• Title/Summary/Keyword: solution accuracy

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Comparison of Sampling and Analytical Methods for Determining Airborne Hexavalent Chromium -Limit of Detection, Accuracy and Precision of Analytical Procedures (공기중 6가 크롬 측정 방법 비교 -검출한계, 정확도 및 정밀도-)

  • 신용철;이병규;이지태
    • Journal of Korean Society for Atmospheric Environment
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    • v.18 no.1
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    • pp.39-49
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    • 2002
  • In this study, limits of detection (LOD), accuracy and precision of four sampling/ analytical methods were evaluated and compared for the determination of airborne hexavalent chromium, Cr (VI). The methods include : (1) a combination of the National Institute for Occupational Safety and Health (NIOSH) Method 7600/U. S. Environmental Protection Agency (EPA) Method 218.6 (NIOSH/EPA Method) proposed by Shin and Paik, 2) two impinger methods using 2% NaOH/3% Na$_2$CO$_3$. (3) same as (2) but with 0.02 N NaHCO$_3$absorbing solution, and (4) the Occupational Safety and Health (OSHA) Method ID-215. An ion chromatograph/visible absorbance detector was used for the analysis of Cr (VI) in sample solution. Limit of detection (LOD) , analytical accuracy, and precision were also tested using Cr (VI) spike samples. Recoveries (as index of accuracy) and coefficient of variation (CV) (as a index of precision) were determined. Two-way ANOVA and Turkey's test were performed to test the significance in differences among recoveries and CVs of the methods. In all the methods, the peaks of Cr (VI) were separated sharply on chromatograms and exhibited a strong linearity with Cr (VI) concentrations in solution. The correlation coefficients of calibration curves typically ranged from 0.9997 to 0.9999, and the analytical LODs from 0.025 to 0.1$\mu\textrm{g}$/sample. All the method had good sensitivities and linearities between Cr (VI) levels and peak areas. The accuracies (% mean recoveries) of the methods ranged from 80.1 to 104.2%, while the precisions (pooled coefficient of variation) ranged from 3.16 to 4.43%. The impinger methods showed higher recoveries ( > 95%) than those of the PVC filter methods (the OSHA Method and the NIOSH/EPA Method). It was assumed that Cr (VI) on PVC filter was exposed to air and reduced to trivalent chromium, Cr (III), whereas it was stabilized in alkali solution contained in impinger. Thus, a special treatment of Cr (VI) samples collected on PVC filters may be required.

Time Synchronization Error and Calibration in Integrated GPS/INS Systems

  • Ding, Weidong;Wang, Jinling;Li, Yong;Mumford, Peter;Rizos, Chris
    • ETRI Journal
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    • v.30 no.1
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    • pp.59-67
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    • 2008
  • The necessity for the precise time synchronization of measurement data from multiple sensors is widely recognized in the field of global positioning system/inertial navigation system (GPS/INS) integration. Having precise time synchronization is critical for achieving high data fusion performance. The limitations and advantages of various time synchronization scenarios and existing solutions are investigated in this paper. A criterion for evaluating synchronization accuracy requirements is derived on the basis of a comparison of the Kalman filter innovation series and the platform dynamics. An innovative time synchronization solution using a counter and two latching registers is proposed. The proposed solution has been implemented with off-the-shelf components and tested. The resolution and accuracy analysis shows that the proposed solution can achieve a time synchronization accuracy of 0.1 ms if INS can provide a hard-wired timing signal. A synchronization accuracy of 2 ms was achieved when the test system was used to synchronize a low-grade micro-electromechanical inertial measurement unit (IMU), which has only an RS-232 data output interface.

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Evaluation of a Nutrition Model in Predicting Performance of Vietnamese Cattle

