• Title/Summary/Keyword: solute

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Analysis of Facilitied Transport through Fixed Site Carrier Membranes

  • Kang, Yong-Soo;Hong, Jae-Min;Kim, Un-Young
    • Proceedings of the Membrane Society of Korea Conference
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    • 1995.09a
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    • pp.57-71
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    • 1995
  • A simple mathematical model for gacilitated mass transport with a fixed site carrier membrane was derived by assuming an instantaneous, microscopic concentration (activity) fluctuation, The concentration fluctuation, developed due to reversible chemical reaction between carrier and solute, could acuse the higher chemical potential gradient and the facilitated transport. For mathematical formulation, an analogy was employed between the mass transfer for the facilitated transport with fixed site carrier membrane and the electron transfer in a parallel resistor-capacitor (RC) circuit. For the single RC model, it was assumed that a single capacitor represented the total carrier and a solute could not inter-diffuse between matrix and carrier, allowing only two diffusional pathways, This assumption was relaxed by adopting a serial combination of the parallel RC circuit. Here, a solute diffuses in two elements (matrix or carrier) can exchange its pathway, exhibiting four diffusional pathways. The current models were examined against experimental data and the agreement was exceptional.

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Variation of Morphology of Solid Particles and Microstructure in Al-Si, Al-Cu and Mg-Al Alloys During Isothermal Heat-Treatment at Semi-Solid Temperatures (반고상 온도구역에서 등온유지한 Al-Si, Al-Cu 및 Mg-Al합금의 고상형상 및 조직의 변화)

  • Jung, Woon-Jae;Kim, Ki-Tae;Hong, Chun-Pyo
    • Journal of Korea Foundry Society
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    • v.16 no.6
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    • pp.556-564
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    • 1996
  • Variation of shape and size of solid particles and solute redistribution in Mg-9wt.%Al, AI-4.5wt.% Cu, and AI-7wt.%Si alloys were investigated when they were heated to semi-solid temperatures and held without stirring. In the case of Mg-9wt.% Al and Al-4.5wt.%Cu alloys, the polygonal shaped solid particles were agglomerated with non-uniform distribution, and there were no disappearance of the solid/solid boundary until the end of melting. But in the case of an Al-7wt.%Si alloys, two or three spherical shaped particles were coalesced or separated individually, and the coalesced particles had no solid/solid interface on the contrary to the prevous case. The maximum size of solid particles during isothermal heating at high temperature was smaller than that at lower temperature, but the time required to reach the maximum size at high temperature was shorter than that at lower temperature. The concentrations of main solute atom whose distribution coefficient is lower than 1, decreased in the primary solid particles as the liquid fraction increased, and the gradient of solute concentration was steeper in Mg-9wt.%Al alloy and Al-4.5wt.%Cu alloy than that of Al-7wt.%Si alloy.

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Effect of the Welding Methods on the Characteristics of Overlaying Seat-surfaces of Engine Valves (엔진밸브 시트 표면의 오버레이층 특성에 미치는 용접법의 영향)

  • 이병영;최병길
    • Journal of Welding and Joining
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    • v.20 no.4
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    • pp.517-524
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    • 2002
  • An overlaying of the seating surfaces of engine valves by OAW, GTAW or PTA weldings are common practice. The OAW method of a lower torch energy density compared to GTAW and PTA methods produces smoother deposits but the pain size at the vicinity of the interface is increased remarkably up to $30~50{\mu\textrm{m}}$ (that of base metal is about $10\mu\textrm{m}$). It's grain coarsening and the solute dilution are related to the decarburizing during OAW could be minimized by reducing the preheating temperature and by maintaining the carbide precipitates in base metal prior to welding. The formation of columnar structures and carbide precipitation zone in the vicinity of the GTAW welded interface, because of the high heat concentration, causes weakened zone on the valve seat face. The width of the reaction boundary zone is about $50\mu\textrm{m}$ for PTA and GTAW overlaying, and about $150\mu\textrm{m}$ for OAW welding. The smaller width of the reaction boundary zone is the less the solute-dilution rate. Thereby PTA welding may be recommended for overlaying of the seating surfaces.

Change of Groundwater Quality derived from Contaminant Sources (오염원에 의한 지하수 수질의 변화)

  • Bae, Sang-Kuen
    • Journal of Environmental Science International
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    • v.4 no.5
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    • pp.75-75
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    • 1995
  • In order to provide for the guidance on groundwater quality monitoring network design and also, to suggest the index to the solution of the contaminated groundwater remediation problems in the lake watershed, it is necessary to analyze the contaminant transport in the groundwater. The solute transport was analyzed in the lake watershed to investigate the behavior of the injected contaminant sources depend on the relationships between the point of contaminant sources and position of the lake. Three hypothetical groundwater flow systems, which is composed of a flow-through lake and two solute sources, were considered. The lakes located in the upper, middle, and lower portions of a watershed respectively. The transported contaminant was numerically simulated for five years by using MT3D contaminant transport model under the three-dimentional steady state conditions. From the above simulations, it can be concluded that the contaminant concentration was high as the contaminant source located at the upper position of a watershed, and the influence of the contaminant injection was large as the solute source located at the lower position. When the injection of contaminant was continued for one year without regard to the position of contaminant source and the lake, the influence of contaminant source was reached to bedrock.

