Rag;Park, So-Jin;Seo, Bum-Kyoung;Lee, Kune Woo;Han, Myeong-Jin
    • Applied Chemistry for Engineering
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    • v.19 no.6
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    • pp.633-639
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    • 2008
  • Polysulfone membranes were prepared via the phase inversion process. Toluene was added as a nonsolvent additive in the casting solution containing a mixture of polysulfone and n-methylpyrrolidone. When prepared via the diffusion-induced process using isopropanol as a precipitation nonsolvent, the solidified membranes revealed a similar asymmetric structure irrespective of the addition of toluene, presenting both a dense skin layer and a sponge-like support layer. The added toluene played a role of enhancing liquid-liquid phase separation of the casting solution, and skin layer thickness of a prepared membrane increased with toluene content in the casting solution. On membrane performance, the solute rejection showed a uniform behavior irrespective of the addition of toluene. However, in spite of the significant increase in dense skin layer thickness, the water permeation through the membrane prepared with 60 wt% toluene revealed five times as much flux, compared with that of the membrane prepared without toluene additive.

Evaluation of the Characteristics of the Aluminum Alloy(AC8A) Casting Material by Heat Treatment(II) (AC8A 알루미늄 합금 주조재의 열처리에 의한 특성 평가(II))

  • Moon, Kyung-Man;Jeong, Jae-Hyun;Lee, Myeong-Hoon;Baek, Tae-Sil
    • Journal of Power System Engineering
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    • v.20 no.5
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    • pp.29-36
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    • 2016
  • Aluminum alloys have been widely used in engine materials, cold & hot-water storage vessels and piping etc., Furthermore, the aluminum alloy of AC8A have been widely used in mold casting material of engine piston for various vehicles because of its properties of temperature, wear and corrosion resistance. Therefore, it is considered that evaluation of corrosion resistance as well as wear resistance of AC8A material is also important to improve its property and to prolong its lifetime. In previous paper, the effect of solution($510^{\circ}C$:4hrs) and tempering($190^{\circ}C$: 16, 24, and 36 hrs)heat treatments to corrosion resistance and hardness were investigated using electrochemical method. In this study, in order to examine completely the effect of the tempering hours to hardness variation and corrosion resistance, the results of solution($510^{\circ}C$:4hrs) and tempering($190^{\circ}C$: 2, 4, 8 and 12hrs)heat treatments to hardness and corrosion resistance were investigated using electrochemical method. The hardness decreased with solution heat treatment compared to mold casting condition, but its value increased with tempering heat treatment. Furthermore, the corrosion resistance increased with decreasing of the hardness, and decreased with increasing of the hardness reversely. And the tempering heat treatment temperature at $190^{\circ}C$ for 8 hrs exhibited the highest value of the hardness and also indicated the highest corrosion current density. However, the values of hardness and corrosion current density was again increasingly decreased with increasing of tempering hours than 8 hrs, Consequently, it is suggested that decision of the optimum. tempering hours is very important to improve the corrosion or wear resistance.