• Journal of Energy Engineering
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• v.27 no.4
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• pp.1-12
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• 2018

The code and standards related to fuel cells were analyzed to derive the SOFC(Solid Oxide Fuel Cell) stack safety performance evaluation items and evaluation methode. Safety performance evluation of the SOFC stack was tested by quoting derived test items. The stack used in the test is an anode-supported type 2 Cell stack (Active surface area : 220cm) manufactured by MICO Inc, and SOFC stack safety performance evaluation system used for the test is self-manufactured. We conducted a leakage test, current voltage characteristic test, rated output test, and power response characteristics test. In the safety performance evaluation test, the stack showed no gas leakage, the maximum output and rated output was recorded to 65.6 W(1.41 V, 46.5 A, $422mA/cm^2$), 62.3 W(1.57 V, 40 A, $363mA/cm^2$). In the power response characteristics test verified that the output is kept stable within two seconds. At the maximum load (40 A) and the minimum load (8 A), the output was recorded 62 W and 16W in $750^{\circ}C$. This study will contribute to the universalization and to provide much safe environment of operating the solid oxide fuel cell system.

• Journal of the Korean Recycled Construction Resources Institute
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• v.5 no.2
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• pp.116-123
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• 2010

The current enforcement regulation of "The Act on the Promotion of Construction Waste Recycling" defines disposal method of combustible construction waste without obvious recyclging method of those. This leads most combustible construction waste to incinerate or landfill as mixed construction waste. Therefore, it needs regulations to decrease incineration or landfill and to increase recyling of combustible construction waste. This study analyzed the problems of disposal and management of domestic combustible construction waste. As well as considerated regulations relative to utilization of waste solid fuel. From these results, it suggested utilization plans of combustible construction waste as fuel.

• Journal of the Korean Society of Propulsion Engineers
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• v.8 no.2
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• pp.95-101
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• 2004

An experimental investigation was conducted to investigate the effects of the equivalence ratio and air mass flux on the combustion efficiency in a solid fuel ramjet used fuel grains which were highly loaded with boron carbide. Combustion efficiency increased with increasing equivalence ratio (grain length), and decreasing air mass flux. Higher inlet air temperature produced higher combustion efficiencies, apparently the result of enhanced combustion of the larger boron particles those burn in a diffusion controlled regime. Short grains which considered primarily of the recirculation region produced larger particles and lower combustion efficiencies. The result of the normalized combustion efficiency increased with inlet air temperatures coincident with the result of the Brayton cycle thermal and the total efficiency relating to the heat input.

• New & Renewable Energy
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• v.5 no.1
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• pp.11-17
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• 2009

To improve the performance of the anode-supported Solid Oxide Fuel Cell (SOFC) which can be operated at an intermediate temperature, the functional layer (FL) is introduced on a anode substrate. And the scandia-stabilized zirconia (ScSZ) and samaria-doped ceria (SDC) which have higher ionic conductivity and better chemical stability than yttria-stabilized zirconia (YSZ) are used as material for the anode FL with the Ni, The fabrication process of anode-supported single cell with the anode FL was established and the power density of those was evaluated. As a result, the sample with anode FL (Ni-YSZ) has higher power density than normal cell. The single cell which was composed of the FL (Ni-YSZ) and electrolyte (YSZ) showed about $550mW/cm^2$ of the maximum power density at $650^{\circ}C$ and $1430mW/cm^2$ at $750^{\circ}C$ respectively, In case of the single cell using the ScSZ and SDC as anode FL, the performance of samples decreased rapidly and those showed unstable voltage during long-term test. In case of using methane as a fuel, the cell performance with each FL decreased comparing with $H_2$ fuel. In the region of a high current density, there are large concentration polarizations.

• Journal of the Korean Ceramic Society
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• v.45 no.12
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• pp.807-814
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• 2008

The Cu-Ni-YSZ cermet anodes for direct use of methane in solid oxide fuel cells have been fabricated by electroplating Cu into the porous Ni-YSZ cermet anode. The uniform distribution of Cu in the Ni-YSZ anode could be obtained via pulse electroplating in the aqueous solution mixture of $CuSO_4{\cdot}5H_{2}O$ and ${H_2}{SO_4}$ for 30 min with 0.05 A of average applied current. The power density ($0.17\;Wcm^{-2}$) of a single cell with a Cu-Ni-YSZ anode was shown to be slightly lower in methane at $700^{\circ}C$, compared with the power density ($0.28\;Wcm^{-2}$) of a single cell with a Ni-YSZ anode. However, the performance of the Ni-YSZ anode-supported single cell was abruptly degraded over 21 h because of carbon deposition, whereas the Cu-Ni-YSZ anode-supported single cell showed the enhanced durability upto 52 h.