Change of Groundwater Quality derived from Contaminant Sources (오염원에 의한 지하수 수질의 변화)

  • 배상근
    • Journal of Environmental Science International
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    • v.4 no.5
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    • pp.461-468
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    • 1995
  • In order to provide for the guidance on groundwater quality monitoring network design and also, to suggest the index to the solution of the contaminated groundwater remediation problems in the lake watershed, it is necessary to analyze the contaminant transport in the groundwater. The solute transport was analyzed in the lake watershed to investigate the behavior of the injected contaminant sources depend on the relationships between the point of contaminant sources and position of the lake. Three hypothetical groundwater flow systems, which is composed of a flow-through lake and two solute sources, were considered. The lakes located in the upper, middle, and lower portions of a watershed respectively. The transported contaminant was numerically simulated for five years by using MT3D contaminant transport model under the three-dimentional steady state conditions. From the above simulations, it can be concluded that the contaminant concentration was high as the contaminant source located at the upper position of a watershed, and the influence of the contaminant injection was large as the solute source located at the lower position. When the injection of contaminant was continued for one year without regard to the position of contaminant source and the lake, the influence of contaminant source was reached to bedrock.

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Numerical Modeling of Seawater Intrusion in Coastal Aquifer (연안 대수층에서 해수침투 축성 해석)

  • 이연규;이희석
    • Tunnel and Underground Space
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    • v.14 no.3
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    • pp.229-240
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    • 2004
  • Coastal aquifers may serve as major sources fur freshwater. In many coastal aquifers, intrusion of seawater has become one of the major constraints imposed on groundwater utilization. The management of groundwater in coastal acquifers means making decision as to the pumping rate and the spatial distribution of wells. Several numerical techniques for flow and solute transport simulation can provide the means to achieve this goal. As a basic study to predict the intrusion of seawater in coastal phreatic aquifers, the coupled flow and solute transport analysis was conducted by use of the 3-D finite element code, SWICHA. In order to understand how the location and the shape of freshwater-seawater transition zone were affected by the boundary conditions and hydrogeologic variables, parametric study was carried out.

Numerical Simulation of Solute Transport in Coastal Areas (해안지역에서의 용존성 물질의 이송확산 거동 수치모의)

  • Kim, Dae-Hong
    • Ecology and Resilient Infrastructure
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    • v.1 no.1
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    • pp.1-7
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    • 2014
  • In this study, a numerical simulation technique for coastal area where wave and current interactions are observed is proposed. Considering the spatial scale of coastal area and the coastal processes such as wave, current, shoaling, wave breaking, and inundation processes, boussinesq equation model is used. A depth-integrated transport model based on the consistent assumption with the boussinesq equation model is used for the prediction of solute transport. To solve the equations, finite volume method with an approximate riemann solver is used. The proposed model is applied to a coastal area and reasonable computational results are obtained.

Effect of Precipitation and Dissolution of Si on the Thermal Diffusivity in the Al-Si Alloy System (열처리를 통한 Si 고용 및 석출 반응이 Al-Si 합금의 열확산도에 미치는 영향)

  • Kim, Yumi;Kim, Youngchan;Choi, Seweon
    • Korean Journal of Materials Research
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    • v.30 no.9
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    • pp.474-479
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    • 2020
  • The effect of precipitation and dissolution of Si on the thermal diffusivity in the Al-Si alloy system is reported in this study and solution heat treatment followed by aging treatment is carried out to determine the effects of heat treatment on the thermal characteristics. The solution treatment is performed at 535 ℃ for 4 and 10 h and then the specimens are cooled by rapid quenching. The samples are aged at 300 ℃ for 4 h to precipitate Si solute. The addition of 9 wt% silicon contents makes the thermal diffusivity decrease from 78 to 74 mm/s2 in the cases of solid solution treated and quenched samples. After quenching and aging, the Si solute precipitates on the Al matrix and increases the thermal diffusivity compared with that after the quenched state. In particular, the increase of the thermal diffusivity is equal to 10 mm/s2 without relation to the Si contents in the Al-Si alloy, which seems to corresponded to solute amount of Si 1 wt% in the Al matrix.

Structure Parameter Change Estimation of a Forward Osmosis Membrane Under Pressurized Conditions in Pressure-assisted Forward Osmosis (PAFO) (가압형 정삼투 시 압력에 따른 정삼투막의 Structure Parameter 변화양상 예측)

  • Kook, Seungho;Kim, Sung-Jo;Lee, Jinwoo;Hwang, Moonhyun;Kim, In S.
    • Membrane Journal
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    • v.26 no.3
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    • pp.187-196
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    • 2016
  • Pressure-assisted forward osmosis (PAFO) process has recently been under spotlight for its potential to improve forward osmosis (FO) process performance by applying low hydraulic pressure on the feed side. Structure parameter, one of the governing factors in estimating water flux and solute flux across FO membranes in the solution-diffusion model (S-D model), determines solute resistivity in FO and PAFO processes. This study aims to estimate the trend of structure parameter change with respect to varying additional hydraulic pressure condition in PAFO.

Marangoni Convection Effects on Crystal Growth (결정 성장에서 Marangoni 대류의 영향)

  • 강승민;최종건;오근호
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.2 no.2
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    • pp.77-82
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    • 1992
  • When a crystal is grown by FZ process, the melt zone is located at between the solid of upper and lower side and is kept by the solid-liquid interface tension. On the surface of the melt zone, a surface tension gradient is occured by the difference of temperature and solute concentration, it is the driving force of marangoni flow. The crystal even in the steady state growth can become imperfect for the dislocation distribution and the solute concentration in the peripheral region of the crystal are higher than those in the inner part and the probability of the formation of the defects such as voids, bubble penetration, secondary phase creation and crack is high near the solid-liquid interface. This is because the solid -liquid interface becomes irregular because of the local variation of temperature in that region due to marangoni convection.

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