• Title/Summary/Keyword: solid medium

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Evolution of reaction zones in reactive barriers consisting of calcite and glass beads

  • Jeong Gon, Kim;Gwang Man, Lee;Ik Hwan, Go
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2004.04a
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    • pp.19-22
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    • 2004
  • Two-dimensional modeling studies using TOUGHREACT were conducted to investigate the coupling between flow and transport developed as a consequence of differences in density, dissolution/ precipitation, and medium heterogeneity. The model includes equilibrium reactions for aqueous species, kinetic reactions between tile solid phases and aqueous constituents, and full coupling of porosity and permeability changes resulting from precipitation and dissolution reactions in porous media. Generally, the evolutions in the concentrations of the aqueous phase are intimately related to the reaction-front dynamics. Plugging of the medium contributed to significant transients in patterns of flow and mass transport.

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Recent Progress in Nanoparticle Synthesis via Liquid Medium Sputtering and its Applications

  • Cha, In Young;Yoo, Sung Jong;Jang, Jong Hyun
    • Journal of Electrochemical Science and Technology
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    • v.7 no.1
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    • pp.13-26
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    • 2016
  • Nanoparticles (NPs), which have been investigated intensively as electrocatalysts, are usually synthesized by chemical methods that allow precise size and shape control. However, it is difficult to control the components and compositions of alloy NPs. On the other hand, the conventional physical method, sputtering with solid substrates, allows for facile composition control but size control is difficult. Recently, “liquid medium sputtering” has been suggested as an alternative method that is capable of combining the advantages of the chemical and conventional physical methods. In this review, we will discuss NP synthesis via the liquid medium sputtering technique using ionic liquid and low-volatile polymer media. In addition, potential applications of the technique, including the generation of oxygen reduction reaction electrocatalysts, will be discussed.

An Investigation on Local Thermodynamic Equilibrium Assumption of Natural Convection in a Porous Medium (다공성 물질 안에서의 자연대류 현상에 대한 열역학적 국소평형상태 가정의 고찰)

  • Kim, In-Seon;Nam, Jin-Hyun;Kim, Charn-Jung
    • Proceedings of the KSME Conference
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    • 2000.11b
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    • pp.112-117
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    • 2000
  • A numerical study on natural convection in a vertical square cavity filled with a porous medium is carried out with Brinkman-Forchheimer-extended Darcy flow model, and the validity of local thermodynamic equilibrium assumption is studied. The local thermodynamic equilibrium refers to the state in which a single temperature can be used to describe a heat transfer process in a multiphase system. With this assumption, the analysis is greatly simplified because only one equation is needed to describe the heat transfer process. But prior to using this assumption, it is necessary to know in what conditions the assumption can be used. The numerical results of this study reveal that large temperature difference between fluid phase and solid phase exists near wall region, paticularily when the convection becomes dominant over conduction. And the influence of flow parameters such as fluid Rayleigh number, fluid Prandtl number, dimensionless particle diameter and conductivity ratio are investigated.

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Acoustic Characteristics of Sand Sediment Slab with Water- and Air-filled Pore

  • Roh Heui-Seol;Lee Kang Il;Yoon Suk Wang
    • Proceedings of the Acoustical Society of Korea Conference
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    • autumn
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    • pp.223-226
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    • 2001
  • Acoustic pressure transmission coefficient and phase velocity are measured as the functions of water porosity and air porosity in sand sediment slabs with water- and air-filled pores. Pores in the sand sediment slab we modeled as the structure of circular cylindrical tube shape filled with water and air. The first kind(fast) wave and second kind (slow) wave, identified by Biot, in the solid and fluid mixed medium are affected by the presence of water and air pores. Acoustic characteristics of such porous medium in water are also theoretically investigated in terms of the modified Biot-Attenborough (MBA) model, which uses the separate treatment of viscosity effect and thermal effect in non-rigid porous medium with water- and air-filed pores. The information on the fast waves introduces new concepts of the generalized tortuosity factor and dynamic shape factor.

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Diffusion Coefficient of Iron in ZnSe Polycrystals from Metal Phase for mid-IR Gain Medium Application

  • Jeong, Junwoo;Myoung, NoSoung
    • Applied Science and Convergence Technology
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    • v.23 no.6
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    • pp.371-375
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    • 2014
  • Diffusion coefficient of Fe in polycrystalline host ZnSe as a mid-IR gain medium has been measured in the annealing temperature ranges of 850 to $950^{\circ}C$. The synthesis of the samples was carried out in quartz ampoule in which the Fe thin film deposited by physical vapor evaporation method on the ZnSe. One can realize that the diffusion coefficient strongly depends on the surface active surfactants through the cleaning process and the substrate temperature during the thin film deposition leading to $2.04{\times}10^{-9}cm^2/s$ for $Fe^{2+}:ZnSe$. The Annealing temperature dependence of the Fe ions diffusion in ZnSe was used to evaluate the activation energy, $E_a$=1.39 eV for diffusion and the pre-exponential factor $D_0$ of $13.5cm^2/s$.

Establishment and Using of mass propagation system for Calanthe discolor Lindle (새우난초(Calanthe discolor Lindley)의 대량증식 시스템 확립 및 이용)

  • 서병기
    • Korean Journal of Plant Resources
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    • v.15 no.3
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    • pp.221-226
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    • 2002
  • This experiment was conducted to establish the mass propagation system of Calanthe discolor Lindley. When the Calanthe discolor seeds were sown in Murashige and Skoog medium, the percentage of germination was 65%. Seedlings grew more rapidly in the liquid medium than the solid medium. All regenerated plantlets were survived in acclimatized condition of 70% shade and more than 80% humidity. Also, we found out that the 88% of survival ratio could be achieved in containing soil mixture of vermiculite and perlite as same as amount.