  • Parsons, David;Van, Nguyen Huu;Malau-Aduli, Aduli E.O.;Ba, Nguyen Xuan;Phung, Le Dinh;Lane, Peter A.;Ngoan, Le Duc;Tedeschi, Luis O.
    • Asian-Australasian Journal of Animal Sciences
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    • v.25 no.9
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    • pp.1237-1247
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    • 2012
  • The objective of this study was to evaluate the predictions of dry matter intake (DMI) and average daily gain (ADG) of Vietnamese Yellow (Vang) purebred and crossbred (Vang with Red Sindhi or Brahman) bulls fed under Vietnamese conditions using two levels of solution (1 and 2) of the large ruminant nutrition system (LRNS) model. Animal information and feed chemical characterization were obtained from five studies. The initial mean body weight (BW) of the animals was 186, with standard deviation ${\pm}33.2$ kg. Animals were fed ad libitum commonly available feedstuffs, including cassava powder, corn grain, Napier grass, rice straw and bran, and minerals and vitamins, for 50 to 80 d. Adequacy of the predictions was assessed with the Model Evaluation System using the root of mean square error of prediction (RMSEP), accuracy (Cb), coefficient of determination ($r^2$), and mean bias (MB). When all treatment means were used, both levels of solution predicted DMI similarly with low precision ($r^2$ of 0.389 and 0.45 for level 1 and 2, respectively) and medium accuracy (Cb of 0.827 and 0.859, respectively). The LRNS clearly over-predicted the intake of one study. When this study was removed from the comparison, the precision and accuracy considerably increased for the level 1 solution. Metabolisable protein was limiting ADG for more than 68% of the treatment averages. Both levels differed regarding precision and accuracy. While level 1 solution had the least MB compared with level 2 (0.058 and 0.159 kg/d, respectively), the precision was greater for level 2 than level 1 (0.89 and 0.70, respectively). The accuracy (Cb) was similar between level 1 and level 2 (p = 0.8997; 0.977 and 0.871, respectively). The RMSEP indicated that both levels were on average under-or over-predicted by about 190 g/d, suggesting that even though the accuracy (Cb) was greater for level 1 compared to level 2, both levels are likely to wrongly predict ADG by the same amount. Our analyses indicated that the level 1 solution can predict DMI reasonably well for this type of animal, but it was not entirely clear if animals consumed at their voluntary intake and/or if the roughness of the diet decreased DMI. A deficit of ruminally-undegradable protein and/or a lack of microbial protein may have limited the performance of these animals. Based on these evaluations, the LRNS level 1 solution may be an alternative to predict animal performance when, under specific circumstances, the fractional degradation rates of the carbohydrate and protein fractions are not known.

Towards improving finite element solutions automatically with enriched 2D solid elements

  • Lee, Chaemin;Kim, San
    • Structural Engineering and Mechanics
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    • v.76 no.3
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    • pp.379-393
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    • 2020
  • In this paper, we propose an automatic procedure to improve the accuracy of finite element solutions using enriched 2D solid finite elements (4-node quadrilateral and 3-node triangular elements). The enriched elements can improve solution accuracy without mesh refinement by adding cover functions to the displacement interpolation of the standard elements. The enrichment scheme is more effective when used adaptively for areas with insufficient accuracy rather than the entire model. For given meshes, an error for each node is estimated, and then proper degrees of cover functions are applied to the selected nodes. A new error estimation method and cover function selection scheme are devised for the proposed adaptive enrichment scheme. Herein, we demonstrate the proposed enrichment scheme through several 2D problems.

A study on the solution stability by the position of internal nodes in hihger order isoparametric elements (고차 등매개요소에서 내부절점의 위치와 해의 안정성 연구)

  • Lee, Joon-Hee;Lim, Jang-Keun
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.21 no.12
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    • pp.1973-1983
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    • 1997
  • Higher order isoparametric elements are usually used in the finite element analysis because they can represent easily the geometric shape of a complex structure ad can improve the solution quality. When these elements are used, the position of internal nodes affects greatly on the solution accuracy. Decreasing of the accuracy related to the position of internal nodes is due to non-conformal mapping often results in an unstable Jacobian value. This paper, in order to remove this difficulty, suggests a modified shape function which can establish conformal mapping between two coordinate systems. Numerical experiments with the proposed shape function show that a stable solution can be obtained without respect to the position of internal nodes, and offer convenience that one can take arbitrarily the position of internal nodes considering only the geometric shape of element boundaries.

Development of a Low-cost Metering Device for Automatic Mixing of Nutrient-Solution

  • Ryu, K.H.;Lee, K.C.;Lee, J.H.
    • Proceedings of the Korean Society for Agricultural Machinery Conference
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    • 1996.06c
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    • pp.1117-1125
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    • 1996
  • A low-cost and precise metering device, which is suitable to automatic mixing of nutrient-solution for hydroponic culture, was developed for small-scale growers. The metering accuracy of the metering device developed was compared with commercial metering pumps. The mixing performance through the control of EC and pH was also evaluated. The accuracy of the metering device in terms of the full -scale error was $\pm$0.3% , which was much better compared to $\pm$2.45% and $\pm$1.38% for the two types of commercial metering pumps. The mixing system of nutrient-solution with the metering device showed a satisfactory control performance with the accuracies of $\pm$0.05mS/cm and$\pm$0.2pH for EC and pH, respectively.