• 한국신재생에너지학회:학술대회논문집
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• 2009.11a
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• pp.218-221
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• 2009

Solid oxide fuel cells (SOFCs), as high-temperature fuel cells, have various advantages. In some merits of SOFCs, high temperature operation can lead to the capability for internal reforming, providing fuel flexibility. SOFCs can directly use CH4 and CO as fuels with sufficient steam feeds. However, hydrocarbons heavier than CH4, such as ethylene, ethane, and propane, induce carbon deposition on the Ni-based anodes of SOFCs. In the case of the ethylene steam reforming reaction on a Ni-based catalyst, the rate of carbon deposition is faster than among other hydrocarbons, even aromatics. In the reformates of heavy hydrocarbons (diesel, gasoline, kerosene and JP-8), the concentration of ethylene is usually higher than other low hydrocarbons such as methane, propane and butane. It is importatnt that ethylene in the reformate is removed for stlable operation of SOFCs. A new methodology, termed post-reforming was introduced for removing low hydrocarbons from the reformate gas stream. In this work, activity tests of some post-reforming catalysts, such as CGO-Ru, CGO-Ni, and CGO-Pt, are investigated. CGO-Pt catalyst is not good for removing ethylene due to low conversion of ethylene and low selectivity of ethylene dehydrogenation. The other hand, CGO-Ru and CGO-Ni catalysts show good ethylene conversion, and CGO-Ni catalyst shows the best reaction selectivity of ethylene dehydrogenation.

• Transactions of the Korean hydrogen and new energy society
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• v.33 no.5
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• pp.550-556
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• 2022

In this study, the flow uniformity was analyzed by performing numerical analysis on the 1 kWe internal manifold type solid oxide fuel cell stack according to the channel height of the separator. Also, it was examined by varying the fuel utilization rate and oxygen utilization rate. From the calculation results, we found that as the channel height of the separator decreased, the pressure drop increased exponentially. In addition, it was found that as the channel height of the separator decreased, the gas flow resistance inside the unit cell increased, and the flow resistance increased the pressure drop, thereby improving the flow uniformity inside the stack. Finally, the calculation results showed that as the fuel and oxygen utilization increased, the flow uniformity also improved.

• Transactions of the Korean hydrogen and new energy society
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• v.28 no.4
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• pp.426-432
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• 2017

Hydrothermal carbonization (HTC) is an effective and environment friendly technique; it possesses extensive potential towards producing high-energy density solid fuels. it is a carbonization method of thermochemical process at a relatively low temperature ($180-250^{\circ}C$). It is reacted by water containing raw material. However, the production and quality of solid fuels from HTC depends upon several parameters; temperature, residence time, and pressure. This study investigates the influence of operating parameters on solid fuel production during HTC. Especially, when food waste was reacted for 2 hours, 4 hours, and 8 hours at $200^{\circ}C$ and 2.0-2.5 MPa, Data including heating value, proximate analysis and water content was consequently collected and analyzed. It was found that reaction temperature, residence time are the primary factors that influence the HTC process.

• Journal of Powder Materials
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• v.15 no.4
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• pp.302-307
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• 2008

$Gd_2O_3$-doped $CeO_2$(GDC) solid solutions have been considered as a promising materials for electrolytes in intermediate-temperature solid oxide fuel cells. In this study, the nano-sized GDC powder with average panicle size of 69nm was prepared by a high energy ball milling process and its sintering behavior was investigated. Heat-treatment at $1200^{\circ}C$ of nano-sized GDC powder mixture led to GDC solid-solution. The enhanced densification over 96% of relative density was obtained after sintering at $1300^{\circ}C$ for 2h. It was found that the sinterability of GDC powder could be significantly improved by the introduction of a high energy ball milling process.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2008.05a
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• pp.349-352
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• 2008

This work is to observe combustion characteristics depending on variation of the solid propellent grain configuration. The LRE (Liquid Rocket Engine) enables adjusting the thrust by controling the required fuel mass glow, but the SRM(Solid Rocket Motor)is not easy to adjust th thrust due to the difficulty of th fuel flow control by its combustion behavior even its configuration is simple. This difficulty can be partly solved by changing th size or the configuration of the propellant grain. In this study a proper grain configuration of a small solid rocket is selected through both the theoretical design and the experimental tests.