Localization of phenoloxidases in coprinus congregatus grown on a low-temperature-liquifying medium (저온 액화성 응고제를 사용한 고체배지에서 자란 coprinus congregatus의 phenoloxidase들의 localization)

  • ;Ross, Ian K.
    • Korean Journal of Microbiology
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    • v.28 no.3
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    • pp.274-277
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    • 1990
  • The hyphal tip phenoloxidases of Coprinus congregatus were localized by the protoplast-concanavalin A method. Protoplast were generated from cultures grown on a solid medium which was solidified with a new gelling agent, Pluronid Polyol F127, instead of agar. the enzymes were associated with the cell membrane which might work as a transducer in the light recepter complex.

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Influence of Al, Cu and Ni Additions on Mechanical Properties of Hot-Rolled Fe-9Mn-0.2C Medium-Manganese Steels

  • Young-Chul Yoon;Sang-Gyu Kim;Sang-Hyeok Lee;Byoungchul Hwang
    • Archives of Metallurgy and Materials
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    • v.66 no.4
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    • pp.1007-1011
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    • 2021
  • The microstructure and mechanical properties of hot-rolled Fe-9Mn-0.2C medium-manganese steels with different Al, Cu, and Ni contents were investigated in this study. Based on the SEM, XRD, and EBSD analysis results, the microstructure was composed of martensite, band-type delta ferrite, and retained austenite phases depending on the Al, Cu, and Ni additions. The tensile and Charpy impact test results showed that the sole addition of Al reduced significantly impact toughness by the presence of delta-ferrite and the decrease of austenite stability although it increased yield strength. However, the combined addition of Al and Cu or Ni provided the best combination of high yield strength and good impact toughness because of solid solution strengthening and increased austenite stability.

A Characteristics of Hg, Pb, As and Se Emitted from Small and Medium Size Waste Incinerator Stacks (중.소형 폐기물 소각시설에서 배출되는 수은, 납, 비소, 셀렌 배출특성)

  • Lee, Han-Kook;Moon, Bu-Shik;Lee, Dong-Hoon
    • Journal of Korean Society of Environmental Engineers
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    • v.27 no.11
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    • pp.1205-1214
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    • 2005
  • This study was carried out to investigate the emission characteristics of volatile metals(Hg, As, Se) and semi volatile metals such as Pb from small and medium size municipal solid waste incinerators(MSWIs). The concentrations of Hg, Pb, As and Se in emission gas from small size waste incinerators were higher than those of medium size waste incinerators. This is probably due to less air pollutant control devices and high emission gas temperature of the small size waste incinerators relative to the medium size waste incinerators. Emission gas temperature from small and medium size waste incinerators were divided into 2 groups. The first group was about $100^{\circ}C$ and the second roup in the range of $400{\sim}700^{\circ}C$. The concentrations of emission gas at the second group were Hg $70.43\;{\mu}g/Sm^3$, Pb $0.94\;{\mu}g/Sm^3$, As $9.83\;{\mu}g/Sm^3$ and Se $5.05\;{\mu}g/Sm^3$. The concentrations of Hg, Pb, As and Se at the first group were lower than those found at the second group. Besides, the removal efficiencies of Hg in medium size waste incinerators were $55.2{\sim}95.9%$. Emission gas temperature reduction from waste heat boiler(WHB) contribute to control of Hg. Based on above results, we postulate that the temperature of flue gas should play a very important role in volatile metal control in small and medium size MSWIs. In order to improve the volatile metals removal efficiency, the temperature of cooling system must be controlled and the air pollution control device should be operated properly.

Criteria of Fruit Quality and Harvest for Production of High Quality Small and Medium-Sized Fruits in 'Hanareum' Pear (Pyrus pyrifolia Nakai) (고품질 중소과 생산을 위한 '한아름' 배의 과실 품질 및 수확 기준)

  • Park, YoSup;Kwon, YongHee
    • Journal of Bio-Environment Control
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    • v.23 no.2
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    • pp.131-138
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    • 2014
  • 'Hanareum' pear is expected to produce the high quality small and medium-sized fruits without any major changes in the current cultivation techniques, inasmuch as its basic characteristics are already included in the range of small and medium-sized fruits. Thus, we tested the possibility of utilization of 'Hanareum' pear for producing small and medium-sized fruits, while establishing the limit of minimum fruit weight for the fruits in high quality. With the results of correlation analysis, it was possible to predict the fruit weight through the observation of soluble solid contents and flesh firmness, because both factors were closely correlated to fruit weight in all treatments. Moreover, these factors were confirmed to be useful indicators of forecasting consumer preference in the sensory evaluation. The fruit marketability was excellent under the conditions that were greater than $11.6^{\circ}Bx$ and less than 25.6 N for soluble solid contents and flesh firmness, respectively. When applying these standards of fruit quality to the results of regression analysis for fruit weight, non-treated fruits fulfilled both standards when the fruit weight was higher than 436 g, and the quality uniformity was also high on this state. Therefore, the production of high quality small and medium-sized fruits was determined to be under this condition. The weight limit for GA treated fruits was 620 g, and both fruit quality and uniformity were below the weight range of small and medium-sized fruits, with 300~500 g. Thus, GA treatment was suggested to be avoided, in order to produce the high quality small and medium-sized fruits.