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Effects of Space Increment and Time Step to the Accuracy of the Implicit Finite Difference Method in a Two-Dimensional Transient Heat Conduction Problem (이차원과도열전도에 대한 음함수형 유한차분법의 정도에 미치는 공간증분 및 시간간격의 영향)

  • CHO Kwon-Ok;LEE Yong-Sung;OH Hoo-Kyu
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.18 no.1
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    • pp.15-22
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    • 1985
  • The study on computation time, accuracy, and convergency characteristic of the implicit finite difference method is presented with the variation of the space increment and time step in a two-dimensional transient heat conduction problem with a dirichlet boundary condition. Numerical analysis were conducted by the model having the conditions of the solution domain from 0 to 3m, thermal diffusivity of 1.26 $m^2/h$, initial condition of 272 K, and boundary condition of 255.4 K. The results obtained are summarized as follows : 1) The degree of influence with respect to the accuracy of the time step and space increment in the alternating-direction implicit method and Crank-Nicholson implicit method were relatively small, but in case of the fully implicit method showed opposite tendency. 2) To prescribe near the zero for the space increment and tine step in a two dimensional transient problem were good in a accuracy aspect but unreasonable in a computational time aspect. 3) The reasonable condition of the space increment and the time step considering accuracy and computation time could be generalized with the Fourier modulus increment, F, ana dimensionless space increment, X, irrespective of the solution domain.

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The Accuracy Analysis of RTK-GPS by Field Calibration in Plane Surveying (국지측량에서의 현장 Calibration에 의한 RTK-GPS 정확도 분석)

  • Park, Woon-Yong;Shin, Dong-Soo
    • Journal of Korean Society for Geospatial Information Science
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    • v.10 no.2 s.20
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    • pp.87-95
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    • 2002
  • Real-time Kinematic GPS enables high accuracy Positioning by real time. If ambiguity use an integer solution, can obtain accuracy of several 'mm', and can obtain accuracy of tens 'em' if use real solution. In this study, We accomplish surveying by existent traditional surveying techniques (Total Station), Static GPS techniques and RTK-GPS techniques by Field Calibration about uniformity measuring point and then compared and ana1yzed each techniques positioning accuracy etc.. Result that achieve by Static-GPS in Plane area, about all measuring points, expressed error fewer than 3cm. Result that achieve RTK-GPS Surveying by Field Calibration in Plane area, could know that RTK-GPS techniques by Field Calibration is available in Plane area because expressing errors fewer than all 6cm, except case that do not get fixed solution of ambiguity Field Calibration RTK-GPS could know economically than existent conventional type measurement and existent GPS's measurement techniques that efficiency is very high.

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Numerical Simulation for the Advection Equation on the Sphere by Sphere-Lagrangian Method (Semi-Lagrangian법을 이용한 구 좌표계에서의 이류 방정식 해석)

  • Yoon Seong Y.
    • Journal of computational fluids engineering
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    • v.9 no.3
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    • pp.8-17
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    • 2004
  • A Semi-Lagrangian method based on CIP(Cubic Interpolated Pseudoparticle)method is proposed and it is applied to solve the two dimensional advection equation. Especially the attentions are given to settle the pole problem and to enhance the accuracy in solving the advection equation on the spherical coordinate system. Tn this algorithm, the CU method is employed as the Semi-Lagrangian method and extended to the spherical coordinate system. To enhance the accuracy of the solution, the spatial discretization is made by CIP method. The mathematical formulation and numerical results are also described. To verify the efficiency, accuracy and capability of proposed algorithm, two dimensional rotating cosine bell problem and the frontogenesis problem are simulated by the present scheme. As results, it is confirmed that the present scheme gives an accurate solution and settles the pole problem in the advection equation on the sphere.

Color accuracy of imaging using color filters

  • Boher, P.;Leroux, T.;Patton, V. Collomb;Bignon, T.
    • Journal of Information Display
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    • v.13 no.1
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    • pp.7-16
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    • 2012
  • In this paper, the problem concerning the color accuracy of imaging systems using color filters is examined. It is shown that the only solution to the problem is to build systems with the spectral response matching the CIE curves as closely as possible. If the spectral response does not closely match the CIE curves, it was demonstrated that calibration cannot solve the problem and will result in very unstable colorimeters. A practical solution that uses telecentric lenses on the sensor side in addition to dedicated color filters for each CCD detector is presented. For systems that closely match the CIE curves, an innovative method of improving the color accuracy based on the precise measurement of the spectral response is presented. The small discrepancies in the spectral response with regard to the CIE curves are corrected in different ways during the measurements. Finally, it is shown that the tristimulus calibration that is used for display measurement is very unstable for systems without CIE matching and is much more stable with systems that closely match the CIE curves.